公开(公告)号：US09266809B2

公开(公告)日：2016-02-23

申请号：US14535375

申请日：2014-11-07

Applicant: UOP LLC ,  Boreskov Institute of Catalysis

Inventor： Alakananda Bhattacharyya ,  Joseph A. Kocal ,  Joel T. Walenga ,  Nikolay Y. Adonin ,  Nina I. Kuznetsova ,  Bair S. Bal'zhinimaev

IPC: C07C51/16 ,  C07C51/265 ,  C07C51/42

CPC classification number: C07C51/265 ,  C07C51/42 ,  Y02P20/52 ,  Y02P20/542 ,  C07C63/26

Abstract: A solid terephthalic acid composition and a process for producing terephthalic acid from para-xylene. The process comprises forming a mixture comprising the para-xylene, a solvent, a bromine source, and a catalyst; and oxidizing the para-xylene by contacting the mixture with an oxidizing agent at oxidizing conditions to produce a solid oxidation product comprising terephthalic acid, para-toluic acid, 4-carboxybenzaldehyde. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an dialkyl imidazolium ionic liquid; and the catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium. The solid terephthalic acid composition comprises, less than about 4,000 ppm-wt 4-carboxybenzaldehyde content, and more than about 2,000 ppm-wt a para-toluic acid.

Abstract translation: 固体对苯二甲酸组合物和由对二甲苯生产对苯二甲酸的方法。 该方法包括形成包含对二甲苯，溶剂，溴源和催化剂的混合物; 并通过在氧化条件下将氧化剂与氧化剂接触来氧化对二甲苯以产生包含对苯二甲酸，对甲苯甲酸，4-羧基苯甲醛的固体氧化产物。 溶剂包括具有1至7个碳原子的羧酸和二烷基咪唑鎓离子液体; 催化剂包括钴，钛，锰，铬，铜，镍，钒，铁，钼，锡，铈和锆中的至少一种。 固体对苯二甲酸组合物包含小于约4,000ppm重量的4-羧基苯甲醛含量和大于约2,000ppm重量的对甲苯甲酸。

公开(公告)号：US20190118169A1

公开(公告)日：2019-04-25

申请号：US16221316

申请日：2018-12-14

Applicant: UOP LLC

Inventor： Timur V. Voskoboynikov ,  Alakananda Bhattacharyya ,  Nikolay Y. Adonin ,  Mariya N. Timofeeva ,  Sergey A. Prikhodko ,  Valentin N. Parmon

IPC: B01J31/08 ,  B01J31/30 ,  B01J41/13 ,  B01J41/14 ,  B01J41/10 ,  B01J41/16 ,  B01J47/016 ,  C07C2/38 ,  C07C5/09

CPC classification number: B01J31/08 ,  B01J23/72 ,  B01J27/128 ,  B01J27/13 ,  B01J27/236 ,  B01J31/30 ,  B01J41/10 ,  B01J41/13 ,  B01J41/14 ,  B01J41/16 ,  B01J47/016 ,  B01J2231/20 ,  C07C2/38 ,  C07C5/09 ,  C07C11/167 ,  C07C11/28 ,  C07C2531/08

Abstract: A catalyst and a process for using the catalyst are presented. The catalyst is a heterogeneous catalyst and includes active metal halides bonded to functional groups. The functional groups are bonded to a polymeric backbone to form the structure supporting the catalyst. The catalyst is useful for the dimerization of acetylene to convert the acetylene to a larger hydrocarbon, and in particular to dimerize acetylene to vinylacetylene.

公开(公告)号：US10668455B2

公开(公告)日：2020-06-02

申请号：US16221316

申请日：2018-12-14

Applicant: UOP LLC

Inventor： Timur V. Voskoboynikov ,  Alakananda Bhattacharyya ,  Nikolay Y. Adonin ,  Mariya N. Timofeeva ,  Sergey A. Prikhodko ,  Valentin N. Parmon

IPC: B01J31/08 ,  C07C2/38 ,  B01J23/72 ,  B01J27/13 ,  B01J27/236 ,  B01J27/128 ,  B01J47/016 ,  B01J41/13 ,  B01J31/30 ,  B01J41/10 ,  B01J41/14 ,  B01J41/16 ,  C07C5/09 ,  C07C11/167 ,  C07C11/28

Abstract: A catalyst and a process for using the catalyst are presented. The catalyst is a heterogeneous catalyst and includes active metal halides bonded to functional groups. The functional groups are bonded to a polymeric backbone to form the structure supporting the catalyst. The catalyst is useful for the dimerization of acetylene to convert the acetylene to a larger hydrocarbon, and in particular to dimerize acetylene to vinylacetylene.

公开(公告)号：US20150065747A1

公开(公告)日：2015-03-05

申请号：US14535375

申请日：2014-11-07

Applicant: UOP LLC ,  Boreskov Institute of Catalysis

Inventor： Alakananda Bhattacharyya ,  Joseph A. Kocal ,  Joel T. Walenga ,  Nikolay Y. Adonin ,  Nina I. Kuznetsova ,  Bair S. Bal'zhinimaev

IPC: C07C51/265 ,  C07C51/42

CPC classification number: C07C51/265 ,  C07C51/42 ,  Y02P20/52 ,  Y02P20/542 ,  C07C63/26

Abstract: A solid terephthalic acid composition and a process for producing terephthalic acid from para-xylene. The process comprises forming a mixture comprising the para-xylene, a solvent, a bromine source, and a catalyst; and oxidizing the para-xylene by contacting the mixture with an oxidizing agent at oxidizing conditions to produce a solid oxidation product comprising terephthalic acid, para-toluic acid, 4-carboxybenzaldehyde. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an dialkyl imidazolium ionic liquid; and the catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium. The solid terephthalic acid composition comprises, less than about 4,000 ppm-wt 4-carboxybenzaldehyde content, and more than about 2,000 ppm-wt a para-toluic acid.

Abstract translation: 固体对苯二甲酸组合物和由对二甲苯生产对苯二甲酸的方法。 该方法包括形成包含对二甲苯，溶剂，溴源和催化剂的混合物; 并通过在氧化条件下将氧化剂与氧化剂接触来氧化对二甲苯以产生包含对苯二甲酸，对甲苯甲酸，4-羧基苯甲醛的固体氧化产物。 溶剂包括具有1至7个碳原子的羧酸和二烷基咪唑鎓离子液体; 催化剂包括钴，钛，锰，铬，铜，镍，钒，铁，钼，锡，铈和锆中的至少一种。 固体对苯二甲酸组合物包含小于约4,000ppm重量的4-羧基苯甲醛含量和大于约2,000ppm重量的对甲苯甲酸。