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    MISCIBLE POLYESTER BLENDS AND SHRINKABLE FILMS PREPARED THEREFROM
    2.
    发明申请
    MISCIBLE POLYESTER BLENDS AND SHRINKABLE FILMS PREPARED THEREFROM 审中-公开
    不可思议的聚酯薄膜和可编织的薄膜

    公开(公告)号：US20090227735A1

    公开(公告)日：2009-09-10

    申请号：US12397624

    申请日：2009-03-04

    申请人： Wayne Ken Shih ,  Rondell Paul Little, JR.

    发明人： Wayne Ken Shih ,  Rondell Paul Little, JR.

    IPC分类号： C08L1/08 ,  C08L67/03 ,  C08L3/04

    CPC分类号： C08J5/18 ,  C08J2367/02 ,  C08L67/02 ,  C08L2666/18

    摘要： Disclosed are polyester blends useful for the preparation of heat-shrinkable films, and heat-shrinkable films prepared therefrom. The heat shrinkable film may be oriented in the machine direction to produce films with high machine-direction shrinkage but low transverse growth or shrinkage. The films are useful for roll-fed, shrink-on label applications. Also disclosed are heat-shrinkable roll-fed labels prepared from reactor-grade polyesters.

    摘要翻译： 公开了可用于制备热收缩膜的聚酯共混物和由其制备的热收缩膜。 热收缩膜可以在机器方向上取向以产生具有高机器方向收缩但低横向生长或收缩的膜。 这些胶片可用于卷筒纸，收缩标签应用。 还公开了由反应器级聚酯制备的热收缩辊式标签。

    Reactor grade copolyesters for shrink film applications
    3.
    发明授权
    Reactor grade copolyesters for shrink film applications 有权
    用于收缩膜应用的反应器级共聚酯

    公开(公告)号：US06362306B1

    公开(公告)日：2002-03-26

    申请号：US09636320

    申请日：2000-08-11

    申请人： Marcus David Shelby ,  Wayne Ken Shih ,  Rondell Paul Little, Jr. ,  Candace Michele Tanner ,  William LeRoy Wortman

    发明人： Marcus David Shelby ,  Wayne Ken Shih ,  Rondell Paul Little, Jr. ,  Candace Michele Tanner ,  William LeRoy Wortman

    IPC分类号： C08G63183

    CPC分类号： C08G63/672 ,  C08G63/199 ,  C08G63/82 ,  C08G63/85 ,  C08J5/18 ,  C08J2367/02

    摘要： A reactor grade copolyester composition, as well as a heat-shrinkable film made therefrom, unexpectedly has higher ductility than a multi-component blend of copolyesters with the same monomer concentrations. The reactor grade copolyester composition is made from a diacid component of at least about 90 mole percent and a diol component of (a) about 72 to about 88 mole percent ethylene glycol, about 10 to about 15 mole percent 1,4-cyclohexanedimethanol, and about 2 to about 13 mole percent diethylene glycol, or (b) about 59 to about 77.5 mole percent ethylene glycol, about 15 to about 28 mole percent 1,4-cyclohexane-dimethanol, and about 7.5 to about 13 mole percent diethylene glycol. Further, the heat-shrinkable film may be produced to closely match the shrink characteristics of polyvinyl chloride by varying the amounts of the diol components of the reactor grade copolyester composition. Furthermore, a reactor grade copolyester composition has a b* color value of −1.0 to less than 4.5, wherein the diacid component is at least about 90 mole percent terephthalic acid and the diol component is about 52 to about 88 mole percent ethylene glycol, about 10 to about 28 mole percent 1,4-cyclohexane-dimethanol, and about 2 to about 20 mole percent diethylene glycol.

    摘要翻译： 反应物级共聚酯组合物以及由其制成的热收缩膜意外地具有比具有相同单体浓度的共聚酯的多组分共混物更高的延展性。 反应器级共聚酯组合物由至少约90摩尔％的二酸组分和（a）约72-约88摩尔％乙二醇，约10-约15摩尔％1,4-环己烷二甲醇的二醇组分和 约2至约13摩尔％的二甘醇，或（b）约59至约77.5摩尔％的乙二醇，约15至约28摩尔％的1,4-环己烷二甲醇和约7.5至约13摩尔％的二甘醇。 此外，可以通过改变反应器级共聚酯组合物的二醇组分的量来生产热收缩膜以与聚氯乙烯的收缩特性紧密匹配。 此外，反应器级共聚酯组合物的ab *颜色值为-1.0至小于4.5，其中二酸组分为至少约90摩尔％对苯二甲酸，二醇组分为约52-约88摩尔％乙二醇，约10 至约28摩尔％的1,4-环己烷二甲醇，和约2至约20摩尔％的二甘醇。

    Clarity and adjustable shrinkage of shrink films using miscible polyester blends
    5.
    发明授权
    Clarity and adjustable shrinkage of shrink films using miscible polyester blends 失效
    使用混溶聚酯混合物的收缩薄膜的澄清度和可调收缩率

    公开(公告)号：US5859116A

    公开(公告)日：1999-01-12

    申请号：US784614

    申请日：1997-01-21

    申请人： Wayne Ken Shih

    发明人： Wayne Ken Shih

    IPC分类号： B29C61/06 ,  B29K67/00 ,  B29L7/00 ,  C08J5/18 ,  C08K3/08 ,  C08K3/32 ,  C08K5/16 ,  C08L67/02 ,  C08L67/03 ,  C08K3/36 ,  C08G63/02

    CPC分类号： C08J5/18 ,  C08L67/02 ,  C08L67/025 ,  C08J2367/02

    摘要： A heat-shrinkable film is made from a copolyester blend of 1 to 98.5 weight percent PETG copolyester, 98.5 to 1 weight DEG modified PET copolyester having a b* value of less than 15, 0.5 to 3 weight percent anti-blocking agent, and optionally, 5 to 15 weight percent crystallizable polyester. The PETG copolyester has a dicarboxylic acid component of at least 95 mol percent terephthalic acid and a diol component of 65 to 80 mol percent ethylene glycol and 35 to 20 mol percent 1,4-cyclohexane-dimethanol. The DEG modified PET copolyester has a dicarboxylic acid component of at least 75 mol percent terephthalic acid; a diol component of 10 to 50 mol percent diethylene glycol and 50 to 90 mol percent ethylene glycol; catalyst residues of 20 to 100 ppm manganese, 50 to 300 ppm antimony, 0 to 100 ppm titanium and 40 to 150 ppm phosphorus; and color control agent residues of (i) 40 to 100 ppm cobalt, (ii) 1.5 to 10 ppm of blue compounds of substituted 1,4-bis(2,6-dialylanilino) anthraquinones and 0.5 to 6 ppm of red compounds of anthraquinones, or (iii) 0.5 to 10 ppm of 1-cyano-3H-dibenz isoquinoline-2,7-diones.

    摘要翻译： 热收缩膜由1至98.5重量％的PETG共聚酯，98.5至1重量％的改性PET共聚酯，其ab *值小于15重量％，0.5重量％至3重量％的防粘连剂，以及任选地， 5至15重量％的可结晶聚酯。 PETG共聚酯具有至少95摩尔％对苯二甲酸和二醇组分为65至80摩尔％乙二醇和35至20摩尔％1,4-环己烷二甲醇的二羧酸组分。 DEG改性PET共聚酯具有至少75mol％对苯二甲酸的二羧酸组分; 10至50mol％二甘醇和50至90mol％乙二醇的二醇组分; 20至100ppm锰的催化剂残余物，50至300ppm的锑，0至100ppm的钛和40至150ppm的磷; 和（i）40〜100ppm钴的颜色调节剂残留物，（ii）1.5〜10ppm的取代的1,4-双（2,6-二甲苯胺基）蒽醌的蓝色化合物和0.5〜6ppm的红色化合物的蒽醌 ，或（iii）0.5〜10ppm的1-氰基-3H-二苯并异喹啉-2,7-二酮。

    Plasticized polyester for shrink film applications
    6.
    发明授权
    Plasticized polyester for shrink film applications 失效
    用于收缩膜应用的增塑聚酯

    公开(公告)号：US5824398A

    公开(公告)日：1998-10-20

    申请号：US792123

    申请日：1997-01-31

    申请人： Wayne Ken Shih

    发明人： Wayne Ken Shih

    IPC分类号： B65B53/00 ,  B29C61/06 ,  B29K67/00 ,  B29L7/00 ,  C08J3/18 ,  C08J5/18 ,  C08K5/103 ,  C08L67/02 ,  B32B3/00 ,  C08F283/00 ,  C08G63/91

    CPC分类号： C08J5/18 ,  C08K5/103 ,  C08J2367/02 ,  Y10T428/24174 ,  Y10T428/24802 ,  Y10T428/249921 ,  Y10T428/29

    摘要： This invention relates to polyester/plasticizer blends which are useful as heat-shrinkable films or sheets in low temperature shrink packaging applications. The heat-shrinkable films or sheets comprise a blend of (A) 90 to 99 weight percent of a polyester having a glass transition temperature of 40.degree. C. to 150.degree. C. and an inherent viscosity of 0.5 to 1.2 dL/g and (B) 1 to 10 weight percent of a plasticizer selected from a C.sub.5 to C.sub.35 monoglyceride prepared from the reaction of glycerol and a fatty acid having 4 to 30 carbon atoms, wherein the combined weights of (A) and (B) total 100 percent. The polyester comprises a dicarboxylic acid component comprising repeat units from at least 80 mole percent of an aromatic dicarboxylic acid having 8 to 14 carbon atoms and a diol component comprising repeat units from at least 10 mole percent of 1,4-cyclohexanedimethanol, based on 100 mole percent dicarboxylic acid and 100 mole percent diol.

    摘要翻译： 本发明涉及在低温收缩包装应用中可用作热收缩膜或片材的聚酯/增塑剂共混物。 热收缩膜或片材包含（A）90至99重量％的玻璃化转变温度为40℃至150℃，特性粘度为0.5至1.2dL / g的聚酯和（ B）1至10重量％的选自由甘油和具有4至30个碳原子的脂肪酸反应制备的C5至C35单甘油酯的增塑剂，其中（A）和（B）的总重量为100％。 聚酯包含二羧酸组分，其包含至少80摩尔％的具有8至14个碳原子的芳族二羧酸的重复单元和包含至少10摩尔％1,4-环己烷二甲醇的重复单元的二醇组分，基于100 摩尔百分比的二羧酸和100摩尔％的二醇。

    Method of determining a thermoforming process window of a thermoplastic material
    7.
    发明授权
    Method of determining a thermoforming process window of a thermoplastic material 失效
    确定热塑性材料的热成型工艺窗口的方法

    公开(公告)号：US5709825A

    公开(公告)日：1998-01-20

    申请号：US636747

    申请日：1996-04-19

    申请人： Wayne Ken Shih

    发明人： Wayne Ken Shih

    IPC分类号： B29C51/00 ,  B29C51/08 ,  B29C51/46 ,  B29K67/00 ,  B29K69/00

    CPC分类号： B29C51/46 ,  B29C51/00 ,  B29C51/082 ,  B29K2033/12 ,  B29K2067/00 ,  B29K2069/00

    摘要： A thermoforming process window of a rectangular sheet of a thermoplastic material is determined by calculating its Sag Number during heating. The Sag Number is a function of the sheets length, width and apex depth at the center of sag. Upon the Sag Number being between 10 and 40, preferably 15 and 35, and more preferably 19 and 28, the sheet is ready for forming into an end product.

    摘要翻译： 通过在加热期间计算其下垂数来确定热塑性材料的矩形片材的热成型工艺窗口。 凹陷数是下垂中心的片材长度，宽度和顶点深度的函数。 当凹陷数在10至40之间时，优选15和35，更优选19和28，所述片准备好形成最终产品。