Methods for producing crosslinkable silyl group-containing polyoxyalkylene polymers
    6.
    发明授权
    Methods for producing crosslinkable silyl group-containing polyoxyalkylene polymers 有权
    制备交联性含甲硅烷基的聚氧化烯聚合物的方法

    公开(公告)号:US08916669B2

    公开(公告)日:2014-12-23

    申请号:US13696918

    申请日:2011-05-26

    摘要: Embodiments of the invention provide for a method of producing a silylated polyoxyalkylene polymer having at least one crosslinkable silyl group and at least one hydroxyl group in each molecule. The method comprises providing a polyoxyalkylene polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule, wherein the polyoxyalkylene polymer includes an impurity double metal cyanide complex mixed therein, and wherein the polyoxyalkylene polymer has not been treated with a metal-coordinating compound; and adding to the polyoxyalkylene polymer a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule and a hydrosilylation catalyst to thereby carry out a hydrosilylation reaction, wherein the hydrosilyation reaction is performed in an absence of a metal-coordinating compound.

    摘要翻译: 本发明的实施方案提供了在每个分子中具有至少一个交联性甲硅烷基和至少一个羟基的甲硅烷基化聚氧化烯聚合物的制备方法。 该方法包括提供在每个分子中具有至少一个不饱和基团和至少一个醇羟基的聚氧化烯聚合物,其中所述聚氧化烯聚合物包含混合在其中的杂质双金属氰化物络合物,并且其中所述聚氧化烯聚合物未被金属处理 配位化合物 并且在每个分子中加入具有氢硅键和交联性甲硅烷基的化合物和氢化硅烷化催化剂,从而进行氢化硅烷化反应,其中在不存在金属配位化合物的情况下进行氢化反应。

    PROCESS FOR MAKING ALKOXYLATED PIPERAZINE COMPOUNDS
    7.
    发明申请
    PROCESS FOR MAKING ALKOXYLATED PIPERAZINE COMPOUNDS 有权
    制备烷氧基哌嗪化合物的方法

    公开(公告)号:US20140256944A1

    公开(公告)日:2014-09-11

    申请号:US14238338

    申请日:2012-08-24

    IPC分类号: C07D295/088

    CPC分类号: C07D295/088 C07D241/04

    摘要: The present invention relates to an improved process for making mono- and di-alkoxylated piperazine compounds especially dihydroxyethylpiperazine. The improvement comprises the addition of an acid to the piperazine compound prior to the addition of an alkylene oxide to a reactor wherein the alkoxylated piperazine compound is prepared. Said improvement reduces the concentration of undesirable glycol ether byproducts which contribute undesirable color and foaming of the alkoxylated piperazine compounds.

    摘要翻译: 本发明涉及制备单 - 和二 - 烷氧基化哌嗪化合物,特别是二羟基乙基哌嗪的改进方法。 改进之处在于在将氧化烯加成到制备烷氧基化哌嗪化合物的反应器中之前向哌嗪化合物中加入酸。 所述改进降低了不希望的乙二醇醚副产物的浓度,这促成了烷氧基化哌嗪化合物的不希望有的颜色和起泡性。

    Process for making alkoxylated piperazine compounds
    10.
    发明授权
    Process for making alkoxylated piperazine compounds 有权
    制备烷氧基化哌嗪化合物的方法

    公开(公告)号:US09169222B2

    公开(公告)日:2015-10-27

    申请号:US14238338

    申请日:2012-08-24

    IPC分类号: C07D295/088 C07D241/04

    CPC分类号: C07D295/088 C07D241/04

    摘要: The present invention relates to an improved process for making mono- and di-alkoxylated piperazine compounds especially dihydroxyethylpiperazine. The improvement comprises the addition of an acid to the piperazine compound prior to the addition of an alkylene oxide to a reactor wherein the alkoxylated piperazine compound is prepared. Said improvement reduces the concentration of undesirable glycol ether byproducts which contribute undesirable color and foaming of the alkoxylated piperazine compounds.

    摘要翻译: 本发明涉及制备单 - 和二 - 烷氧基化哌嗪化合物,特别是二羟基乙基哌嗪的改进方法。 改进之处在于在将氧化烯加成到制备烷氧基化哌嗪化合物的反应器中之前向哌嗪化合物中加入酸。 所述改进降低了不希望的乙二醇醚副产物的浓度,这促成了烷氧基化哌嗪化合物的不希望有的颜色和起泡性。