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1.发明授权FCC for producing low emission fuels from high hydrogen and low nitrogen and aromatic feeds 失效FCC用于从高氢和低氮和芳香的饲料生产低排放燃料
公开(公告)号：US5318694A
公开(公告)日：1994-06-07
申请号：US982932
申请日：1992-11-30
CPC分类号： C10G11/05
摘要： A fluid catalytic cracking process for producing relatively low emissions fuels. The feedstock is exceptionally low in nitrogen and aromatics and relatively high in hydrogen and a 345.degree. C.+ products fraction is recycled to the cracking zone. The catalyst is an amorphous silica-alumina or a zeolitic material which is iso-structural to faujasite. The feedstock can be characterized as having less than about 50 wppm nitrogen; greater than about 13 wt. % hydrogen; less than about 7.5 wt. % 2+ ring aromatic cores; and not more than about 15 wt. % aromatic cores overall.
摘要翻译： 用于生产相对低排放燃料的流化催化裂化方法。 原料的氮气和芳烃特别低，氢气相对较高，而345℃+产物馏分再循环到裂化区。 催化剂是无定形二氧化硅 - 氧化铝或与八面沸石异构结构的沸石材料。 原料可以表征为具有小于约50wppm氮; 大于约13重量％ ％氢; 小于约7.5重量％ ％2+环芳烃芯; 并且不超过约15wt。 ％芳香核心总体。
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公开(公告)号：US4176049A
公开(公告)日：1979-11-27
申请号：US892938
申请日：1978-04-03
CPC分类号： C10G11/05 , C10G2400/02
摘要： A process which comprises recracking a cracked naphtha feed containing up to about 60 percent, suitably from about 20 to about 40 percent olefins, over a crystalline aluminosilicate zeolite catalyst to further crack the naphtha and saturate at least about 50 percent of the olefins, preferably from about 90 percent to about 100 percent of the olefins, based on the weight of said cracked naphtha feed. In a preferred combination a gas oil is catalytically cracked in a first stage to produce a cat cracked naphtha product of high olefin content, and an intermediate boiling component thereof is recracked as a feed in a second stage over a zeolite catalyst to saturate the olefins, and hydrodenitrogenate and hydrodesulfurize said cat cracked naphtha. The recracked cat cracked naphtha is then hydrotreated at low to mild severities and then catalytically reformed (hydroformed) to produce high octane gasoline.
摘要翻译： 一种方法，其包括将超过约60％（优选约20至约40％的烯烃）的裂化石脑油原料重结晶在结晶硅铝酸盐沸石催化剂上，以进一步裂化石脑油并使至少约50％的烯烃饱和 约90％至约100％的烯烃，基于所述裂化石脑油进料的重量。 在优选的组合中，瓦斯油在第一阶段被催化裂化以产生高烯烃含量的催化裂化石脑油产物，其中间沸点组分作为进料在第二阶段中重新沸石沸石催化剂以使烯烃饱和， 加氢脱氮和加氢脱硫所述猫裂解石脑油。 然后将重新开裂的猫裂解的石脑油加热处理至低至轻微的严重程度，然后催化重整（液压成型）以产生高辛烷值汽油。
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公开(公告)号：US4308129A
公开(公告)日：1981-12-29
申请号：US206085
申请日：1980-11-12
CPC分类号： C10G11/05 , B01J29/084
摘要： A cracking catalyst comprising discrete particles of ultra-stable Y-type zeolite and discrete particles of alumina, which particles are dispersed in a porous oxide matrix to produce a catalyst containing 5-40 wt. % ultra-stable Y-type zeolite, 5-40 wt. % alumina and 40-90 wt. % of porous oxide matrix. The cracking catalyst has unusually high activity and selectivity for the production of high octane gasoline fractions from higher boiling point feedstocks.
摘要翻译： 包含超稳定Y型沸石和离散的氧化铝颗粒的裂解催化剂，该颗粒分散在多孔氧化物基质中以产生含有5-40wt。 ％超稳定Y型沸石，5-40wt。 ％氧化铝和40-90重量％ ％的多孔氧化物基质。 裂解催化剂对于从高沸点原料生产高辛烷值汽油馏分具有非常高的活性和选择性。
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公开(公告)号：US4376039A
公开(公告)日：1983-03-08
申请号：US344865
申请日：1982-02-01
CPC分类号： B01J29/061 , C10G11/05
摘要： A catalyst, having a specified amount of rare earth metal content and a specified amount of alkali metal content, suitable for conversion of hydrocarbon oils to lower boiling products comprises a crystalline aluminosilicate zeolite, such as zeolite Y, an inorganic oxide matrix and, optionally discrete particles of alumina dispersed in the matrix. The zeolite prior to being composited with the matrix has a unit cell size above about 24.5 Angstroms. A cracking process utilizing the catalyst is also provided.
摘要翻译： 具有特定量的稀土金属含量和规定量的碱金属含量的催化剂适用于将烃油转化为低沸点产物包括结晶铝硅酸盐沸石，例如沸石Y，无机氧化物基质和任选的离散的 分散在基质中的氧化铝颗粒。 在与基质复合之前的沸石具有高于约24.5埃的晶胞尺寸。 还提供了利用催化剂的裂化方法。
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公开(公告)号：US4259212A
公开(公告)日：1981-03-31
申请号：US80146
申请日：1979-09-28
CPC分类号： B01J29/084 , C10G11/05
摘要： A cracking catalyst comprising discrete particles of ultra-stable Y-type zeolite and discrete particles of alumina, which particles are dispersed in a porous oxide matrix to produce a catalyst containing 5-40 wt. % ultra-stable Y-type zeolite, 5-40 wt. % alumina and 40-90 wt. % of porous oxide matrix. The cracking catalyst has unusually high activity and selectivity for the production of high octane gasoline fractions from higher boiling point feedstocks.
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公开(公告)号：US5318695A
公开(公告)日：1994-06-07
申请号：US982933
申请日：1992-11-30
CPC分类号： C10G11/05
摘要： A fluid catalytic cracking process for producing relatively low emissions fuels. The feedstock is exceptionally low in nitrogen and aromatics and relatively high in hydrogen. The catalyst is an amorphous silica-alumina or a zeolitic material having a relatively small unit cell size. The feedstock can be characterized as having less than about 50 wppm nitrogen; greater than about 13 wt. % hydrogen; less than about 7.5 wt. % 2+ring aromatic cores; and not more than about 15 wt. % aromatic cores overall.
摘要翻译： 用于生产相对低排放燃料的流化催化裂化方法。 原料的氮气和芳烃特别低，氢气相对较高。 该催化剂是具有相对小的晶胞尺寸的无定形二氧化硅 - 氧化铝或沸石材料。 原料可以表征为具有小于约50wppm氮; 大于约13重量％ ％氢; 小于约7.5重量％ ％2 +环芳烃芯; 并且不超过约15wt。 ％芳香核心总体。
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公开(公告)号：US4339354A
公开(公告)日：1982-07-13
申请号：US196191
申请日：1980-10-10
IPC分类号： C10G35/095 , B01J29/06 , B01J29/08 , C10G11/05 , C10G47/16
CPC分类号： B01J29/061
摘要： A catalyst, having a specified amount of rare earth metal content and a specified amount of alkali metal content, suitable for conversion of hydrocarbon oils to lower boiling products comprises a crystalline aluminosilicate zeolite, such as zeolite Y, an inorganic oxide matrix and, optionally discrete particles of alumina dispersed in the matrix. The zeolite prior to being composited with the matrix has a unit cell size above about 24.5 Angstroms. A cracking process utilizing the catalyst is also provided.
摘要翻译： 具有特定量的稀土金属含量和规定量的碱金属含量的催化剂适用于将烃油转化为低沸点产物包括结晶铝硅酸盐沸石，例如沸石Y，无机氧化物基质和任选的离散的 分散在基质中的氧化铝颗粒。 在与基质复合之前的沸石具有高于约24.5埃的晶胞尺寸。 还提供了利用催化剂的裂化方法。
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8.发明授权FCC process incorporating crystalline microporous oxide catalysts having increased Lewis acidity 有权FCC方法结合具有增加的路易斯酸度的结晶微孔氧化物催化剂公开(公告)号：US06482313B1
公开(公告)日：2002-11-19
申请号：US09653135
申请日：2000-08-31
IPC分类号： C10G1104
CPC分类号： B01J29/08 , B01J37/0238 , C10G11/05 , C10G11/18
摘要： A catalyst component, a catalyst, and a process for making the component and catalyst are disclosed herein. Also disclosed herein is a fluid catalytic cracking process for converting petroleum feedstocks to lower boiling products wherein the feedstock is contacted with the catalyst. The catalyst component is a crystalline microporous oxide catalyst to which a compound for promoting dehydrogenation and increasing Lewis acidity is effectively added. This catalyst component can be included in an inorganic oxide matrix material and used as a catalyst. Preferably, the compound for promoting dehydrogenation and increasing Lewis acidity is effectively added to a non-framework portion of the crystalline microporous oxide.
摘要翻译： 本文公开了催化剂组分，催化剂和制备组分和催化剂的方法。 本文还公开了用于将石油原料转化为较低沸点产物的流化催化裂化方法，其中原料与催化剂接触。 催化剂组分是一种结晶微孔氧化物催化剂，其中有效地添加了用于促进脱氢和增加路易斯酸度的化合物。 该催化剂组分可以包括在无机氧化物基质材料中并用作催化剂。 优选地，用于促进脱氢和增加路易斯酸度的化合物被有效地加入结晶微孔氧化物的非骨架部分。
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9.发明授权Crystalline microporous oxide catalysts having increased Lewis acidity and methods for the preparation thereof 有权具有增加的路易斯酸度的结晶微孔氧化物催化剂及其制备方法公开(公告)号：US06673734B1
公开(公告)日：2004-01-06
申请号：US09653136
申请日：2000-08-31
IPC分类号： B01J2906
CPC分类号： B01J29/08 , B01J37/0238 , C10G11/05 , C10G11/18
摘要： A catalyst component, a catalyst, and a process for making the component and catalyst are disclosed herein. Also disclosed herein is a fluid catalytic cracking process for converting petroleum feedstocks to lower boiling products wherein the feedstock is contacted with the catalyst. The catalyst component is a crystalline microporous oxide catalyst to which a compound for promoting dehydrogenation and increasing Lewis acidity is effectively added. This catalyst component can be included in an inorganic oxide matrix material and used as a catalyst. Preferably, the compound for promoting dehydrogenation and increasing Lewis acidity is effectively added to a non-framework portion of the crystalline microporous oxide.
摘要翻译： 本文公开了催化剂组分，催化剂和制备组分和催化剂的方法。 本文还公开了用于将石油原料转化为较低沸点产物的流化催化裂化方法，其中原料与催化剂接触。 催化剂组分是一种结晶微孔氧化物催化剂，其中有效地添加了用于促进脱氢和增加路易斯酸度的化合物。 该催化剂组分可以包括在无机氧化物基质材料中并用作催化剂。 优选地，用于促进脱氢和增加路易斯酸度的化合物被有效地加入结晶微孔氧化物的非骨架部分。
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公开(公告)号：US4243557A
公开(公告)日：1981-01-06
申请号：US973000
申请日：1978-12-26
IPC分类号： B01D53/86 , B01J29/06 , B01J29/068 , B01J29/80 , C10G11/00 , C10G11/04 , C10G11/05 , C10G35/095 , B01J29/08 , B01J29/12
CPC分类号： B01J29/068 , C10G11/05 , Y10S502/517
摘要： An improved catalyst, and process utilizing said catalyst for catalytically cracking a sulfur-containing hydrocarbon feed, and for the fixation of sulfur by the catalyst and transfer thereof from the catalyst regeneration zone to the reaction zone of a catalytic cracking unit. The catalyst comprises an admixture of composite particles, one present in major concentration for providing principally cracking and combustion promoting functions, and the other present in minor concentration for providing principally sulfur fixation and transfer functions. The particle present in major concentration, on the one hand, is constituted essentially of one or more Group VIII noble metals, preferably platinum, composited with a support comprised of a crystalline alumino silicate component distributed in an active cracking catalyst matrix, suitably one constituted of silica-alumina. The minor component particle, on the other hand, is comprised of one or more Group II-A metals, preferably magnesium, composited with a support, suitably silica-magnesia or silica-alumina, which may also contain a crystalline aluminosilicate zeolite component dispersed within thesilica-magnesia or silica-alumina support matrix.
摘要翻译： 一种改进的催化剂，以及利用所述催化剂催化裂化含硫烃进料和通过催化剂固定硫并将其从催化剂再生区转移到催化裂化装置的反应区的方法。 催化剂包括复合颗粒的混合物，其以主要浓度存在以提供主要的裂化和燃烧促进功能，另一种以较小的浓度存在以提供主要的硫固定和转移功能。 主要浓度的颗粒一方面由一种或多种VIII族贵金属，优选铂组成，与由分散在活性裂化催化剂基质中的结晶铝硅酸盐组分组成的载体复合，合适的是由 二氧化硅 - 氧化铝。 另一方面，次要组分颗粒由一种或多种II-A族金属组成，优选镁，其与载体（合适的二氧化硅 - 氧化镁或二氧化硅 - 氧化铝）复合，其也可以含有分散在其中的结晶铝硅酸盐沸石组分 二氧化硅 - 氧化镁或二氧化硅 - 氧化铝载体基质。
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