公开(公告)号：US09895683B2

公开(公告)日：2018-02-20

申请号：US14793428

申请日：2015-07-07

申请人： UNIZEO CO., LTD. ,  The University of Tokyo ,  NATIONAL UNIVERSITY COPORATION YOKOHAMA NATIONAL UNIVERSITY

发明人： Yoshihiro Kubota ,  Satoshi Inagaki ,  Raita Komatsu ,  Keiji Itabashi ,  Tatsuya Okubo ,  Toyohiko Hieda

IPC分类号： C01B39/46 ,  B01J29/70 ,  C10G11/10 ,  C01B39/02 ,  C10G11/05 ,  C10G11/00 ,  C07C11/06 ,  C07C4/06 ,  C07B61/00 ,  B01J35/00

CPC分类号： B01J29/7007 ,  B01J29/70 ,  B01J35/002 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  C01B39/026 ,  C01B39/46 ,  C01B39/48 ,  C07B61/00 ,  C07C4/06 ,  C07C11/06 ,  C10G11/00 ,  C10G11/05 ,  C10G11/10 ,  C10G2400/20

摘要： A MSE-type zeolite which has a Si/Al ratio of 5 or more, is a proton-type zeolite, and is obtained by transforming a raw material MSE-type zeolite synthesized without using a structure directing agent into an ammonium-type zeolite through ion exchange, then, exposing the MSE-type zeolite to water vapor, and subjecting the exposed MES-type zeolite to an acid treatment.

公开(公告)号：US20170368539A1

公开(公告)日：2017-12-28

申请号：US14793428

申请日：2015-07-07

申请人： UNIZEO CO., LTD. ,  THE UNIVERSITY OF TOKYO ,  NATIONAL UNIVERSITY COPORATION YOKOHAMA NATIONAL UNIVERSITY

发明人： Yoshihiro Kubota ,  Satoshi Inagaki ,  Raita Komatsu ,  Keiji Itabashi ,  Tatsuya Okubo ,  Toyohiko Hieda

IPC分类号： B01J29/70 ,  C01B39/46 ,  C10G11/10 ,  C01B39/02 ,  C10G11/05 ,  C07B61/00 ,  B01J35/00 ,  C07C4/06 ,  C07C11/06 ,  C10G11/00

CPC分类号： B01J29/7007 ,  B01J29/70 ,  B01J35/002 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  C01B39/026 ,  C01B39/46 ,  C01B39/48 ,  C07B61/00 ,  C07C4/06 ,  C07C11/06 ,  C10G11/00 ,  C10G11/05 ,  C10G11/10 ,  C10G2400/20

摘要： Provided is a beta-type zeolite which has a high catalytic activity and is not easily deactivated.The beta-type zeolite of the invention has a substantially octahedral shape, has a Si/Al ratio of 5 or more, and is a proton-type zeolite. The Si/Al ratio is preferably 40 or more. This beta-type zeolite is preferably obtained by transforming a raw material beta-type zeolite synthesized without using a structure directing agent into an ammonium-type zeolite through ion exchange, then, exposing the beta-type zeolite to water vapor, and subjecting the exposed beta-type zeolite to an acid treatment.

公开(公告)号：US09238219B2

公开(公告)日：2016-01-19

申请号：US13813104

申请日：2012-11-22

申请人： NIPPON CHEMICAL INDUSTRIAL CO., LTD. ,  NATIONAL UNIVERSITY CORPORATION YOKOHAMA NATIONAL UNIVERSITY ,  The University of Tokyo

发明人： Yoshihiro Kubota ,  Satoshi Inagaki ,  Raita Komatsu ,  Keiji Itabashi ,  Tatsuya Okubo ,  Toyohiko Hieda

IPC分类号： C01B39/46 ,  B01J29/70 ,  C07C4/06 ,  C01B39/48 ,  C01B39/02 ,  B01J35/00 ,  C07B61/00 ,  C07C11/06 ,  C10G11/00

CPC分类号： B01J29/7007 ,  B01J29/70 ,  B01J35/002 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  C01B39/026 ,  C01B39/46 ,  C01B39/48 ,  C07B61/00 ,  C07C4/06 ,  C07C11/06 ,  C10G11/00 ,  C10G11/05 ,  C10G11/10 ,  C10G2400/20

摘要： Provided is a beta-type zeolite which has a high catalytic activity and is not easily deactivated. The beta-type zeolite of the invention has a substantially octahedral shape, has a Si/Al ratio of 5 or more, and is a proton-type zeolite. The Si/Al ratio is preferably 40 or more. This beta-type zeolite is preferably obtained by transforming a raw material beta-type zeolite synthesized without using a structure directing agent into an ammonium-type zeolite through ion exchange, then, exposing the beta-type zeolite to water vapor, and subjecting the exposed beta-type zeolite to an acid treatment.

摘要翻译： 提供了具有高催化活性并且不容易失活的β型沸石。 本发明的β型沸石具有大致八面体形状，Si / Al比为5以上，为质子型沸石。 Si / Al比优选为40以上。 该β型沸石优选通过将通过离子交换将不使用结构导向剂合成的原料β型沸石转化成铵型沸石，然后将β型沸石暴露于水蒸气，并对暴露的 β型沸石进行酸处理。

公开(公告)号：US20140322126A1

公开(公告)日：2014-10-30

申请号：US13813104

申请日：2012-11-22

申请人： NIPPON CHEMICAL INDUSTRIAL CO., LTD. ,  NATIONAL UNIVERISTY CORPORATION YOKOHAMA NATIONAL UNIVERISTY ,  The University of Tokyo

发明人： Yoshihiro Kubota ,  Satoshi Inagaki ,  Raita Komatsu ,  Keiji Itabashi ,  Tatsuya Okubo ,  Toyohiko Hieda

IPC分类号： B01J29/70

CPC分类号： B01J29/7007 ,  B01J29/70 ,  B01J35/002 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  C01B39/026 ,  C01B39/46 ,  C01B39/48 ,  C07B61/00 ,  C07C4/06 ,  C07C11/06 ,  C10G11/00 ,  C10G11/05 ,  C10G11/10 ,  C10G2400/20

摘要： Provided is a beta-type zeolite which has a high catalytic activity and is not easily deactivated.The beta-type zeolite of the invention has a substantially octahedral shape, has a Si/Al ratio of 5 or more, and is a proton-type zeolite. The Si/Al ratio is preferably 40 or more. This beta-type zeolite is preferably obtained by transforming a raw material beta-type zeolite synthesized without using a structure directing agent into an ammonium-type zeolite through ion exchange, then, exposing the beta-type zeolite to water vapor, and subjecting the exposed beta-type zeolite to an acid treatment.

摘要翻译： 提供了具有高催化活性并且不容易失活的β型沸石。 本发明的β型沸石具有大致八面体形状，Si / Al比为5以上，为质子型沸石。 Si / Al比优选为40以上。 该β型沸石优选通过将通过离子交换将不使用结构导向剂合成的原料β型沸石转化成铵型沸石，然后将β型沸石暴露于水蒸气，并对暴露的 β型沸石进行酸处理。