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1.发明授权公开(公告)号：US06956129B2
公开(公告)日：2005-10-18
申请号：US10074180
申请日：2002-02-12
IPC分类号： C07C45/46 , C07C45/62 , C07C49/697 , C07C51/363 , C07C57/60 , C07C51/347 , C07C231/14 , C07C233/00
CPC分类号： C07C57/60 , C07C45/46 , C07C45/62 , C07C49/697 , C07C51/363
摘要： Polyhalogenated cinnamic acids and cinnamic acid derivatives are prepared by reacting diazonium salts accessible from polyhalogenated anilines with acrylic acid or acrylic acid derivatives in the presence of a homogeneous, palladium-containing catalyst at about −5 to about +100° C. Some of the cinnamic acids and cinnamic acid derivatives obtainable in this way are new. Cinnamic acids and cinnamic acid derivatives which can be prepared according to the invention can be used for the preparation of indanones which are precursors for agro- and pharmaceutical chemicals and for substances having liquid-crystalline properties.
摘要翻译： 多卤代肉桂酸和肉桂酸衍生物通过在大约-5至大约+ 100℃的均相的含钯催化剂存在下，将可从多卤代苯胺获得的重氮盐与丙烯酸或丙烯酸衍生物反应来制备。一些肉桂酸 以这种方式获得的酸和肉桂酸衍生物是新的。 可以根据本发明制备的肉桂酸和肉桂酸衍生物可用于制备作为农药和药物化学品的前体的茚满酮和具有液晶性质的物质。
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公开(公告)号：US20080200731A1
公开(公告)日：2008-08-21
申请号：US12148752
申请日：2008-04-22
IPC分类号： C07C45/62
CPC分类号： C07C57/60 , C07C45/46 , C07C45/62 , C07C49/697 , C07C51/363
摘要： Polyhalogenated cinnamic acids and cinnamic acid derivatives are prepared by reacting diazonium salts accessible from polyhalogenated anilines with acrylic acid or acrylic acid derivatives in the presence of a homogeneous, palladium-containing catalyst at about −5 to about +100° C. Some of the cinnamic acids and cinnamic acid derivatives obtainable in this way are new. Cinnamic acids and cinnamic acid derivatives which can be prepared according to the invention can be used for the preparation of indanones which are precursors for agro- and pharmaceutical chemicals and for substances having liquid-crystalline properties.
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3.发明授权公开(公告)号：US07381832B2
公开(公告)日：2008-06-03
申请号：US11150721
申请日：2005-06-10
IPC分类号： C07C69/76 , C07C63/64 , C07C233/00
CPC分类号： C07C57/60 , C07C45/46 , C07C45/62 , C07C49/697 , C07C51/363
摘要： Polyhalogenated cinnamic acids and cinnamic acid derivatives are prepared by reacting diazonium salts accessible from polyhalogenated anilines with acrylic acid or acrylic acid derivatives in the presence of a homogeneous, palladium-containing catalyst at about −5 to about +100° C. Some of the cinnamic acids and cinnamic acid derivatives obtainable in this way are new. Cinnamic acids and cinnamic acid derivatives which can be prepared according to the invention can be used for the preparation of indanones which are precursors for agro- and pharmaceutical chemicals and for substances having liquid-crystalline properties.
摘要翻译： 多卤代肉桂酸和肉桂酸衍生物通过在大约-5至大约+ 100℃的均相的含钯催化剂存在下，将可从多卤代苯胺获得的重氮盐与丙烯酸或丙烯酸衍生物反应来制备。一些肉桂酸 以这种方式获得的酸和肉桂酸衍生物是新的。 可以根据本发明制备的肉桂酸和肉桂酸衍生物可用于制备作为农药和药物化学品的前体的茚满酮和具有液晶性质的物质。
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公开(公告)号：US20050234264A1
公开(公告)日：2005-10-20
申请号：US11150721
申请日：2005-06-10
IPC分类号： C07C45/46 , C07C45/62 , C07C49/697 , C07C51/363 , C07C57/60 , C07C233/81 , C07C63/04 , C07C65/36
CPC分类号： C07C57/60 , C07C45/46 , C07C45/62 , C07C49/697 , C07C51/363
摘要： Polyhalogenated cinnamic acids and cinnamic acid derivatives are prepared by reacting diazonium salts accessible from polyhalogenated anilines with acrylic acid or acrylic acid derivatives in the presence of a homogeneous, palladium-containing catalyst at about −5 to about +100° C. Some of the cinnamic acids and cinnamic acid derivatives obtainable in this way are new. Cinnamic acids and cinnamic acid derivatives which can be prepared according to the invention can be used for the preparation of indanones which are precursors for agro- and pharmaceutical chemicals and for substances having liquid-crystalline properties.
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公开(公告)号：US06455725B1
公开(公告)日：2002-09-24
申请号：US09762838
申请日：2001-02-13
IPC分类号： C07C26100
CPC分类号： C07C69/76 , C07C51/353 , C07C51/36 , C07C51/373 , C07C63/74 , C07C67/303 , C07C67/313 , C07C67/343 , C07C63/68 , C07C62/38 , C07C69/757
摘要： The invention relates to substituted cinnamic acids and cinnamic acid esters of formula (I), wherein X represents F, Cl or J and R1 and R2 are the same or different and represent hydrogen, an optionally substituted C1-C10-alkyl radical or an optionally substituted benzyl radical. Substituted indanone carboxylic acid esters are produced using said substituted cinnamic acid and cinnamic acid ester in a technically simple and non-dangerous manner as far as safety is concerned.
摘要翻译： 本发明涉及式（I）的取代肉桂酸和肉桂酸酯，其中X表示F，Cl或J，R 1和R 2相同或不同，表示氢，任选取代的C 1 -C 10 - 烷基或任选地 取代的苄基。 在安全性方面，以技术上简单且非危险的方式使用所述取代的肉桂酸和肉桂酸酯制备取代的茚满酮羧酸酯。
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公开(公告)号：US5922874A
公开(公告)日：1999-07-13
申请号：US122160
申请日：1998-07-24
IPC分类号： C07D295/04 , C07D295/06 , C07D295/08 , C07D295/088 , C07D295/096 , C07D295/13 , C07D295/073
CPC分类号： C07D295/096 , C07D295/088
摘要： N-aryl-N'-alkyl-piperazines are obtained in a particularly simple manner, in good yields and in short reaction times when an aniline is reacted under pressure with an N-alkyl-bishydroxyethyl-amine in the presence of a strong acid.
摘要翻译： 在强酸存在下苯胺在压力下与N-烷基 - 二羟乙基胺反应时，以良好的收率和短的反应时间，以特别简单的方式获得N-芳基-N'-烷基 - 哌嗪。
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7.发明授权Process for preparing 6-oxo-(6H)-dibenz-[c,e][1,2]-oxaphosphorins (ODOPs) 失效制备6-氧代 - （6H） - 二苯并[c，e] [1,2] - 氧磷杂菁（ODOP）的方法
公开(公告)号：US5650530A
公开(公告)日：1997-07-22
申请号：US527234
申请日：1995-09-12
IPC分类号： C09K15/32 , C07F9/6571 , C07F9/6574 , C08K5/53 , C09K21/12 , C07F9/02
CPC分类号： C07F9/65719
摘要： Optionally substituted ODOP is obtained by reaction of optionally substituted o-phenylphenol with PCl.sub.3 in the presence of Lewis acids at elevated temperature in a first stage, with according to the invention an excess of at least 0.05 mol of PCl.sub.3 per mol of o-phenylphenol being maintained during the entire reaction time, and, after removal of the PCl.sub.3, by hydrolysis in a second stage using 1-2 mol of H.sub.2 O per chlorine equivalent of the product of the first stage at 50.degree.-150.degree. C. and with removal of HCl and residual H.sub.2 O.
摘要翻译： 任选取代的ODOP通过任选取代的邻苯基苯酚与PCl 3在路易斯酸存在下在升高的温度下在第一阶段中反应获得，根据本发明，每摩尔邻苯基苯酚的过量至少为0.05摩尔的PCl 3 在整个反应时间内保持，并且在除去PCl 3之后，在第二阶段中通过在50-150℃的第一阶段的产物中每1-2当量的H 2 O使用1-2摩尔水解并除去 HCl和残余的H 2 O。
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8.发明授权Process for the preparation of halogenomethylcyclopropanes and ultrapure halogenomethylcyclopropane 失效制备卤代甲基环丙烷和超纯卤代甲基环丙烷的方法
公开(公告)号：US6063971A
公开(公告)日：2000-05-16
申请号：US340558
申请日：1999-06-28
CPC分类号： C07C22/04 , C07C17/16 , C07C22/00 , C07C2101/02
摘要： A process for producing a compound of the formula (I) ##STR1## wherein Hal is chlorine or bromine, and R.sup.1 to R.sup.5 are, each independently, hydrogen, unsubstituted or substituted C.sub.1 -C.sub.10 -alkyl, or unsubstituted or substituted C.sub.6 -C.sub.10 -aryl;comprising reacting a compound of the formula (II) ##STR2## wherein R.sup.1 to R.sup.5 are the same as above with chlorine or bromine, the chlorine or bromine being in an excess of at least 5 mol % compared to the compound of formula (I), with an organic phosphorus compound of the formula (III) ##STR3## wherein each Ar is independently an unsubstituted or substituted C.sub.6 -C.sub.10 -aryl, the process yielding the compound of formula (I) having a purity of over 95%.
摘要翻译： 制备式（I）化合物的方法，其中Hal为氯或溴，R 1至R 5各自独立地为氢，未取代或取代的C 1 -C 10 - 烷基或未取代或取代的C 6 -C 10 - 芳基; 包括使式（II）化合物（其中R 1至R 5与上述相同）与氯或溴反应，与式（I）化合物相比，氯或溴至少5摩尔％，与 式（III）的有机磷化合物，其中每个Ar独立地是未取代或取代的C 6 -C 10 - 芳基，该方法得到纯度超过95％的式（I）化合物。
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9.发明授权Process for the production of halogen methyl cyclopropanes and highly pure halogen methyl cyclopropanes 失效制备卤代甲基环丙烷和高纯度卤代甲基环丙烷的方法
公开(公告)号：US6008420A
公开(公告)日：1999-12-28
申请号：US137387
申请日：1998-08-20
CPC分类号： C07C22/04 , C07C17/16 , C07C22/00 , C07C2101/02
摘要： The invention relates to a process for the preparation of halogenomethylcyclopropanes.
摘要翻译： 本发明涉及一种制备卤代甲基环丙烷的方法。
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公开(公告)号：US06433228B1
公开(公告)日：2002-08-13
申请号：US09486010
申请日：2000-02-18
IPC分类号： C07C49697
CPC分类号： C07C45/46 , C07C49/697
摘要： 2-Halogenoindan-1-ones are prepared in an advantageous manner by converting anilines into diazonium salts and these, with acrylic compounds, into 3-phenyl-1-halogenoproprionic acid derivatives, and latter are cyclized.
摘要翻译： 通过将苯胺转化为重氮盐，并将其与丙烯酸类化合物一起转化为3-苯基-1-卤代丙酸衍生物，然后将其环化，制备2-卤代茚并-1 -1-酮。
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