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1.发明授权Dental compositions comprising acrylic esters of tricyclo [5.2.1.0.sup.2,6 ] decane polymers 失效牙科组合物包含三环{8 5.2.1.0 {hu 2,6 {b {9癸烷聚合物
公开(公告)号：US4131729A
公开(公告)日：1978-12-26
申请号：US898680
申请日：1978-04-21
IPC分类号： A61K6/083 , C08F120/30 , C08F32/08 , C08F4/34 , C08F122/10 , C08F132/08
CPC分类号： A61K6/083 , C08F120/30 , Y10S522/908 , Y10S528/92
摘要： An improved dental composition having shortened hardening time and after hardening increased compressive strength and abrasion resistance, including a radical-inducing compound and a polymerizable acrylic or methacrylic acid ester or diester compound with at least 20 percent by weight of the polymerizable compound being the diacrylic or dimethacrylic acid ester of bishydroxymethyltricyclo [5.2.1.0.sup.2,6 ]-decane. Other monofunctional or difunctional acrylic or methacrylic acid esters as well as fillers, pigments and stabilizers can be included.
摘要翻译： 具有缩短的硬化时间和硬化后的改进的牙科组合物增加抗压强度和耐磨性，包括自由基诱导化合物和可聚合的丙烯酸或甲基丙烯酸酯或二酯化合物，其中至少20重量％的可聚合化合物是二丙烯酸或 双羟甲基三环[5.2.1.02,6] - 癸烷二甲基丙烯酸酯。 可以包括其它单官能或双官能的丙烯酸或甲基丙烯酸酯以及填料，颜料和稳定剂。
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公开(公告)号：US4093555A
公开(公告)日：1978-06-06
申请号：US756925
申请日：1977-01-04
IPC分类号： A61C9/00 , A61C13/34 , A61K6/087 , C07D203/08 , C08G73/02 , C08L79/02 , C09K3/00 , A61C13/08 , A61C13/22
CPC分类号： C08L79/02 , A61C9/00 , A61K6/087 , C07D203/08 , C08G73/024 , Y10S528/92
摘要： Novel bromine-containing compounds of the formula ##STR1## in which R is an alkylidene radical having 1 to 6 carbon atoms, a cycloalkylidene radical or a SO.sub.2 radical, R' is an alkylene radical having 2 to 6 carbon atoms or a cycloalkylene radical and Y is an acyl radical of a carboxylic acid having 2 to 6 carbon atoms and optionally bearing an aromatic substituent, and x is 1 or 2 and y is 0, 1 or 2, which are particularly useful for the preparation of dental replacement parts and dental models when mixed with a substance that catalyzes the polymerization of the compounds.
摘要翻译： 其中R是具有1至6个碳原子的亚烷基，环烷叉基或SO 2基团的新颖的含溴化合物，其中R'是具有2-6个碳原子的亚烷基 或亚环烷基，Y是具有2至6个碳原子并且任选带有芳族取代基的羧酸的酰基，x是1或2，y是0,1或2，这对制备 当与催化化合物的聚合的物质混合时，牙科替代部件和牙科模型。
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3.发明授权(Meth)acrylic acid esters and the use thereof for preparing dental compositions 失效（甲基）丙烯酸酯及其制备牙科用组合物的用途
公开(公告)号：US4795823A
公开(公告)日：1989-01-03
申请号：US20902
申请日：1987-03-02
申请人： Werner Schmitt , Peter Jochum , Wolf-Dietrich Zahler , Heijo Hubner , Manfred Holupirek , Oswald Gasser , Christian Herzig
发明人： Werner Schmitt , Peter Jochum , Wolf-Dietrich Zahler , Heijo Hubner , Manfred Holupirek , Oswald Gasser , Christian Herzig
IPC分类号： C07C69/708 , A61K6/08 , A61K6/083 , C08F20/10 , C08F20/26 , C08F20/28 , C08F220/28 , C07C69/66
CPC分类号： A61K6/083 , Y10S522/908
摘要： (Methy)acrylic acid esters of the general formula(Mo).sub.n --[--A--O--CO--CH.sub.2 --O--CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CO--O--].sub.x --A--(OM).sub.nare described whereinA is an alcohol radical having at least 4 chain atoms between two junction sites.M is CH.sub.2 .dbd.C(R.sup.1)--CO wherein R.sup.1 stands for hydrogen or methyl,n is 1 or 2, andx is 0.3 to 3.These esters are suited for the preparation of dental compositions.
摘要翻译： （Mo）n - [ - AO-CO-CH2-O-CH2-CH2-O-CH2-CO-O-] xA（OM）n的（甲基）丙烯酸酯，其中A是 在两个连接位点之间具有至少4个链原子的醇基。 M为CH 2 = C（R 1）-CO，其中R 1代表氢或甲基，n为1或2，x为0.3至3.这些酯适于制备牙科用组合物。
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4.发明授权1,2,6-Thiadiazine-3,5-dione-1,1-dioxides and their use as polymerization accelerators 失效1,2,6-噻二嗪-3,5-二酮-1,1-二氧化物及其作为聚合促进剂的用途
公开(公告)号：US4443587A
公开(公告)日：1984-04-17
申请号：US349769
申请日：1982-02-18
IPC分类号： A61K6/083 , C07D285/16 , C08F2/38 , C08F2/40 , C08F4/00 , C08F4/28 , C08F4/32 , C08F4/40 , C08F20/12 , C08F20/20
CPC分类号： C07D285/16 , A61K6/083 , C08F2/40
摘要： 1,2,6-Thiadiazine-3,5-dione-1,1-dioxides of the general formula ##STR1## wherein each R and R.sub.3 independently may be substituted or unsubstituted alkyl, alkenyl or substituted cycloalkyl are described. These compounds, as well as those wherein the R substituents additionally may be cycloalkyl or substituted or unsubstituted aryl, are useful as accelerators for the peroxidic polymerization of ethylenically unsaturated compounds, such as methacrylic acid compounds, and have particular utility in dental compositions.
摘要翻译： 描述了通式为“IMAGE”的1,2,6-噻二嗪-3,5-二酮-1,1-二氧化物，其中R和R 3各自独立地可以是取代或未取代的烷基，烯基或取代的环烷基。 这些化合物以及其中R取代基可以是环烷基或取代或未取代的芳基的化合物可用作烯属不饱和化合物如甲基丙烯酸化合物的过氧化聚合的促进剂，并且在牙科用组合物中具有特别的用途。
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公开(公告)号：US4389497A
公开(公告)日：1983-06-21
申请号：US285115
申请日：1981-07-22
CPC分类号： A61K6/083 , C09C1/3036 , C01P2004/50
摘要： The invention relates to the use of agglomerates of silicic acid having an average agglomerate size of 0.5 to 50 .mu.m, containing primary particles of silicic acid having an average particle size of 1 to 100 nm and serving as filler in dental materials on the basis of ethylenically unsaturated polymerizable monomers. This reinforcing filler is practically colorless and can be blended in considerable quantity into the polymerizable monomer material especially mono-functional and di-functional as well as polyfunctional esters of the acrylic acid and the methacrylic acid and yields a satisfactorily processable plastically deformable paste. If necessary, the agglomerated silicic acid is used together with non-agglomerated micro-fine silicic acid of an average particle size of 1 to 100 nm. The shaped bodies obtained after the curing of the polymerizable material with the fillers show superior compressive strength, low thermal expansion, high colour stability and low water absorption, and moreover can be finished to high luster. The agglomerated fillers provided according to the invention are generally suitable for tooth filling preparations and tooth restoration materials as well as for the production of artificial teeth.
摘要翻译： PCT No.PCT / EP80 / 00135 Sec。 371日期1981年7月22日 102（e）日期1981年7月22日PCT提交1980年11月21日PCT公布。 第WO81 / 01366号公报 日期：1981年5月28日本发明涉及平均粒度为0.5〜50μm的硅酸附聚物，其含有平均粒径为1〜100nm的硅酸一次粒子，作为填料使用 基于烯属不饱和可聚合单体的牙科材料。 该增强填料实际上是无色的，并且可以大量掺入可聚合单体材料中，特别是单官能和二官能以及丙烯酸和甲基丙烯酸的多官能酯，并产生令人满意的可加工的可塑性变形的糊剂。 必要时，将聚集的硅酸与平均粒径为1〜100nm的非凝集微细硅酸一起使用。 可聚合材料固化后获得的成型体具有优异的抗压强度，低热膨胀性，高颜色稳定性和低吸水性，而且可以完成高光泽度。 根据本发明提供的凝聚填料通常适用于牙齿填充制剂和牙齿修复材料以及用于生产人造牙齿。
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6.发明授权
公开(公告)号：US4067853A
公开(公告)日：1978-01-10
申请号：US601689
申请日：1975-08-01
IPC分类号： A61K6/083 , C08F20/20 , C08F120/38 , C08F20/38 , C08F20/30
CPC分类号： C08F120/38 , A61K6/083 , C08F20/20 , Y10S528/92
摘要： Superior artificial teeth, dentures, other dental replacement parts and dental prosthetic articles and devices, which exhibit high abrasion resistance, stability to moisture and which do not undergo volume changes, are obtained by polymerization of a compound of the formula ##STR1## in which R is H or -CH.sub.3, X is an alkylidene or the -SO.sub.2 -group, Y is an oxyalkylene group having between 2 and 5 carbon atoms, or an alkylidene group having between 1 and 5 carbon atoms. In some instances, the polymerization is carried out in the presence of a filler.
摘要翻译： 通过聚合下式的化合物获得优异的人造牙齿，假牙，其他牙齿替代部件和表现出高耐磨性，水分稳定性和不经历体积变化的牙科修复物品和装置，其中R 是H或-CH 3，X是亚烷基或-SO 2 - 基团，Y是具有2至5个碳原子的氧化烯基团或具有1至5个碳原子的亚烷基基团。 在一些情况下，聚合在填料存在下进行。
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公开(公告)号：US4493911A
公开(公告)日：1985-01-15
申请号：US559703
申请日：1983-12-09
申请人： Werner Schmitt , Robert Purrmann , Peter Jochum
发明人： Werner Schmitt , Robert Purrmann , Peter Jochum
摘要： Impression materials based on cross-linked aziridino-polyester compounds which tend to adhere to the surface to be reproduced, are made nonadhesive by the addition of 1-15% by weight of oleic acid ethanolamide with respect to the aziridino-polyether component, and may thereafter be more easily and smoothly released from the object to be reproduced.
摘要翻译： 通过加入1-15重量％的油酸乙醇酰胺相对于氮丙啶基 - 聚醚组分，易于粘附在待再现表面上的交联氮丙啶 - 聚酯化合物的印模材料制成非粘合剂，并且可以 此后可以更容易地从被再现的对象中顺利地释放出来。
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公开(公告)号：US3986998A
公开(公告)日：1976-10-19
申请号：US404886
申请日：1973-10-10
CPC分类号： A61K6/0612 , A61K6/0835 , C08K3/34
摘要： Dental cements are prepared by mixing a silicate powder with an aqueous solution of polymers of unsaturated alpha, beta-dicarboxylic acids.
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公开(公告)号：US4544742A
公开(公告)日：1985-10-01
申请号：US573391
申请日：1984-02-28
CPC分类号： C07D285/16 , A61K6/083 , C08F2/40
摘要： 1,2,6-Thiadiazine-3,5-dione-1,1-dioxides of the general formula ##STR1## wherein each R and R.sub.3 independently may be substituted or unsubstituted alkyl, alkenyl or substituted cycloalkyl are described. These compounds, as well as those wherein the R substituents additionally may be cycloalkyl or substituted or unsubstituted aryl, are useful as accelerators for the peroxidic polymerization of ethylenically unsaturated compounds, such as methacrylic acid compounds, and have particular utility in dental compositions.
摘要翻译： 描述了通式为“IMAGE”的1,2,6-噻二嗪-3,5-二酮-1,1-二氧化物，其中R和R 3各自独立地可以是取代或未取代的烷基，烯基或取代的环烷基。 这些化合物以及其中R取代基可以是环烷基或取代或未取代的芳基的化合物可用作烯属不饱和化合物如甲基丙烯酸化合物的过氧化聚合的促进剂，并且在牙科用组合物中具有特别的用途。
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10.发明授权
公开(公告)号：US4372836A
公开(公告)日：1983-02-08
申请号：US185903
申请日：1979-07-31
CPC分类号： A61K6/083
摘要： An improved opaque, photopolymerizable dental filling material is provided comprised of acrylic acid ester compounds containing mono and/or polyfunctional acrylic or methacrylic ester compounds, photoinitiators, pigments and possibly activators and silicon dioxide or silicate fillers, the improvement comprising the presence of finely divided calcium fluoride as a white pigment in a quantity of from 1-20 percent by weight. The presence of the calcium fluoride enables an opaque effect to be achieved without reducing the permeability of the filling material to polymerization radiation.
摘要翻译： PCT No.PCT / DE79 / 00001 Sec。 371日期1979年7月31日 102（e）1979年7月31日PCT 2007年1月2日PCT。提供改进的不透明光聚合牙科填充材料，其包含含有单和/或多官能丙烯酸或甲基丙烯酸酯化合物的丙烯酸酯化合物，光引发剂，颜料和 可能的活化剂和二氧化硅或硅酸盐填料，改进包括以1-20重量％的量存在细分散的白色颜料的氟化钙。 氟化钙的存在使得能够实现不透明效果而不降低填充材料对聚合辐射的渗透性。
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