公开(公告)号：US3784594A

公开(公告)日：1974-01-08

申请号：US3784594D

申请日：1971-05-25

Applicant: UNION CARBIDE CORP

Inventor： PAPA A ,  PROOPS W

IPC: C07D317/12 ,  C07D317/20 ,  C07D317/24 ,  C07D319/06 ,  C07D319/08 ,  C08G18/81 ,  C08G61/00 ,  C08G53/08

CPC classification number: C07D319/08 ,  C07D317/12 ,  C07D317/20 ,  C07D317/24 ,  C07D319/06 ,  C08G18/8158 ,  C08G61/00

Abstract: NOVEL COPOLYMERIZATION PRODUCTS ARE PROVIDED BY THE CATIONIC POLYMERIZATION OF A DI-(DIHYDROPYRANYL) COMPOUND WITH A SUBSTITUTED 1,3-DIOXOLANE OR A SUBSTITUTED 1,3-DIOXANE. THE COPOLYMERIZATION PRODUCTS POSSESS IMPROVED ABRASION RESISTANCE AND TOUGHNESS AS COMPARED WITH THE HOMOPOLYMERS OF THE DI-(DIHYDROPYRANYL) MONERS. ESPECIALLY USEFUL, PARTICULARLY IN PROVIDING FOAMED POLYMERIC MATERIALS OF IMPROVED FRIABILITY RESISTANCE, ARE THE POLYMERIZATION REACTION PRODUCTS OF 3,4DIHYDRO-2H-PYRAN-2-METHYL(3,4 - DIHYDRO-2H-PYRAN-2-CARBOXYLATE) AND A BIS-DIOXOLANYL OR A BIS-DIOXANYL CARBAMATE.

公开(公告)号：US3833665A

公开(公告)日：1974-09-03

申请号：US17226271

申请日：1971-08-16

Applicant: UNION CARBIDE CORP

Inventor： PAPA A ,  PROOPS W

IPC: C08L71/00 ,  C08G18/00 ,  C08G18/38 ,  C08G18/50 ,  C08G18/65 ,  C08G63/00 ,  C08G63/682 ,  C08G65/28 ,  C08L67/00 ,  C08L71/02 ,  C07C43/18

CPC classification number: C08G18/381 ,  C08G18/5012

Abstract: OXYALKYLATED DERIVATIVES OF A 3 - CYCLOHEXANE-1,1-DIMETHANOL AND A 3,4-DIBROMOCYCLOHEXANE-1,1-DIMETHANOL ARE PROVIDED WHICH ARE USEFUL POLYOLS IN THE MANUFACTURE OF POLYMERIC COMPOSITIONS INCLUDING POLYURETHANES. ALSO PROVIDED ARE POLYMERIC COMPOSITIONS TO WHICH FLAME-RETARDANT PROPERTIES HAVE BEEN IMPARTED BY THE INCORPORATION THEREIN OF A 3,4-DIBROMOCYCLOHEXANE-1,1-DIMETHANOL, AN OXYALKYLATED 3,4-DIBROMOCYCLOHEXANE-1,1-DIMETHANOL, OR A COMBINATION THEREOF. THE DIBROMO-CYCLOALIPHATIC DIOLS OF THE INVENTION ARE ESPECIALLY USEFUL IN THE FORMATION OF FLAME-RETARDED POLYURETHANES INCLUDING CELLULAR POLYURETHANES AND, IN PARTICULAR, FLEXIBLE FOAMS.

公开(公告)号：US3849445A

公开(公告)日：1974-11-19

申请号：US24820172

申请日：1972-04-27

Applicant: UNION CARBIDE CORP

Inventor： PAPA A ,  PROOPS W

IPC: C07D317/24 ,  C07D319/06 ,  C08G18/80 ,  C08G18/81 ,  C08G61/00 ,  C07D13/04

CPC classification number: C08G18/8158 ,  C07D317/24 ,  C07D319/06 ,  C08G18/8064 ,  C08G61/00

Abstract: 1. A POLYCARBONATE HAVING A FORMULA SELECTED FROM THE GROUP CONSISTING OF

S1-(2-S3-1,3-DIOXOLAN-2,4-YLENE)-H2MCM-OOC-NH-ROO-(NH-

COO-CMH2M-(2-S3-1,3-DIOXOLAN-4,2-YLENE)-SI)I-1

AND

(S1-(5-S2-1,3-DIOXOLAN-4,2-YLENE))2-CMH2M-OOC-NH-ROO-(NH-

COO-CMH2M-((5-S2-1,3-DIOXOLAN-2,4-YLENE)-S1)2)I-1

WHEREIN: S1 IS SELECTED FROM THE GROUP CONSISTING OF HYDROGEN AND ALKYL HAVING FROM 1 TO 10 CARBON ATOMS; S2 IS SELECTED FROM THE GROUP CONSISTING OF HYDROGEN AND ALKYL HAVING FROM 1 TO 10 CARBON ATOMS; S3 IS SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, ALKYL HAVING FROM 1 TO 10 CARBON ATOMS, ALKENYL HAVING FROM 2 TO 10 CARBON ATOMS AND DIHALOALKYL HAVING DROM 2 TO 10 CARBON ATOMS; M IS AN INTEGER HAVING A VALUE FROM 1 TO 10; R** REPRESENTS THE UNSUBSTITUTED NUCLEUS OF 2,4-TOLYLENE DIISOCYANATE, 2.6-TOLYLENE DIISOCYANATE OR LIQUID POLY (PHENYLMETHYLENE) POLYISOCYANATE; AND I HAS A AVERAGE VALUE FROM 2 TO ABOUT 3.2.

公开(公告)号：US3833641A

公开(公告)日：1974-09-03

申请号：US17229671

申请日：1971-08-16

Applicant: UNION CARBIDE CORP

Inventor： PAPA A ,  PROOPS W

IPC: C08G18/38 ,  C08K5/20 ,  C07C101/42

CPC classification number: C08G18/3825 ,  C08K5/20

Abstract: NOVEL AROMATIC COMPOUNDS ARE PROVIDED IN WHICH THE AROMATIC NUCLEUS HAS BONDED THERETO (1) AT LEAST ONE BROMINE OR CHLORINE ATOM, (2) AN AMIDO GROUP WHEREIN NITROGEN IS BONDED TO AT LEAST ONE HYDROXYALKYL GROUP OR AN ORGANIC MOIETY BEARING A HYDROXYALKYL GROUP, AND (3) A HYDROXYL-TERMINATED OXYALKYLATED CARBOXYLIC ACID ESTER GROUP. THE HALOGEN-SUBSTITUTED AROMATIC AMIDE-ESTER POLYOLS OF THE INVENTION ARE USEFUL IN IMPARTING FLAME-RETARDANCY TO ORGANIC POLYMERS NORMALLY SUSCEPTIBLE TO BURNING INCLUDING POLYURETHANES SUCH AS, IN PARTICULAR, FLEXIBLE POLYURETHANE FOAMS.

公开(公告)号：US3856865A

公开(公告)日：1974-12-24

申请号：US38174773

申请日：1973-07-23

Applicant: UNION CARBIDE CORP

Inventor： PAPA A ,  PROOPS W ,  SHIELDS T

IPC: C07C43/13 ,  C08G18/38 ,  C08K5/06 ,  C07C43/12

CPC classification number: C08K5/06 ,  C07C43/137 ,  C08G18/381

Abstract: This invention is directed to the new compound, 2,3dihydroxyprop-1-yl 2,3,7,8-tetrabromooct-1-yl ether, and to flame-retarded polymeric compositions having said compound incorporated therein. The tetrabromooctyl ether diol is employed with particular advantage in the formation of flame-retarded cellular polyurethanes including self-extinguishing flexible foams.

Abstract translation: 本发明涉及新的化合物2,3-二羟基丙-1-基2,3,7,8-四溴辛-1-基醚以及其中掺入所述化合物的阻燃聚合物组合物。 使用四溴辛醚二醇特别有利于形成包含自熄性柔性泡沫的阻燃细胞聚氨酯。

公开(公告)号：US3779953A

公开(公告)日：1973-12-18

申请号：US3779953D

申请日：1971-08-16

Applicant: UNION CARBIDE CORP

Inventor： PAPA A ,  PROOPS W

IPC: C08G18/38 ,  C08G18/66 ,  C08G22/08 ,  C08G51/58

CPC classification number: C08G18/381 ,  C08G18/66 ,  Y10S260/24

Abstract: POLYMER COMPOSITIONS NORMALLY SUSCEPTIBLE TO BURNING ARE RENDERED FLAME-RETARDANT BY THE INCORPORATION THEREIN OF 1,2,5,6-TETRABROMO-3,4-DIHYDROXYHEXANE. IN PARTICULAR, A HIGHER MELTING STEREOISOMERIC FORM OF THE LATTER COMPOUND PROVIDES ESSENTIALLY SCORCH-FREE, SELF-EXTINGUISHING POLYURETHANE FOAMS WHICH EXHIBIT A GOOD OVERALL COMBINATION OF PHYSICAL AND MECHANICAL PROPERTIES.

公开(公告)号：US3773696A

公开(公告)日：1973-11-20

申请号：US3773696D

申请日：1971-08-16

Applicant: UNION CARBIDE CORP

Inventor： PAPA A ,  PROOPS W ,  SHIELDS T

IPC: C08G18/38 ,  C08K5/06 ,  C08C17/08

CPC classification number: C08K5/06 ,  C08G18/381

Abstract: This invention is directed to the new compound, 2,3dihydroxyprop-1-yl 2,3,7,8-tetrabromooct-1-yl ether, and to flame-retarded polymeric compositions having said compound incorporated therein. The tetrabromooctyl ether diol is employed with particular advantage in the formation of flame-retarded cellular polyurethanes including self-extinguishing flexible foams.