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公开(公告)号：US4740645A
公开(公告)日：1988-04-26
申请号：US903915
申请日：1986-09-05
CPC分类号： C10G50/00 , C07C11/02 , C07C2/12 , C07C2529/46 , Y02P20/52
摘要： A continuous multi-stage catalytic process for converting ethene-rich lower olefinic feedstock to heavier liquid hydrocarbon product, comprising the steps ofcontacting ethene-rich feedstock at elevated temperature and moderate pressure in a primary stage reaction zone with a first catalyst comprising shape selective medium pore zeolite to convert at least a portion of the lower olefinic components to intermediate olefinic hydrocarbons;cooling primary stage reaction effluent by introducing a stream of cold water sufficient to reduce the primary stage effluent to second stage reaction temperature; andcontacting unreacted ethene and at least a portion of the intermediate olefinic hydrocarbons from the primary stage with nickel-containing shape selective medium pore zeolite oligomerization component at elevated temperature to provide a heavier hydrocarbon effluent stream comprising gasoline and/or distillate range hydrocarbons.
摘要翻译： 一种用于将含富烯烃的较低级烯烃原料转化为较重液体烃产物的连续多级催化方法，包括以下步骤：在初级阶段反应区中将升温和中等压力的富含烯烃的原料与包含形状选择介质 孔沸石将至少一部分低级烯烃组分转化成中间体烯烃; 通过引入足以将初级阶段流出物降至第二阶段反应温度的冷水流来冷却初级反应流出物; 并在升高的温度下使未反应的乙烯和至少一部分来自初级阶段的中间体烯烃与含镍形状选择性中孔沸石低聚组分接触，以提供包含汽油和/或馏出物范围烃的较重烃流出物流。
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2.发明授权Multistage system for conversion of lower olefins with reactor quenching means 失效用反应器淬火方法转化低级烯烃的多级体系
公开(公告)号：US4942021A
公开(公告)日：1990-07-17
申请号：US137224
申请日：1987-12-23
摘要： A continuous multistage catalytic conversion system for upgrading lower olefins comprisingfirst adaibatic catalytic bed reactor means containing an acidic zeolite solid catalyst;means for feeding light olefinic gas directly to the first reactor without addition of separate diluent or recycle streams;means for operating the first reactor under olefin partial conversion conditions at elevated temperature to control adiabatic temperature increase;interstage quench means for injecting a liquid coolant directly into first stage effluent for reducing the temperature thereof and protecting downstream catalyst;second catalytic bed reactor means for receiving cooled first stage effluent with injected liquid coolant and further converting the olefins over a metallic zeolite catalyst having a metal ethene oligomerization component;means for cooling and recovering heavier liquid hydrocarbon product from the second reactor effluent; andmeans for recovering liquid coolant from the second effluent for recycle to the interstage quench means.
摘要翻译： 一种用于升级低级烯烃的连续多级催化转化系统，包括含有酸性沸石固体催化剂的第一辅助催化床反应器装置; 用于将轻质烯属气体直接供给到第一反应器而不加入单独的稀释剂或再循环流的装置; 用于在高温下在烯烃部分转化条件下操作第一反应器的装置，以控制绝热温度升高; 级间骤冷装置，用于将液体冷却剂直接注入第一级流出物中以降低其温度并保护下游催化剂; 第二催化床反应器装置，用于接收具有注入的液体冷却剂的冷却的第一级流出物，并进一步转化具有金属乙烯低聚组分的金属沸石催化剂的烯烃; 用于从第二反应器流出物冷却和回收较重液体烃产物的装置; 以及用于从第二流出物回收液体冷却剂以再循环到级间骤冷装置的装置。
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公开(公告)号：US4717782A
公开(公告)日：1988-01-05
申请号：US893522
申请日：1986-08-05
CPC分类号： C07C2/12 , C07C2529/46 , Y02P20/52
摘要： A continuous catalytic process for converting ethene-rich olefinic feedstock containing reducing gas to heavier liquid hydrocarbon product, comprising the steps ofcontacting the ethene-rich feedstock at elevated temperature in a catalytic reaction zone with a zeolite catalyst comprising a nickel-ethene oligomerization component and a shape-selective medium pore acid zeolite oligomerization component to convert at least a portion of the lower olefinic components to heavier olefinic hydrocarbons; andfeeding water with the feedstock in sufficient amount to prevent substantial reduction of the nickel component.
摘要翻译： 一种用于将含有还原气体的富含烯烃的烯烃原料转化为较重液体烃产物的连续催化方法，包括以下步骤：使催化反应区中升温的富含乙烯的原料与包含镍 - 乙烯低聚组分的沸石催化剂和 形状选择性中孔酸性沸石低聚组分，将至少一部分较低级烯烃组分转化成较重的烯烃; 并用足够量的原料给予原料以防止镍组分的显着减少。
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4.发明授权Production of gasoline from light olefins with FCC gas plant improvement by olefin upgrading 失效通过烯烃升级生产FCC轻油烯烃汽油改善汽油
公开(公告)号：US4831204A
公开(公告)日：1989-05-16
申请号：US133772
申请日：1987-12-16
IPC分类号： C07C11/02
CPC分类号： C07C11/02
摘要： A continuous technique for upgrading light olefinic crackate gas from hydrocarbon cracking comprising methods and means for: (a) compressing and cooling a first portion of the light crackate gas to provide a first pressurized ethene-rich vapor stream and a first condensed crackate stream rich in C.sub.3.sup.+ aliphatics; (b) contacting said first ethene-rich vapor stream under pressure with a C.sub.5 + liquid sorbent stream in a gas-liquid contact absorber column under sorption conditions to selectively absorb a major amount of C.sub.3.sup.+ components; (c) recovering a second ethene-rich vapor stream overhead from the absorber column; (d) converting said second ethene-rich vapor stream in a reaction zone in once-through contact with a fluidized bed of said medium pore zeolite catalyst solid particles under oligomerization conditions to produce an olefinic hydrocarbon effluent stream rich in C.sub.5 + hydrocarbons; (e) cooling and separating the reaction effluent stream to provide a light offgas stream and a condensed liquid hydrocarbon product stream; (f) fractionating the condensed liquid hydrocarbon product stream in the absorber column concurrently with sorption of the first ethene-rich vapor stream for recovery of liquid hydrocarbon product with an absorber bottoms liquid stream rich in C.sub.3.sup.+ components; (g) further fractionating the absorber bottoms liquid stream to provide a C.sub.3 -C.sub.4 product and a liquid hydrocarbon fraction consisting essentially of C.sub.5.sup.+ hydrocarbons; (h) recycling at least a portion of the C.sub.5.sup.+ liquid hydrocarbon fraction to the absorber column as the liquid sorbent stream; and bypassing a second portion of said light crackate gas around said absorber to the reaction zone for conversion concurrently with said second ethene-rich vapor stream.
摘要翻译： 一种用于从烃裂解中提取轻质烯属裂化气体的连续技术，包括以下步骤的方法和装置：（a）压缩和冷却轻质裂化气体的第一部分，以提供富含第一加压的富含乙烯的蒸气流和富含第 C3 +脂肪 （b）在吸附条件下，使气体 - 液体接触吸收塔中的压力下的所述第一富乙烯蒸气流与气液接触吸收塔中的C5 +液体吸附剂流接触以选择性地吸收大量的C3 +组分; （c）从吸收塔塔顶回收第二富含乙烯的蒸汽流; （d）在低聚条件下与所述中孔沸石催化剂固体颗粒的流化床在反应区中转化所述第二富乙烯蒸气流，以产生富含C5 +烃的烯烃排出物流; （e）冷却和分离反应流出物流以提供轻质废气流和冷凝液态烃产物流; （f）吸收吸收塔中的冷凝液体烃产物流与吸附第一富含乙烯的蒸气流同时回收具有富含C3 +组分的吸收塔底液流的液态烃产物; （g）进一步对吸收塔底液流进行分馏以提供基本上由C5 +烃组成的C3-C4产物和液态烃馏分; （h）将至少一部分C5 +液体烃馏分循环至吸收塔作为液体吸附剂流; 并且绕所述吸收器周围的所述轻质裂化气体的第二部分绕过所述反应区，以与所述第二富乙烯蒸气流同时转化。
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公开(公告)号：US5043512A
公开(公告)日：1991-08-27
申请号：US576566
申请日：1990-08-31
IPC分类号： B01J29/86 , B01J29/04 , B01J29/70 , B01J29/87 , B01J29/88 , C07B61/00 , C07C2/12 , C07C5/27 , C07C15/02 , C07C15/08
CPC分类号： C07C5/2708 , B01J29/04 , C07C2/12 , C07C5/2737 , C07C2529/70
摘要： A process is provided for converting feedstock alkylaromatic compounds by isomerization over a catalyst comprising MCM-22.
摘要翻译： 提供了通过在包含MCM-22的催化剂上异构化来转化原料烷基芳族化合物的方法。
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6.发明授权Petroleum refinery process and apparatus for the production of alkyl aromatic hydrocarbons from fuel gas and catalytic reformate 失效用于从燃料气体和催化重整油生产烷基芳烃的石油炼厂工艺和装置
公开(公告)号：US4992607A
公开(公告)日：1991-02-12
申请号：US325736
申请日：1989-03-20
CPC分类号： C07C2/66 , C07C2529/40 , Y02P20/584
摘要： A petroleum refinery process for the production of alkyl aromatic hydrocarbons from a C.sub.4.sup.- fuel gas containing light olefins including ethene and propene and catalytic reformate containing C.sub.6 to C.sub.8 aromatics. The C.sub.4.sup.- fuel gas is contacted with the catalytic reformate at a weight ratio of aromatics to olefins of 10:1 to 15:1 over a zeolite catalyst under process conditions to alkylate the C.sub.6 to C.sub.8 aromatics, particularly benzene, in the reformate with ethene and propene in the C.sub.4.sup.- fuel gas to form alkyl aromatic hydrocarbons. The reaction is carried out in a riser reactor having multiple olefin feed injection points in the riser section of the reactor.The catalytic reaction also causes the conversion of a small amount of light olefins in the fuel gas to coke by-product and the deposition of coke on the catalyst. The deposited coke causes the partial deactivation of the catalyst. A portion of the partially deactivated catalyst is continuously or intermittently withdrawn from the riser reactor and regenerated in a catalyst regenerator by contacting the catalyst with hydrogen containing regeneration gas or by contacting the catalyst with an oxygen containing regeneration gas to remove substantially all of the coke from the catalyst. The regenerated catalyst is introduced in the riser reactor and contacted with fresh feed.
摘要翻译： 一种用于从含有轻质烯烃（包括乙烯和丙烯）的C4-燃料气体生产烷基芳族烃的炼油方法和含有C6至C8芳族化合物的催化重整产物。 在沸石催化剂的工艺条件下，C4-燃料气体与芳烃与烯烃的重量比为10:1至15:1接触，以在乙烯中重整产物中的C6至C8芳族化合物，特别是苯烷基化 并在C4-燃料气体中丙烯形成烷基芳族烃。 反应在反应器的提升管部分中具有多个烯烃进料注入点的提升管反应器中进行。 催化反应还导致将少量燃料气体中的轻质烯烃转化为焦炭副产物和焦炭沉积在催化剂上。 沉积的焦炭导致催化剂的部分失活。 部分失活的催化剂的一部分连续地或间歇地从提升管反应器中取出，并通过使催化剂与含氢再生气体接触或者通过使催化剂与含氧再生气体接触来再次在催化剂再生器中再生，以将基本上所有的焦炭从 催化剂。 将再生的催化剂引入提升管反应器中并与新鲜进料接触。
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公开(公告)号：US4992606A
公开(公告)日：1991-02-12
申请号：US469998
申请日：1990-01-25
CPC分类号： C07C2/12 , B01J29/04 , C07C2529/06 , C07C2529/70
摘要： Relatively short chain alkyl aromatic compounds are prepared by alkylating an alkylatable aromatic compound with a relatively short chain alkylating agent under alkylation reaction conditions in the presence of catalyst comprising a synthetic porous crystalline material characterized by an X-ray diffraction pattern including interplanar d-spacings at 12.36.+-.0.4, 11.03.+-.0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07, 3.91.+-.0.07 and 3.42.+-.0.06 Angstroms.
摘要翻译： 通过在烷基化反应条件下，在催化剂存在下，在烷基化反应条件下，使烷基化芳族化合物与相对短链烷基化剂进行烷基化，制备相对短链烷基芳族化合物，所述催化剂包含合成多孔结晶材料，其特征在于X射线衍射图包括在 12.36 +/- 0.4,11.03 +/- 0.2,8.83±0.14 6.18 +/- 0.12,6.00 +/- 0.10,4.06 +/- 0.07,3.91 +/- 0.07和3.42 +/- 0.06埃。
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