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    Combating fungi with substituted 1-azolyl-butan-2-ones and -2-ols
    5.
    发明授权
    Combating fungi with substituted 1-azolyl-butan-2-ones and -2-ols 失效
    用真菌与取代的1-噻唑基 - 丁-2-酮和-2-ols进行灭菌

    公开(公告)号：US4549900A

    公开(公告)日：1985-10-29

    申请号：US481615

    申请日：1983-04-04

    申请人： Wolfgang Kramer ,  Karl H. Buchel ,  Hans-Ludwig Elbe ,  Udo Kraatz ,  Erik Regel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Klaus Lurssen

    发明人： Wolfgang Kramer ,  Karl H. Buchel ,  Hans-Ludwig Elbe ,  Udo Kraatz ,  Erik Regel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Klaus Lurssen

    IPC分类号： A01N43/50 ,  A01N43/64 ,  A01N43/653 ,  A01N47/02 ,  C07C45/63 ,  C07C45/67 ,  C07C45/71 ,  C07C45/75 ,  C07D249/08 ,  C07D521/00 ,  C07D233/60

    CPC分类号： C07D231/12 ,  A01N43/50 ,  A01N43/64 ,  A01N47/02 ,  C07C323/00 ,  C07C45/63 ,  C07C45/673 ,  C07C45/71 ,  C07C45/75 ,  C07D233/56 ,  C07D249/08

    摘要： Substituted 1-azolyl-but-2-ones and -2-ols of the formula ##STR1## in which B is --CO-- or --CH(OH)--Az represents a 1,2,4-triazol-1-yl or -4-yl or imidazol-1-yl radical,R.sup.1 represents a hydrogen atom, an alkyl, alkenyl, alkinyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted phenoxyalkyl or optionally substituted aralkyl radical,n is 0 or 1,R.sup.2 represents a cyano radical or a grouping of the general formula --X--R.sup.3 or --CO--NR.sup.4 R.sup.5, or, if n does not represent O at the same time as R.sup.1 represents a hydrogen atom and Az represents a 1,2,4-triazolyl radical,R.sup.2 also additionally represents an optionally substituted aryl or alkoxycarbonyl radical,and whereinX represents an oxygen or sulphur atom or an SO or SO.sub.2 group,R.sup.3 represents an alkyl, halogenoalkyl, optionally substituted aryl or optionally substituted aralkyl radical,R.sup.4 represents a hydrogen atom or an alkyl or optionally substituted aryl radical, andR.sup.5 represents a hydrogen atom or an alkyl radical, or acid addition salts or metal salt complexes thereof which possess fungicidal activity and plant growth regulatory and which can be reduced to the corresponding alcohols which are also fungicidally active.

    摘要翻译： 其中B为-CO-或-CH（OH）的取代的1-噻唑基 - 但-2-酮和2-取代的式“IMAGE”为Az代表1,2,4-三唑-1-基或 R 1表示氢原子，烷基，烯基，炔基，任选取代的环烷基，任选取代的环烷基烷基，任选取代的苯氧基烷基或任选取代的芳烷基，n为0或1，R 2表示 氰基或通式-X-R3或-CO-NR4R5的基团，或者如果在R1表示氢原子的同时不表示O，并且Az表示1,2,4-三唑基 R2还另外表示任选取代的芳基或烷氧基羰基，并且其中X表示氧或硫原子或SO或SO 2基团，R 3表示烷基，卤代烷基，任选取代的芳基或任选取代的芳烷基，R 4表示氢原子 或烷基或任选取代的芳基，R 5表示氢原子或 烷基或其酸加成盐或金属盐络合物，其具有杀真菌活性和植物生长调节，并且可以还原成也是杀真菌活性的相应的醇。

    Fungicidally active 3-substituted 1-azolyl-3-methyl-1-phenoxy-butan-2-ones and -ols
    10.
    发明授权
    Fungicidally active 3-substituted 1-azolyl-3-methyl-1-phenoxy-butan-2-ones and -ols 失效
    杀真菌活性3-取代的1-噻唑基-3-甲基-1-苯氧基 - 丁-2-酮和醇

    公开(公告)号：US4629732A

    公开(公告)日：1986-12-16

    申请号：US600581

    申请日：1984-04-17

    申请人： Udo Kraatz ,  Erich Klauke ,  Gerhard Jager ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

    发明人： Udo Kraatz ,  Erich Klauke ,  Gerhard Jager ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

    IPC分类号： A01N43/50 ,  A01N43/64 ,  A01N43/653 ,  C07D233/60 ,  C07D249/08 ,  C07D521/00

    CPC分类号： C07D231/12 ,  A01N43/50 ,  A01N43/653 ,  C07C323/00 ,  C07D233/56 ,  C07D249/08

    摘要： New 3-substituted 1-azolyl-3-methyl-1-phenoxy-butan-2-ones and -ols of the general formula ##STR1## in which Az represents 1,2,4-triazol-1-yl, 1,2,4-triazol-4-yl or imidazol-1-yl,B represents the keto group or the CH(OH) group,Y represents oxygen or sulphur,R represents halogenoalkyl, optionally substituted phenyl or optionally substituted benzyl, or provided Y represents sulphur, may represent alkyl andX.sup.1, X.sup.2 and X.sup.3 are selected independently and each represent hydrogen, halogen, alkyl, halogenoalkyl, alkoxy, alkylthio, alkylsulphonyl, nitro, cyano, alkoxycarbonyl or optionally substituted phenyl,are obtained if halogenoether ketones are reacted with 1,2,4-triazole or imidazole in the presence of a diluent and of an acid-binding agent, and, if appropriate, the keto derivatives thus obtained are reduced. The compounds, as such or as their acid-addition salts or metal-salt complexes, have fungicidal activity, for example against those fungi which cause powdery mildew diseases or cause rice diseases.

    摘要翻译： 新的3-取代的1-吡唑基-3-甲基-1-苯氧基 - 丁-2-酮和通式为其中的Az表示1,2,4-三唑-1-基的 - 1,2,4-三唑-4-基或咪唑-1-基，B表示酮基或CH（OH）基，Y表示氧或硫，R表示卤代烷基，任选取代的苯基或任选取代的苄基，或 提供Y表示硫，可以代表烷基，X 1，X 2和X 3独立选择，各自代表氢，卤素，烷基，卤代烷基，烷氧基，烷硫基，烷基磺酰基，硝基，氰基，烷氧基羰基或任选取代的苯基， 与1,2,4-三唑或咪唑在稀释剂和酸结合剂的存在下反应，如果合适，则所得到的酮衍生物被还原。 化合物本身或其酸加成盐或金属盐络合物具有杀真菌活性，例如针对引起白粉病或引起水稻病的那些真菌。