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    Silica-reinforced rubber compounded with an alkoxysilane and a strong organic base
    5.
    发明授权
    Silica-reinforced rubber compounded with an alkoxysilane and a strong organic base 有权
    二氧化硅增强橡胶与烷氧基硅烷和强有机碱配合

    公开(公告)号：US07271208B2

    公开(公告)日：2007-09-18

    申请号：US11416295

    申请日：2006-05-02

    申请人： Chenchy Jeffrey Lin ,  William L. Hergenrother ,  Terrence E. Hogan

    发明人： Chenchy Jeffrey Lin ,  William L. Hergenrother ,  Terrence E. Hogan

    IPC分类号： C08G18/62

    CPC分类号： C08K5/31 ,  C08K3/36 ,  C08K5/54 ,  C08L43/04 ,  C08L21/00

    摘要： Improved tensile mechanical and dynamic viscoelastic properties of silica-reinforced sulfur vulcanized rubbers can be achieved by compounding elastomers with silica in the presence of an alkoxysilane and a catalytic amount of a strong organic base. The strong organic base acts as a catalyst to accelerate the alkoxysilane-silica reaction, especially at high compounding temperatures, resulting in rubber compounds that exhibit reduced compound viscosity, improved dispersion of silica, and reduced filler flocculation after compounding, and reduced hysteresis and improved abrasion resistance in the vulcanized product, compared to similar compounds prepared at the temperature without the strong organic base catalyst.

    摘要翻译： 通过在烷氧基硅烷和催化量的强有机碱的存在下，将弹性体与二氧化硅混合可以实现二氧化硅增强的硫磺硫化橡胶的拉伸机械和动态粘弹性的改进。 强有机碱作为加速烷氧基硅烷 - 二氧化硅反应的催化剂，特别是在高复合温度下，导致化合物粘度降低，二氧化硅分散性提高，配混后填料絮凝减少的橡胶化合物，减少滞后和改善磨损 与在没有强有机碱催化剂的温度下制备的类似化合物相比，硫化产物中的电阻。

    Method for making alkoxy-modified silsesquioxanes
    6.
    发明授权
    Method for making alkoxy-modified silsesquioxanes 有权
    制备烷氧基改性倍半硅氧烷的方法

    公开(公告)号：US08822620B2

    公开(公告)日：2014-09-02

    申请号：US13030611

    申请日：2011-02-18

    申请人： William L. Hergenrother ,  James H. Pawlow ,  Terrence E. Hogan ,  Ashley S. Hilton

    发明人： William L. Hergenrother ,  James H. Pawlow ,  Terrence E. Hogan ,  Ashley S. Hilton

    IPC分类号： C08G77/08

    CPC分类号： C08G77/08 ,  B60C1/00 ,  C08G77/18 ,  C08G77/28 ,  C08K3/013 ,  C08L9/00 ,  C08L21/00 ,  C08L83/06 ,  C08L83/08 ,  Y02P20/584 ,  C08L83/00

    摘要： A method is presented for making alkoxy-modified silsesquioxanes (AMS) or co-alkoxy-modified silsesquioxanes (co-AMS,) comprising the steps of (a) combining as a reaction mixture (i) water, (ii) an acid-stable solvent for the water, (iii) a solid strong cationic hydrolysis and condensation catalyst, and (iv) a trialkoxysilane compound, (b) allowing the reaction mixture to react for about 0.5 hours to about 200 hours to form the alkoxy-modified silsesquioxanes; and (c) recovering the alkoxy-modified silsesquioxanes from the reaction mixture. The use of solid strong cationic catalysts in this reaction system is advantageous because they remain as solids throughout the reaction, allowing simplified separation of the solid catalyst from the soluble AMS or co-AMS products, resulting in total or near total recovery of the AMS or co-AMS products, the products being free of, or substantially free of residual acid catalyst, as well as virtual total recovery of the catalyst for recycling. The improved AMS and co-AMS compounds, vulcanizable rubber compounds containing them, and a pneumatic tire having a component made from the vulcanized rubber compounds are also presented.

    摘要翻译： 提出了制备烷氧基改性倍半硅氧烷（AMS）或共 - 烷氧基改性倍半硅氧烷（co-AMS）的方法，该方法包括以下步骤：（a）将反应混合物（i）和（ii）酸稳定 溶剂，（iii）固体强阳离子水解和缩合催化剂，和（iv）三烷氧基硅烷化合物，（b）使反应混合物反应约0.5小时至约200小时以形成烷氧基改性倍半硅氧烷; 和（c）从反应混合物中回收烷氧基改性的倍半硅氧烷。 在该反应系统中使用固体强阳离子催化剂是有利的，因为它们在整个反应中保持固体，允许固体催化剂与可溶性AMS或共AMS产物的简单分离，导致AMS或 共AMS产品，产品没有或基本上没有残留的酸催化剂，以及用于再循环的催化剂的虚拟总回收。 还提出了改进的AMS和共AMS化合物，含有它们的可硫化橡胶化合物和具有由硫化橡胶化合物制成的组分的充气轮胎。

    METHOD FOR MAKING ALKOXY-MODIFIED SILSESQUIOXANES
    7.
    发明申请
    METHOD FOR MAKING ALKOXY-MODIFIED SILSESQUIOXANES 有权
    制备改性硅烷氧基硅烷的方法

    公开(公告)号：US20080293858A1

    公开(公告)日：2008-11-27

    申请号：US11752715

    申请日：2007-05-23

    申请人： William L. Hergenrother ,  James H. Pawlow ,  Terrence E. Hogan ,  Ashley S. Hilton

    发明人： William L. Hergenrother ,  James H. Pawlow ,  Terrence E. Hogan ,  Ashley S. Hilton

    IPC分类号： B60C1/00 ,  C07F7/00

    CPC分类号： C08G77/08 ,  B60C1/00 ,  C08G77/18 ,  C08G77/28 ,  C08K3/013 ,  C08L9/00 ,  C08L21/00 ,  C08L83/06 ,  C08L83/08 ,  Y02P20/584 ,  C08L83/00

    摘要： A method is presented for making alkoxy-modified silsesquioxanes (AMS) or co-alkoxy-modified silsesquioxanes (co-AMS,) comprising the steps of (a) combining as a reaction mixture (i) water, (ii) an acid-stable solvent for the water, (iii) a solid strong cationic hydrolysis and condensation catalyst, and (iv) a trialkoxysilane compound, (b) allowing the reaction mixture to react for about 0.5 hours to about 200 hours to form the alkoxy-modified silsesquioxanes; and (c) recovering the alkoxy-modified silsesquioxanes from the reaction mixture. The use of solid strong cationic catalysts in this reaction system is advantageous because they remain as solids throughout the reaction, allowing simplified separation of the solid catalyst from the soluble AMS or co-AMS products, resulting in total or near total recovery of the AMS or co-AMS products, the products being free of, or substantially free of residual acid catalyst, as well as virtual total recovery of the catalyst for recycling. The improved AMS and co-AMS compounds, vulcanizable rubber compounds containing them, and a pneumatic tire having a component made from the vulcanized rubber compounds are also presented.

    摘要翻译： 提出了制备烷氧基改性倍半硅氧烷（AMS）或共 - 烷氧基改性倍半硅氧烷（co-AMS）的方法，该方法包括以下步骤：（a）将反应混合物（i）和（ii）酸稳定 溶剂，（iii）固体强阳离子水解和缩合催化剂，和（iv）三烷氧基硅烷化合物，（b）使反应混合物反应约0.5小时至约200小时以形成烷氧基改性倍半硅氧烷; 和（c）从反应混合物中回收烷氧基改性的倍半硅氧烷。 在该反应系统中使用固体强阳离子催化剂是有利的，因为它们在整个反应中保持固体，允许固体催化剂与可溶性AMS或共AMS产物的简单分离，导致AMS或 共AMS产品，产品没有或基本上没有残留的酸催化剂，以及用于再循环的催化剂的虚拟总回收。 还提出了改进的AMS和共AMS化合物，含有它们的可硫化橡胶化合物和具有由硫化橡胶化合物制成的组分的充气轮胎。

    Method for making alkoxy-modified silsesquioxanes
    9.
    发明授权
    Method for making alkoxy-modified silsesquioxanes 有权
    制备烷氧基改性倍半硅氧烷的方法

    公开(公告)号：US07915368B2

    公开(公告)日：2011-03-29

    申请号：US11752715

    申请日：2007-05-23

    申请人： William L. Hergenrother ,  James H. Pawlow ,  Terrence E. Hogan ,  Ashley S. Hilton

    发明人： William L. Hergenrother ,  James H. Pawlow ,  Terrence E. Hogan ,  Ashley S. Hilton

    IPC分类号： C08G77/08

    CPC分类号： C08G77/08 ,  B60C1/00 ,  C08G77/18 ,  C08G77/28 ,  C08K3/013 ,  C08L9/00 ,  C08L21/00 ,  C08L83/06 ,  C08L83/08 ,  Y02P20/584 ,  C08L83/00

    摘要： A method is presented for making alkoxy-modified silsesquioxanes (AMS) or co-alkoxy-modified silsesquioxanes (co-AMS,) comprising the steps of (a) combining as a reaction mixture (i) water, (ii) an acid-stable solvent for the water, (iii) a solid strong cationic hydrolysis and condensation catalyst, and (iv) a trialkoxysilane compound, (b) allowing the reaction mixture to react for about 0.5 hours to about 200 hours to form the alkoxy-modified silsesquioxanes; and (c) recovering the alkoxy-modified silsesquioxanes from the reaction mixture. The use of solid strong cationic catalysts in this reaction system is advantageous because they remain as solids throughout the reaction, allowing simplified separation of the solid catalyst from the soluble AMS or co-AMS products, resulting in total or near total recovery of the AMS or co-AMS products, the products being free of, or substantially free of residual acid catalyst, as well as virtual total recovery of the catalyst for recycling. The improved AMS and co-AMS compounds, vulcanizable rubber compounds containing them, and a pneumatic tire having a component made from the vulcanized rubber compounds are also presented.

    摘要翻译： 提出了制备烷氧基改性倍半硅氧烷（AMS）或共 - 烷氧基改性倍半硅氧烷（co-AMS）的方法，该方法包括以下步骤：（a）将反应混合物（i）和（ii）酸稳定 溶剂，（iii）固体强阳离子水解和缩合催化剂，和（iv）三烷氧基硅烷化合物，（b）使反应混合物反应约0.5小时至约200小时以形成烷氧基改性倍半硅氧烷; 和（c）从反应混合物中回收烷氧基改性的倍半硅氧烷。 在该反应系统中使用固体强阳离子催化剂是有利的，因为它们在整个反应中保持固体，允许固体催化剂与可溶性AMS或共AMS产物的简单分离，导致AMS或 共AMS产品，产品没有或基本上没有残留的酸催化剂，以及用于再循环的催化剂的虚拟总回收。 还提出了改进的AMS和共AMS化合物，含有它们的可硫化橡胶化合物和具有由硫化橡胶化合物制成的组分的充气轮胎。

    Method For Making Alkoxy-Modified Silsesquioxanes
    10.
    发明申请
    Method For Making Alkoxy-Modified Silsesquioxanes 有权
    制备烷氧基改性倍半硅氧烷的方法

    公开(公告)号：US20110144235A1

    公开(公告)日：2011-06-16

    申请号：US13030611

    申请日：2011-02-18

    申请人： William L. Hergenrother ,  James H. Pawlow ,  Terrence E. Hogan ,  Ashley S. Hilton

    发明人： William L. Hergenrother ,  James H. Pawlow ,  Terrence E. Hogan ,  Ashley S. Hilton

    IPC分类号： C08K5/5419 ,  B60C1/00 ,  C08L19/00

    CPC分类号： C08G77/08 ,  B60C1/00 ,  C08G77/18 ,  C08G77/28 ,  C08K3/013 ,  C08L9/00 ,  C08L21/00 ,  C08L83/06 ,  C08L83/08 ,  Y02P20/584 ,  C08L83/00

    摘要： A method is presented for making alkoxy-modified silsesquioxanes (AMS) or co-alkoxy-modified silsesquioxanes (co-AMS,) comprising the steps of (a) combining as a reaction mixture (i) water, (ii) an acid-stable solvent for the water, (iii) a solid strong cationic hydrolysis and condensation catalyst, and (iv) a trialkoxysilane compound, (b) allowing the reaction mixture to react for about 0.5 hours to about 200 hours to form the alkoxy-modified silsesquioxanes; and (c) recovering the alkoxy-modified silsesquioxanes from the reaction mixture. The use of solid strong cationic catalysts in this reaction system is advantageous because they remain as solids throughout the reaction, allowing simplified separation of the solid catalyst from the soluble AMS or co-AMS products, resulting in total or near total recovery of the AMS or co-AMS products, the products being free of, or substantially free of residual acid catalyst, as well as virtual total recovery of the catalyst for recycling. The improved AMS and co-AMS compounds, vulcanizable rubber compounds containing them, and a pneumatic tire having a component made from the vulcanized rubber compounds are also presented.

    摘要翻译： 提出了制备烷氧基改性倍半硅氧烷（AMS）或共 - 烷氧基改性倍半硅氧烷（co-AMS）的方法，该方法包括以下步骤：（a）将反应混合物（i）和（ii）酸稳定 溶剂，（iii）固体强阳离子水解和缩合催化剂，和（iv）三烷氧基硅烷化合物，（b）使反应混合物反应约0.5小时至约200小时以形成烷氧基改性倍半硅氧烷; 和（c）从反应混合物中回收烷氧基改性的倍半硅氧烷。 在该反应系统中使用固体强阳离子催化剂是有利的，因为它们在整个反应中保持固体，允许固体催化剂与可溶性AMS或共AMS产物的简单分离，导致AMS或 共AMS产品，产品没有或基本上没有残留的酸催化剂，以及用于再循环的催化剂的虚拟总回收。 还提出了改进的AMS和共AMS化合物，含有它们的可硫化橡胶化合物和具有由硫化橡胶化合物制成的组分的充气轮胎。