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142 条记录 (耗时 0.034 秒)

    Process for preparing porous metal-organic framework materials
    8.
    发明授权
    Process for preparing porous metal-organic framework materials 有权
    制备多孔金属 - 有机骨架材料的方法

    公开(公告)号：US08372998B2

    公开(公告)日：2013-02-12

    申请号：US13336396

    申请日：2011-12-23

    申请人： Markus Schubert ,  Ulrich Mueller ,  Michael Hesse ,  Uwe Diehlmann

    发明人： Markus Schubert ,  Ulrich Mueller ,  Michael Hesse ,  Uwe Diehlmann

    IPC分类号： C07C1/08 ,  B01D15/00 ,  B01D59/26

    CPC分类号： C07C51/418 ,  C07C63/307

    摘要： The present invention relates to a method for producing a porous metal-organic framework material comprising the stepreacting a reaction mixture in the liquid phase of at least one copper compound having at least one at least bidentate, organic compound which can bind by coordination to the copper in the presence of a nonaqueous solvent, the at least one at least bidentate, organic compound being derived from a polycarboxylic acid having at least three carboxyl groups, and the reaction proceeding at atmospheric pressure above 80° C.

    摘要翻译： 本发明涉及多孔金属 - 有机骨架材料的制造方法，该方法包括使具有至少一种至少二齿的有机化合物的至少一种铜化合物的液相中的反应混合物反应，该有机化合物可通过配位与 铜在非水溶剂的存在下，所述至少一种至少二齿的有机化合物衍生自具有至少三个羧基的多元羧酸，并且所述反应在大气压下高于80℃进行。

    Process for preparing porous metal-organic framework materials
    9.
    发明授权
    Process for preparing porous metal-organic framework materials 有权
    制备多孔金属 - 有机骨架材料的方法

    公开(公告)号：US08115024B2

    公开(公告)日：2012-02-14

    申请号：US12278514

    申请日：2007-02-05

    申请人： Markus Schubert ,  Ulrich Mueller ,  Michael Hesse ,  Uwe Diehlmann

    发明人： Markus Schubert ,  Ulrich Mueller ,  Michael Hesse ,  Uwe Diehlmann

    IPC分类号： C07F1/00

    CPC分类号： C07C51/418 ,  C07C63/307

    摘要： The present invention relates to a method for producing a porous metal-organic framework material comprising the step reacting a reaction mixture in the liquid phase of at least one copper compound having at least one at least bidentate, organic compound which can bind by coordination to the copper in the presence of a nonaqueous solvent, the at least one at least bidentate, organic compound being derived from a polycarboxylic acid having at least three carboxyl groups, and the reaction proceeding at atmospheric pressure above 80° C.

    摘要翻译： 本发明涉及多孔金属 - 有机骨架材料的制造方法，该方法包括使具有至少一种至少二齿的有机化合物的至少一种铜化合物的液相中的反应混合物反应，该有机化合物可通过配位与 铜在非水溶剂的存在下，所述至少一种至少二齿的有机化合物衍生自具有至少三个羧基的多元羧酸，并且所述反应在大气压下高于80℃进行。

    Process for the separation of unbranched hydrocarbons from their branched isomers
    10.
    发明授权
    Process for the separation of unbranched hydrocarbons from their branched isomers 失效
    从支链异构体中分离未分支烃的方法

    公开(公告)号：US08658849B2

    公开(公告)日：2014-02-25

    申请号：US12668436

    申请日：2008-06-30

    申请人： Markus Schubert ,  Ulrich Mueller ,  Christoph Kiener ,  Ingo Richter ,  William Dolan ,  Frank Poplow

    发明人： Markus Schubert ,  Ulrich Mueller ,  Christoph Kiener ,  Ingo Richter ,  William Dolan ,  Frank Poplow

    IPC分类号： C07C7/13

    CPC分类号： C07C7/12 ,  B01J20/22 ,  B01J20/226 ,  B01J2220/56 ,  C07C7/135 ,  C10G25/003 ,  C07C9/00

    摘要： The present invention relates to a process for the separation of at least one unbranched C4-C2O hydrocarbon from a fluid mixture containing the unbranched hydrocarbon and at least one branched isomer of the unbranched hydrocarbon, which comprises the step of—contacting the fluid mixture with an adsorbent comprising a porous metal organic framework material, which material comprises at least one at least bidentate organic compound coordinately bound to at least one metal ion, to get the unbranched hydrocarbon adsorbed, wherein the at least one at least bidentate organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived from at least one heterocycle selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens and is unsubstituted or bears one or more substituents selected independently from the group consisting of halogen, Ci-6-alkyl, phenyl, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl, where the substituents Ci_6-alkyl and phenyl are unsubstituted or bear one or more substituents selected independently from the group consisting of halogen, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl. The present invention also relates to the use of said porous metal-organic framework material in a process for the separation of unbranched hydrocarbons from their branched isomers.

    摘要翻译： 本发明涉及从含有非支链烃和非支链烃的至少一种支链异构体的流体混合物中分离至少一种未分支的C 4 -C 20烃的方法，其包括使流体混合物与 吸附剂，其包含多孔金属有机骨架材料，该材料包含与至少一种金属离子配位结合的至少一种至少二齿有机化合物，以获得非支化烃被吸附，其中至少一种至少二齿有机化合物是单环， 衍生自选自吡咯，α-吡啶酮和γ-吡啶酮的至少一种杂环的双环或多环系统，并且具有至少两个环氮并且是未取代的或带有一个或多个独立地选自以下的取代基： 的卤素，C 1-6 - 烷基，苯基，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH，苯基和OC 1-6 - 烷基 ，其中取代基C 1-6 - 烷基和苯基是未取代的或具有一个或多个独立地选自卤素，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH， 和OC 1-6烷基。 本发明还涉及所述多孔金属 - 有机骨架材料在从其支化异构体中分离未分支烃的方法中的用途。