公开(公告)号：US09670109B2

公开(公告)日：2017-06-06

申请号：US14428013

申请日：2013-09-11

申请人： University Court of the University of St. Andrews

发明人： Jennifer Julis ,  David John Cole-Hamilton ,  Catherine Cazin

IPC分类号： C07C37/50 ,  C07C41/03 ,  C07C1/20 ,  C07C37/00 ,  C07C39/19

CPC分类号： C07C1/20 ,  C07C37/003 ,  C07C37/50 ,  C07C39/19 ,  C07C41/03 ,  C07C2531/22 ,  C07C2531/28 ,  Y02P30/42 ,  C07C11/02 ,  C07C11/12 ,  C07C11/21 ,  C07C39/06 ,  C07C43/23

摘要： The invention provides a method of alkene metathesis comprising contacting at least a first alkene, which is cardanol and/or anacardic acid, with an alkylidene ruthenium alkene metathesis catalyst comprising two ligands P1 and P2, which may be the same or different and of formula P(R1)3, in which P is a phosphorus atom coordinated to the ruthenium ion and each R1 is independently an optionally substituted alkyl or alkoxy group; or two R1 groups within one P1 or P2 ligand constitute an optionally substituted bicycloalkyl.

公开(公告)号：US10128447B2

公开(公告)日：2018-11-13

申请号：US15532298

申请日：2015-12-01

申请人： UNIVERSITY COURT OF THE UNIVERSITY OF ST ANDREWS

发明人： Catherine Cazin ,  Ifor David William Samuel ,  Eli Zysman-Colman

IPC分类号： H01L51/00 ,  C09K11/06 ,  C07F15/00 ,  H01L51/50

摘要： A light-emitting device includes an organometallic complex of the form Z-M-Z1, as light emitting material. M is Pd(0) or Pt(0) and Z is a nitrogen containing heterocyclic carbene ligand. Z1 is a phosphorus ligand or a nitrogen containing heterocyclic carbene ligand that may be the same as or different from Z. The light emitting device may be an organic light-emitting diode (OLED), a sensor, or a light-emitting electrochemical cell (LEEC).

公开(公告)号：US20150321981A1

公开(公告)日：2015-11-12

申请号：US14428013

申请日：2013-09-11

申请人： University Court of the University of St. Andrews

发明人： Jennifer Julis ,  David John Cole-Hamilton ,  Catherine Cazin

IPC分类号： C07C37/50 ,  C07C41/03 ,  C07C1/20 ,  C07C37/00

CPC分类号： C07C1/20 ,  C07C37/003 ,  C07C37/50 ,  C07C39/19 ,  C07C41/03 ,  C07C2531/22 ,  C07C2531/28 ,  Y02P30/42 ,  C07C11/02 ,  C07C11/12 ,  C07C11/21 ,  C07C39/06 ,  C07C43/23

摘要： The invention provides a method of alkene metathesis comprising contacting at least a first alkene, which is cardanol and/or anacardic acid, with an alkylidene ruthenium alkene metathesis catalyst comprising two ligands P1 and P2, which may be the same or different and of formula P(R1)3, in which P is a phosphorus atom coordinated to the ruthenium ion and each R1 is independently an optionally substituted alkyl or alkoxy group; or two R1 groups within one P1 or P2 ligand constitute an optionally substituted bicycloalkyl.

摘要翻译： 本发明提供了一种烯烃复分解方法，其包括将至少一种第一烯烃（其为腰果酚和/或酸硬酸）与包含两个配体P1和P2的亚烷基钌烯烃复分解催化剂接触，所述配体P1和P2可以相同或不同，并且具有式P （R1）3，其中P是与钌离子配位的磷原子，每个R 1独立地是任选取代的烷基或烷氧基; 或一个P1或P2配体内的两个R1基团构成任选取代的双环烷基。

公开(公告)号：US20180212160A1

公开(公告)日：2018-07-26

申请号：US15532298

申请日：2015-12-01

申请人： UNIVERSITY COURT OF THE UNIVERSITY OF ST ANDREWS

发明人： Catherine Cazin ,  Ifor David William Samuel ,  Eli Zysman-Colman

IPC分类号： H01L51/00 ,  C07F15/00 ,  C09K11/06

CPC分类号： H01L51/0084 ,  C07F15/006 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L51/0087 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5032

摘要： A light-emitting device includes an organometallic complex of the form Z-M-Z1, as light emitting material. M is Pd(0) or Pt(0) and Z is a nitrogen containing heterocyclic carbene ligand. Z1 is a phosphorus ligand or a nitrogen containing heterocyclic carbene ligand that may be the same as or different from Z. The light emitting device may be an organic light-emitting diode (OLED), a sensor, or a light-emitting electrochemical cell (LEEC).

公开(公告)号：US09815765B2

公开(公告)日：2017-11-14

申请号：US14348407

申请日：2012-09-28

申请人： UNIVERSITY COURT OF THE UNIVERSITY OF ST ANDREWS

发明人： Catherine Cazin

IPC分类号： C07F15/00 ,  C08G61/08 ,  C07C67/317 ,  C07C6/02 ,  C07C253/30 ,  C07C67/333 ,  C07C67/343 ,  C07F17/02 ,  C07D207/20 ,  C07D211/70 ,  C07D223/04 ,  C07D307/28 ,  C07F7/18

CPC分类号： C07C67/317 ,  C07C6/02 ,  C07C67/333 ,  C07C67/343 ,  C07C253/30 ,  C07C2531/18 ,  C07C2531/22 ,  C07C2531/30 ,  C07C2601/10 ,  C07C2601/16 ,  C07C2602/22 ,  C07D207/20 ,  C07D211/70 ,  C07D223/04 ,  C07D307/28 ,  C07F7/1804 ,  C07F15/0046 ,  C07F17/02 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/418 ,  C07C13/44 ,  C07C255/46 ,  C07C69/74 ,  C07C69/75 ,  C07C69/738

摘要： Cis and trans ruthenium complexes that can be used as catalysts for ring opening metathesis polymerization (ROMP) are described. The complexes are generally square pyramidal in nature, having two anionic ligands X. Corresponding cationic complexes where one or both of the anionic ligands X are replaced by a non-co-ordinating anionic ligand are also described. Polymers such as polydicyclopentadiene (PDCPD) can be prepared using the catalysts.

公开(公告)号：US20140228563A1

公开(公告)日：2014-08-14

申请号：US14348407

申请日：2012-09-28

申请人： UNIVERSITY COURT OF THE UNIVERSITY OF ST ANDREWS

发明人： Catherine Cazin

IPC分类号： C07F15/00 ,  C07C67/317 ,  C07D223/04 ,  C07F7/18 ,  C07D211/70 ,  C07D207/20 ,  C07D307/28

CPC分类号： C07C67/317 ,  C07C6/02 ,  C07C67/333 ,  C07C67/343 ,  C07C253/30 ,  C07C2531/18 ,  C07C2531/22 ,  C07C2531/30 ,  C07C2601/10 ,  C07C2601/16 ,  C07C2602/22 ,  C07D207/20 ,  C07D211/70 ,  C07D223/04 ,  C07D307/28 ,  C07F7/1804 ,  C07F15/0046 ,  C07F17/02 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/418 ,  C07C13/44 ,  C07C255/46 ,  C07C69/74 ,  C07C69/75 ,  C07C69/738

摘要： Cis and trans ruthenium complexes that can be used as catalysts for ring opening metathesis polymerisation (ROMP) are described. The complexes are generally square pyramidal in nature, having two anionic ligands X. Corresponding cationic complexes where one or both of the anionic ligands X are replaced by a non-co-ordinating anionic ligand are also described. Polymers such as polydicyclopentadiene (PDCPD) can be prepared using the catalysts.

摘要翻译： 描述了可用作开环易位聚合（ROMP）催化剂的顺式和反式钌络合物。 复合物本质上通常为方形金字塔形，具有两个阴离子配体X.还描述了其中一个或两个阴离子配体X被非配位阴离子配体代替的相应的阳离子络合物。 可以使用催化剂制备聚二聚戊二烯（PDCPD）等聚合物。