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    Asymmetric aryl phosphites
    2.
    发明授权
    Asymmetric aryl phosphites 失效
    不对称芳基亚磷酸酯

    公开(公告)号：US5401845A

    公开(公告)日：1995-03-28

    申请号：US212756

    申请日：1994-03-11

    申请人： Rita Pitteloud ,  Peter Hofmann ,  Rudolf Maul ,  Volker Schenk ,  Eduard Troxler ,  Horst Zinke

    发明人： Rita Pitteloud ,  Peter Hofmann ,  Rudolf Maul ,  Volker Schenk ,  Eduard Troxler ,  Horst Zinke

    IPC分类号： C07F9/145 ,  C07F9/146 ,  C07F9/59 ,  C08K5/52 ,  C08K5/526 ,  C08K5/529 ,  C08L23/00 ,  C08L101/00

    CPC分类号： C08K5/526 ,  C07F9/145 ,  C07F9/146 ,  C07F9/591 ,  C07F9/595

    摘要： Compounds of the formula I ##STR1## in which x is 1, 2 or 3, and, if x=1, R.sup.1 is C.sub.1 -C.sub.30 alkyl, C.sub.1 -C.sub.18 alkyl substituted by halogen, --COOR.sup.2, --CN, --NR.sup.3 R.sup.4 or by --CONR.sup.3 R.sup.4, C.sub.2 -C.sub.18 alkyl which is interrupted by --NR.sup.5 --, --O-- or --S--, C.sub.3 -C.sub.18 alkenyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl-C.sub.1 -C.sub.4 alkyl, phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.12 alkyl, halogen, phenyl-C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, or R.sub.1 is naphthyl, a radical of the formula ##STR2## R.sub.2, R.sub.3, R.sub.4 and R.sub.5, independently of one another, are hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl or phenyl-C.sub.1 -C.sub.4 alkyl, R.sup.6 is hydrogen, methyl, allyl or benzyl, R.sup.7 is hydrogen or --OR.sup.9, R.sup.8 is hydrogen or methyl, R.sup.9 is hydrogen or C.sub.1 -C.sub.30 alkyl, R.sup.10 and R.sup.11, independently of one another, are hydrogen or C.sub.1 -C.sub.8 alkyl, and n is 3-6, with the proviso that R.sup.1 is not a phenyl radical which is substituted in both ortho-positions to the carbon atom bonded to the oxygen atom,if x=2, R.sup.1 is C.sub.2 -C.sub.18 alkylene, C.sub.2 -C.sub.18 alkylene which is interrupted by --NR.sup.5, --O-- or --S--, or is a ##STR3## radical, and, if x=3, R.sup.1 is C.sub.4 -C.sub.12 alkanetriyl or a ##STR4## group in which m is 1-4, are suitable as stabilizers for organic materials which are sensitive to thermal, oxidative and/or photoinduced degradation.

    摘要翻译： 式I的化合物（I）其中x为1,2或3，如果x = 1，则R1为C1-C30烷基，被卤素取代的C1-C18烷基，-COOR2，-CN，-NR3R4或 被-CONR 3 R 4，被-NR 5 - ，-O-或-S-，C 3 -C 18烯基，C 5 -C 12环烷基，苯基-C 1 -C 4烷基，未被取代或被C 1 -C 12烷基取代的苯基，卤素， 苯基-C 1 -C 4烷基和/或C 1 -C 4烷氧基，或者R 1为萘基，R 2，R 3，R 4和R 5彼此独立地为氢，C 1 -C 18烷基， C 1 -C 12烷基或苯基-C 1 -C 4烷基，R 6是氢，甲基，烯丙基或苄基，R 7是氢或-OR 9，R 8是氢或甲基，R 9是氢或C 1 -C 30烷基，R 10和R 11彼此独立地是氢 或C 1 -C 8烷基，n为3-6，条件是R 1不是在与氧原子键合的碳原子的两个邻位被取代的苯基，如果x = 2，则R1为C2-C18亚烷基 被-NR 5，-O-或-S-中断的C 2 -C 18亚烷基，或者是a 如果x = 3，则R 1为C 4 -C 12烷基三乙基或其中m为1-4的基团，适用于对热，氧化和/或光诱导降解敏感的有机材料的稳定剂 。

    Asymmetric aryl phosphites
    3.
    发明授权
    Asymmetric aryl phosphites 失效
    不对称芳基亚磷酸酯

    公开(公告)号：US5322871A

    公开(公告)日：1994-06-21

    申请号：US49647

    申请日：1993-04-20

    申请人： Rita Pitteloud ,  Peter Hofmann ,  Rudolf Maul ,  Volker Schenk ,  Eduard Troxler ,  Horst Zinke

    发明人： Rita Pitteloud ,  Peter Hofmann ,  Rudolf Maul ,  Volker Schenk ,  Eduard Troxler ,  Horst Zinke

    IPC分类号： C07F9/145 ,  C07F9/146 ,  C07F9/59 ,  C08K5/52 ,  C08K5/526 ,  C08K5/529 ,  C08L23/00 ,  C08L101/00

    CPC分类号： C08K5/526 ,  C07F9/145 ,  C07F9/146 ,  C07F9/591 ,  C07F9/595

    摘要： Compounds of the formula I ##STR1## in which x is 1, 2 or 3, and, if x=1, R.sup.1 is C.sub.1 -C.sub.30 alkyl, C.sub.1 -C.sub.18 alkyl substituted by halogen, --COOR.sup.2, --CN, --NR.sup.3 R.sup.4 or by --CONR.sup.3 R.sup.4, C.sub.2 -C.sub.18 alkyl which is interrupted by --NR.sup.5 --, --O-- or --S--, C.sub.3 -C.sub.18 alkenyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl-C.sub.1 -C.sub.4 alkyl, phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.12 alkyl, halogen, phenyl-C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, or R.sub.1 is naphthyl, a radical of the formula ##STR2## R.sub.2, R.sub.3, R.sub.4 and R.sub.5, independently of one another, are hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl or phenyl-C.sub.1 -C.sub.4 alkyl, R.sup.6 is hydrogen, methyl, allyl or benzyl, R.sup.7 is hydrogen or --OR.sup.9, R.sup.8 is hydrogen or methyl, R.sup.9 is hydrogen or C.sub.1 -C.sub.30 alkyl, R.sup.10 and R.sup.11, independently of one another, are hydrogen or C.sub.1 -C.sub.8 alkyl, and n is 3-6, with the proviso that R.sup.1 is not a phenyl radical which is substituted in both ortho-positions to the carbon atom bonded to the oxygen atom, if x=2, R.sup.1 is C.sub.2 -C.sub.18 alkylene, C.sub.2 -C.sub.18 alkylene which is interrupted by --NR.sup.5 --, --O-- or --S--, or is a ##STR3## radical, and, if x=3, R.sup.1 is C.sub.4 -C.sub.12 alkanetriyl or a ##STR4## group in which m is 1-4, are suitable as stabilisers for organic materials which are sensitive to thermal, oxidative and/or photoinduced degradation.

    摘要翻译： 式I的化合物（I）其中x为1,2或3，如果x = 1，则R1为C1-C30烷基，被卤素取代的C1-C18烷基，-COOR2，-CN，-NR3R4或 被-CONR 3 R 4，被-NR 5 - ，-O-或-S-，C 3 -C 18烯基，C 5 -C 12环烷基，苯基-C 1 -C 4烷基，未被取代或被C 1 -C 12烷基取代的苯基，卤素， 苯基-C 1 -C 4烷基和/或C 1 -C 4烷氧基，或者R 1为萘基，R 2，R 3，R 4和R 5彼此独立地为氢，C 1 -C 18烷基， C 1 -C 12烷基或苯基-C 1 -C 4烷基，R 6是氢，甲基，烯丙基或苄基，R 7是氢或-OR 9，R 8是氢或甲基，R 9是氢或C 1 -C 30烷基，R 10和R 11彼此独立地是氢 或C 1 -C 8烷基，n为3-6，条件是R 1不是在与氧原子键合的碳原子的两个邻位被取代的苯基，如果x = 2，则R1为C2-C18亚烷基 被-NR 5 - ，-O-或-S-中断的C 2 -C 18亚烷基，或者是a 如果x = 3，则R 1为C 4 -C 12烷基三乙基或其中m为1-4的基团，适用于对热，氧化和/或光诱导降解敏感的有机材料的稳定剂 。

    Novel 1,2-diaza-1,5,9-cyclo dodecatrienes and 1,2-diaza-1-cyclododecenes
    4.
    发明授权
    Novel 1,2-diaza-1,5,9-cyclo dodecatrienes and 1,2-diaza-1-cyclododecenes 失效
    新的1,2-二氮杂-1,5,9-环十二碳烯和1,2-二氮杂-1-环十二碳烯

    公开(公告)号：US3939147A

    公开(公告)日：1976-02-17

    申请号：US370081

    申请日：1973-06-14

    申请人： Bernard Hugelin ,  Eduard Troxler

    发明人： Bernard Hugelin ,  Eduard Troxler

    IPC分类号： A01N43/62 ,  C07D245/02 ,  C07D405/04 ,  C07D405/10 ,  C07D405/14

    CPC分类号： C07D245/02

    摘要： New unsaturated 1,2-diazacyclododecanes, more particularly 1,2-diazacyclododecatrienes-1,5,9 and 1,2-diazacyclododecanes-1 and a novel process for the preparation thereof are disclosed which process comprises reacting a 1,3-diolefin with an azine in the presence of certain nickel catalysts. Said process unexpectedly yields 12-membered ring compounds only, and more especially oligomerization products of 2 mols of a 1,3-diolefin and 1 mol of an azine, while deactivation of the nickel catalyst by the -N=N-bond is avoided.

    摘要翻译： 公开了新的不饱和1,2-二氮杂环十二烷，更特别是1,2-二氮杂环十二碳二烯-1,5,9和1,2-二氮杂环十二烷-1及其制备方法，该方法包括使1,3-二油烯与 在某些镍催化剂存在下的吖嗪。 所述方法意外地仅产生12元环化合物，更特别地是2摩尔1,3-二烯烃和1摩尔吖嗪的低聚产物，同时避免了由-N = N-键失活镍催化剂。

    Process for the preparation of sterically hindered hydroxphenylcarboxylic acid esters
    5.
    发明授权
    Process for the preparation of sterically hindered hydroxphenylcarboxylic acid esters 失效
    空间位阻羟基羧酸酯的制备方法

    公开(公告)号：US4536593A

    公开(公告)日：1985-08-20

    申请号：US510705

    申请日：1983-07-05

    申请人： Ivan Orban ,  Eduard Troxler

    发明人： Ivan Orban ,  Eduard Troxler

    IPC分类号： C07C67/03 ,  B01J21/16 ,  B01J29/00 ,  B01J31/12 ,  C07B61/00 ,  C07C67/00 ,  C07C69/003 ,  C07C69/732 ,  C07C69/88 ,  C07C313/00 ,  C07C323/12 ,  C07C69/76

    CPC分类号： C07C69/732 ,  C07C69/88

    摘要： If the transesterification of esters of the formula ##STR1## with alcohols of the formula III A--(OH).sub.m is catalyzed by successive treatment with catalytic amounts (a) of a tin compound of a metal of the fourth main group or the fourth sub-group of the periodic system and (b) of an acid earth, compounds of the formula I ##STR2## are obtained in virtually quantitative yield. The products thus obtained contain no troublesome by-products and do not have to be additionally purified.R is methyl or ethyl, A is a radical derived from an m-hydric aliphatic alcohol, n is 0 to 2, and m is 1 to 4.

    摘要翻译： 如果通过用催化量（a）第四主族的金属的锡化合物或第四主体的第四主体的连续处理来催化式II-（OH）m的醇的酯交换， 周期性系统的亚组和（b）酸性土，以几乎定量的产率获得式I“IMAGE”的化合物。 由此获得的产品不含麻烦的副产物，不必另外纯化。 R为甲基或乙基，A为衍生自间二羟基脂肪醇的基团，n为0〜2，m为1〜4。

    Process for the preparation of polyesters from aliphatic dicarboxylic acids and polyalkylpiperidyl diols
    7.
    发明授权
    Process for the preparation of polyesters from aliphatic dicarboxylic acids and polyalkylpiperidyl diols 失效
    从脂族二羧酸和聚烷基哌啶二醇制备聚酯的方法

    公开(公告)号：US4535145A

    公开(公告)日：1985-08-13

    申请号：US626507

    申请日：1984-06-29

    申请人： Eduard Troxler ,  Thomas Kainmuller ,  Rudolf Maul

    发明人： Eduard Troxler ,  Thomas Kainmuller ,  Rudolf Maul

    IPC分类号： C08G63/00 ,  C08G63/66 ,  C08G63/68 ,  C08G63/685 ,  C08G63/688 ,  C08G63/82 ,  C08G63/85 ,  C08G73/06 ,  C08G63/44 ,  C08G73/16

    CPC分类号： C08G63/6856 ,  C08G63/85

    摘要： The invention relates to a novel process for the preparation of compounds of the formula I ##STR1## by polycondensation of a diol of the formula II ##STR2## with a dicarboxylic acid ester of the formula III ##STR3## In the above formulae, the substituents and symbols R.sub.1, R.sub.2, R.sub.3 and n are as defined in claim 1.The process comprises stirring the reaction medium which contains an excess of 2 to 50 mol. %, based on the diol of formula II, of the dicarboxylic acid ester of the formula III, in the presence of at least 0.03 mol. % of a suitable catalyst, until the bulk of the alkanol of the formula R.sub.3 OH formed during the reaction is distilled off, under a pressure of 0.7 to 1.3 bar, and thereafter stirring under a pressure of less than 5 mbar, in the temperature range from 100.degree. to 170.degree. C., and subsequently working up the resultant melt in conventional manner.

    摘要翻译： 本发明涉及通过式II（Ⅱ）的二醇与式III的二羧酸酯缩合制备式I化合物（I）的新方法（IMAGE III）在上式中，取代基和符号R1，R2，R3和n如权利要求1中所定义。该方法包括搅拌含有过量2-50mol的反应介质。 ％，基于式II的二元醇，式III的二羧酸酯在至少0.03mol的存在下反应。 ％的合适的催化剂，直到在反应中形成的式R3OH的烷醇的主体在0.7至1.3巴的压力下蒸馏出，然后在小于5毫巴的压力下搅拌，温度范围为 100℃至170℃，然后以常规方式处理所得的熔体。

    Quaternized 1-(pyrazolinylphenylsulphonyl)-piperazines
    10.
    发明授权
    Quaternized 1-(pyrazolinylphenylsulphonyl)-piperazines 失效
    季铵化的1-（吡唑啉基苯基磺酰基） - 哌嗪

    公开(公告)号：US4151163A

    公开(公告)日：1979-04-24

    申请号：US857725

    申请日：1977-12-05

    申请人： Eduard Troxler ,  Christian Luthi

    发明人： Eduard Troxler ,  Christian Luthi

    IPC分类号： D06L3/12 ,  G03C1/815 ,  G03G5/06 ,  H01S3/213 ,  C07D241/50

    CPC分类号： H01S3/213 ,  D06L3/12 ,  G03C1/8155 ,  G03G5/0661

    摘要： (Pyrazolinylphenylsulfonyl)-piperazines of the formula ##STR1## wherein R.sub.1 is unsubstituted or substituted alkyl, aralkyl or alkenyl, R.sub.2 is unsubstituted or substituted alkyl, aryl or aralkyl R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 are certain substituents and Y is an anion, their preparation as well as their use as optical brighteners are disclosed.

    摘要翻译： （吡唑啉基苯基磺酰基） - 哌嗪，其中R1是未取代或取代的烷基，芳烷基或烯基，R2是未取代或取代的烷基，芳基或芳烷基R3，R4，R5，R6，R7和R8是某些取代基，Y是 公开了阴离子，它们的制备以及它们作为荧光增白剂的用途。