Pyridyloxyalkanoic acid amide derivatives useful as fungicides

    公开(公告)号:US20050065032A1

    公开(公告)日:2005-03-24

    申请号:US10497627

    申请日:2002-11-25

    摘要: Fungicidal compounds of the general formula (I): wherein X and Y are independently H, halo, C1-8 alkyl, C3-6 cycloalkyl, C2-8 alkenyl, C2-8 alkynyl, C1-8 alkoxy, C1-8 alkylthio, nitro, amino, mono- or di-(C1-6)alkylamino, mono- or di-(C2-6)alkenylamino, mono- or di-(C2-6)alkynylamino, formylamino, C1-4 alkyl(formyl)amino, C1-4 alkylcarbonylamino, C1-4 alkyl(C1-4 alkylcarbonyl)amino, cyano, formyl, C1-4 alkylcarbonyl, C1-4 alkoxycarbonyl, aminocarbonyl, mono- or di-(C1-4)alkylaminocarbonyl, carboxy, C1-4 alkylcarbonyloxy, aryl(C1-4)alkylcarbonyloxy, C1-4 alkylsulphinyl, C1-4 alkylsulphonyl, C1-4 alkylsulphonyloxy, aryl, heteroaryl, aryloxy, arylthio, heteroaryloxy or heteroarylthio wherein any of the foregoing alkyl, cycloalkyl, alkenyl, alkynyl, aryl, heteroaryl, groups or moieties are optionally substituted; R1 is phenyl, cyano, C1-4 alkyl, C2-4 alkenyl or C2-4 alkynyl in which the alkyl, alkenyl and alkynyl groups are optionally substituted on their terminal carbon atom with one, two or thre halogen atoms, with a cyano group, with a C1-4 alkylcarbonyl group, with a C1-4 alkoxycarbonyl group or with a hydroxy group, or R1 is alkoxyalkyl, alkylthioalkyl, alkylsulphinylalkyl or alkylsulphonylalkyl in which the total number of carbon atoms is 2 or 3; R2 is H, C1-4 alkyl, C1-4 alkoxymethyl or benzyloxymethyl in which the phenyl ring of the benzyl moiety is optionally substituted with C1-4 alkoxy; R3 and R4 are independently H, C1-3 alkyl, C2-3 alkenyl or C2-3 alkynyl provided that both are not H and that when both are other than H their combined total of carbon atoms does not exceed 4, or R3 and R4 join with the carbon atom to which they are attached to form a 3 or 4 membered carbocyclic ring optionally containing one O, S or N atom and optionally substituted with halo or C1-4 alkyl; and R5 is halo, C1-4 alkyl or C3-4 cycloalkyl in which the alkyl or cycloalkyl group is optionally substituted with halo, hydroxy, C1-6 alkoxy, C1-6 alkylthio, cyano, C1-4 alkylcarbonyloxy, aminocarbonyloxy, mono- or di(C1-4)alkylaminocarbonyloxy, or tri(C1-4)alkylsilyloxy. The compounds and compositions containing them are especially useful for combating fungal infections of plants.

    PYRIDYLOXYALKANOIC ACID AMIDE DERIVATIVES USEFUL AS FUNGICIDES

    公开(公告)号:US20070135468A1

    公开(公告)日:2007-06-14

    申请号:US11623448

    申请日:2007-01-16

    摘要: Fungicidal compounds of the general formula (I): wherein X and Y are independently H, halo, C1-8 alkyl, C3-6 cycloalkyl, C2-8 alkenyl, C2-8 alkynyl, C1-8 alkoxy, C1-8 alkylthio, nitro, amino, mono- or di-(C1-6)alkylamino, mono- or di-(C2-6)alkenylamino, mono- or di-(C2-6)alkynylamino, formylamino, C1-4 alkyl(formyl)amino, C1-4 alkylcarbonylamino, C1-4 alkyl(C1-4 alkylcarbonyl)amino, cyano, formyl, C1-4 alkylcarbonyl, C1-4 alkoxycarbonyl, aminocarbonyl, mono- or di-(C1-4)alkylaminocarbonyl, carboxy, C1-4 alkylcarbonyloxy, aryl(C1-4)alkylcarbonyloxy, C1-4 alkylsulphinyl, C1-4 alkylsulphonyl, C1-4 alkylsulphonyloxy, aryl, heteroaryl, aryloxy, arylthio, heteroaryloxy or heteroarylthio wherein any of the foregoing alkyl, cycloalkyl, alkenyl, alkynyl, aryl, heteroaryl, groups or moieties are optionally substituted; R1 is phenyl, cyano, C1-4 alkyl, C2-4 alkenyl or C2-4 alkynyl in which the alkyl, alkenyl and alkynyl groups are optionally substituted on their terminal carbon atom with one, two or three halogen atoms, with a cyano group, with a C1-4 alkylcarbonyl group, with a C1-4 alkoxycarbonyl group or with a hydroxy group, or R1 is alkoxyalkyl, alkylthioalkyl, alkylsulphinylalkyl or alkylsulphonylalkyl in which the total number of carbon atoms is 2 or 3; R2 is H, C1-4 alkyl, C1-4 alkoxymethyl or benzyloxymethyl in which the phenyl ring of the benzyl moiety is optionally substituted with C1-4 alkoxy; R3 and R4 are independently H, C1-3 alkyl, C2-3 alkenyl or C2-3 alkynyl provided that both are not H and that when both are other than H their combined total of carbon atoms does not exceed 4, or R3 and R4 join with the carbon atom to which they are attached to form a 3 or 4 membered carbocyclic ring optionally containing one O, S or N atom and optionally substituted with halo or C1-4 alkyl; and R5 is halo, C1-4 alkyl or C3-4 cycloalkyl in which the alkyl or cycloalkyl group is optionally substituted with halo, hydroxy, C1-6 alkoxy, C1-6 alkylthio, cyano, C1-4 alkylcarbonyloxy, aminocarbonyloxy, mono- or di(C1-4)alkylaminocarbonyloxy, or tri(C1-4)alkylsilyloxy. The compounds and compositions containing them are especially useful for combating fungal infections of plants.

    Fungicidal mixtures
    4.
    发明授权
    Fungicidal mixtures 失效
    杀菌混合物

    公开(公告)号:US06699874B2

    公开(公告)日:2004-03-02

    申请号:US10314594

    申请日:2002-12-10

    IPC分类号: A01N4354

    CPC分类号: A01N43/90 A01N2300/00

    摘要: Fungicidal compositions comprising an acceptable carrier and/or surface active agent and synergistically effective amounts of (a) at least one azolopyrimidine of formula I  in which R1, R2, L1, L2 and L3 have the meaning given in claim 1; and (b) at least one fungicidal active ingredient selected from benomyl, carboxin, captan, chlorothalonil, copper oxychloride, cyprodinil, dimethomorph, dithianon, dodine, famoxadone, fenhexamid, fenpiclonil, fenpropimorph, fluazinam, mancozeb, metalaxyl, pyrimethanil, quinoxifen, sulfur, triforine, vinclozolin, a fungicidal triazole derivative, and a synthetic strobilurine derivative. The invention also provides a method of controlling the growth of phytopathogenic fungi at a locus by applying synergistically effective amounts of at least one azolopyrimidine of formula I and at least one fungicidal active ingredient (b) to the locus.

    摘要翻译: 包含可接受的载体和/或表面活性剂和协同有效量的(a)至少一种R 1,R 2,L 1,L 2和L 3的式Iin的偶氮嘧啶的杀真菌组合物 >具有权利要求1中给出的含义; 和(b)至少一种杀真菌活性成分,其选自苯菌灵,呋喃丹,克拉曼,百菌清,氯氧化铜,西酞替尼,烯酰吗啉,二噻吩,十二烷,恶唑酮,芬己酰,芬替尼,芬卡芬,氟啶胺,代森锰锌,甲霜灵,嘧霉胺,喹喔啉, ,triperine,长春菌素,杀真菌三唑衍生物和合成次溴酸衍生物。 本发明还提供了一种通过将协同有效量的至少一种式I的偶氮嘧啶和至少一种杀真菌活性成分(b)施用于该基因座来控制植物病原真菌在一个场所生长的方法。

    Fungicidal mixtures
    7.
    发明授权
    Fungicidal mixtures 失效
    杀菌混合物

    公开(公告)号:US06518275B1

    公开(公告)日:2003-02-11

    申请号:US09809512

    申请日:2001-03-15

    IPC分类号: A01N3744

    摘要: Fungicidal compositions comprising an acceptable carrier and/or surface active agent and synergistically effective amounts of (a) at least one azolopyrimidine of formula I  in which R1, R2, L1, L2 and L3 have the meaning given in claim 1; and (b) at least one fungicidal active ingredient selected from benomyl, carboxin, captan, chlorothalonil, copper oxychloride, cyprodinil, dimethomorph, dithianon, dodine, famoxadone, fenhexamid, fenpiclonil, fenpropimorph, fluazinam, mancozeb, metalaxyl, pyrimethanil, quinoxifen, sulfur, triforine, vinclozolin, a fungicidal triazole derivative, and a synthetic strobilurine derivative. The invention also provides a method of controlling the growth of phytopathogenic fungi at a locus by applying synergistically effective amounts of at least one azolopyrimidine of formula I and at least one fungicidal active ingredient (b) to the locus.

    摘要翻译: 包含可接受的载体和/或表面活性剂的杀真菌组合物和协同有效量的(a)至少一种式I的偶氮嘧啶,其中R 1,R 2,L 1,L 2和L 3具有权利要求1中给出的含义; 和(b)至少一种杀真菌活性成分,其选自苯菌灵,呋喃丹,克拉曼,百菌清,氯氧化铜,西酞替尼,烯酰吗啉,二噻吩,十二烷,恶唑酮,芬己酰,芬替尼,芬卡芬,氟啶胺,代森锰锌,甲霜灵,嘧霉胺,喹喔啉, ,triperine,长春菌素,杀真菌三唑衍生物和合成次溴酸衍生物。 本发明还提供了一种通过将协同有效量的至少一种式I的偶氮嘧啶和至少一种杀真菌活性成分(b)施用于该基因座来控制植物病原真菌在一个场所生长的方法。

    Enhancement of the efficacy of triazolopyrimidines
    9.
    发明授权
    Enhancement of the efficacy of triazolopyrimidines 失效
    提高三唑嘧啶的疗效

    公开(公告)号:US6124301A

    公开(公告)日:2000-09-26

    申请号:US268853

    申请日:1999-03-15

    CPC分类号: C07D487/04 A01N43/90

    摘要: Adjuvants selected from liquid polyalkoxylated aliphatic alcohols, solid sodium hydrocarbyl sulfonates and polyalkoxylated trisiloxanes enhance the efficacy of fungicidal triazolopyrimidines. They can be incorporated into formulations of the fungicidal compounds or be added to spray mixtures (tank mix) as separately formulated additives in order to improve the efficacy, systemicity and spectrum of these fungicides.

    摘要翻译: 选自液体聚烷氧基化脂族醇,固体烷基磺酸钠和聚烷氧基化三硅氧烷的佐剂增强了杀真菌三唑并嘧啶的功效。 它们可以并入到杀真菌化合物的制剂中,或者作为单独配制的添加剂加入到喷雾混合物(罐混合物)中,以提高这些杀真菌剂的功效,系统性和光谱。

    Fungicidal mixtures
    10.
    发明授权
    Fungicidal mixtures 失效
    杀菌混合物

    公开(公告)号:US06656944B2

    公开(公告)日:2003-12-02

    申请号:US09832964

    申请日:2001-04-11

    IPC分类号: A01N4354

    摘要: The invention relates to fungicidal compositions comprising an acceptable carrier and/or surface active agent and synergistically effective amounts of (a) at least one azolopyrimidine of formula I  in which R1 through R2, L, A and n have the meaning given in claim 1; (b) and at least one melanin biosynthesis inhibitor (MBI), preferably a phenoxyamide of formula II  wherein R5 through R9, Y and m have the meaning given in claim 2; and to a method of controlling the growth of phythopathogenic fungi at a locus which comprises applying synergistically effective amounts of at least one azolopyrimidine of formula I (a) and at least one MBI (b) to the locus.

    摘要翻译: 本发明涉及包含可接受的载体和/或表面活性剂和协同有效量的(a)至少一种式Iin的至少一种氮杂嘧啶的杀真菌组合物,其中R 1至R 2,L,A和n具有其含义 在权利要求1中给出;(b)和至少一种黑色素生物合成抑制剂(MBI),优选式VII的苯氧基酰胺,其中R 5至R 9,Y和m具有权利要求2中给出的含义; 以及在一个场所控制植物病原真菌的生长的方法,其包括将协同有效量的至少一种式I(a)的偶氮嘧啶和至少一种MBI(b)施用于该基因座。