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    Organotemplate-free synthetic process for the production of a zeolitic material of the LEV-type structure
    7.
    发明授权
    Organotemplate-free synthetic process for the production of a zeolitic material of the LEV-type structure 有权
    用于生产LEV型结构的沸石材料的无机无合成工艺

    公开(公告)号：US09114991B2

    公开(公告)日：2015-08-25

    申请号：US13805092

    申请日：2011-06-17

    申请人： Bilge Yilmaz ,  Ulrich Müller ,  Meike Pfaff ,  Feng-Shou Xiao ,  Bin Xie ,  Haiyan Zhang

    发明人： Bilge Yilmaz ,  Ulrich Müller ,  Meike Pfaff ,  Feng-Shou Xiao ,  Bin Xie ,  Haiyan Zhang

    IPC分类号： C01B39/46 ,  C01B37/02 ,  B01J29/70 ,  C01B39/02 ,  B01J20/18 ,  B01J20/28 ,  B01J20/30

    CPC分类号： C01B39/02 ,  B01J20/186 ,  B01J20/28042 ,  B01J20/28057 ,  B01J20/3007 ,  B01J29/70 ,  C01B37/02 ,  C01B39/46

    摘要： Described is an organotemplate-free synthetic process for the production of a zeolitic material having an LEV-type framework structure comprising YO2 and optionally comprising X2O3, wherein said process comprises:(1) preparing a mixture comprising seed crystals and one or more sources for YO2; and(2) crystallizing the mixture obtained in step (1);wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises one or more alkali metals M, and wherein the seed crystals comprise zeolitic material having an LEV-type framework structure. Also described is a zeolitic material having an LEV-type framework structure obtainable by said process, as well as an organotemplate-free zeolitic material having an LEV-type framework structure comprising YO2 and optionally comprising X2O3, wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises one or more alkali metals M, wherein said zeolitic material is non-calcined.

    摘要翻译： 描述了一种用于生产具有包含YO 2和任选地包含X 2 O 3的LEV型骨架结构的沸石材料的合成方法，其中所述方法包括：（1）制备包含晶种和一种或多种YO2源的混合物 ; 和（2）使步骤（1）中获得的混合物结晶; 其中Y是四价元素，X是三价元素，其中所述沸石材料任选地包含一种或多种碱金属M，并且其中所述晶种包含具有LEV型框架结构的沸石材料。 还描述了具有通过所述方法可获得的LEV型骨架结构的沸石材料，以及具有无机无模板的沸石材料，其具有包含YO 2和任选地包含X 2 O 3的LEV型骨架结构，其中Y是四价元素，X 是三价元素，其中沸石材料任选地包含一种或多种碱金属M，其中所述沸石材料是未煅烧的。

    Process for coating a support surface with a porous metal-organic framework
    8.
    发明授权
    Process for coating a support surface with a porous metal-organic framework 失效
    用多孔金属 - 有机骨架涂覆支撑表面的方法

    公开(公告)号：US08697191B2

    公开(公告)日：2014-04-15

    申请号：US13313122

    申请日：2011-12-07

    申请人： Manuela Gaab ,  Andrea Weber ,  Milan Kostur ,  Ulrich Müller

    发明人： Manuela Gaab ,  Andrea Weber ,  Milan Kostur ,  Ulrich Müller

    IPC分类号： B05D1/02

    CPC分类号： D21H19/10 ,  D21H19/02

    摘要： Described is a process for coating at least part of a surface of a support with a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, which process comprises the steps (a) spraying of the at least one part of the support surface with a first solution comprising the at least one metal ion; (b) spraying of the at least one part of the support surface with a second solution comprising the at least one at least bidentate organic compound, wherein step (b) is carried out before, after or simultaneously with step (a), to form a layer of the porous metal-organic framework.

    摘要翻译： 描述了一种用多孔金属 - 有机骨架涂覆载体表面的至少一部分的方法，所述多孔金属 - 有机骨架包含至少一种与至少一种金属离子配位的至少二齿有机化合物，该方法包括步骤（a） 所述支撑表面的至少一部分具有包含所述至少一种金属离子的第一溶液; （b）用包含至少一种至少二齿有机化合物的第二溶液喷洒至少一部分载体表面，其中步骤（b）在步骤（a）之前或之后进行，以形成 一层多孔金属 - 有机骨架。