摘要:
A process for producing a polyurethane foam with bimodal cell size distribution, comprising the following steps: providing a mixture in a mixing head, where the mixture comprises: A) a component reactive towards isocyanates; B) a surfactant component; C) a blowing agent component selected from the group consisting of linear, branched or cyclic C1- to C6-alkanes, linear, branched or cyclic C1- to C6-fluoroalkanes, N2, O2, argon and/or CO2, where blowing agent component C) is present in the supercritical or near-critical state; D) a polyisocyanate component; discharging the mixture comprising components A), B), C), and D) from the mixing head where, during the discharge of the mixture, the pressure prevailing in the mixture is lowered to atmospheric pressure.
摘要:
Process for producing a polyurethane foam and polyurethane foam obtainable therefrom A process for producing a polyurethane foam with bimodal cell size distribution, comprising the following steps: providing a mixture in a mixing head, where the mixture comprises: A) a component reactive towards isocyanates; B) a surfactant component; C) a blowing agent component selected from the group consisting of linear, branched or cyclic C1- to C6-alkanes, linear, branched or cyclic C1- to C6-fluoroalkanes, N2, O2, argon and/or CO2, where blowing agent component C) is present in the supercritical or near-critical state; D) a polyisocyanate component; discharging the mixture comprising components A), B), C), and D) from the mixing head where, during the discharge of the mixture, the pressure prevailing in the mixture is lowered to atmospheric pressure.
摘要:
The present invention relates to a process for producing a polyurethane foam, where the blowing agent used is present in the supercritical or near-critical state. A reaction mixture is introduced into a closed mould, where the closed mould has been set up in such a way that its interior volume and/or the pressure prevailing in its interior can be altered after the introduction of the mixture by external influence. Through the selection of the surfactant it is possible to obtain microemulsions of the blowing agent in the polyol phase. The invention further relates to a nanocellular polyurethane foam obtainable by the process of the invention.
摘要:
The present invention relates to a process for producing a polyurethane foam, where the blowing agent used is present in the supercritical or near-critical state. A reaction mixture is introduced into a closed mould, where the closed mould has been set up in such a way that its interior volume and/or the pressure prevailing in its interior can be altered after the introduction of the mixture by external influence. Through the selection of the surfactant it is possible to obtain microemulsions of the blowing agent in the polyol phase. The invention further relates to a nanocellular polyurethane foam obtainable by the process of the invention.
摘要:
The present invention relates to a reaction mixture in emulsion form, suitable for conversion into polyurethanes, comprising a first phase and a second phase in the emulsion and further comprising the following components: A) polyols; B) blowing agent; C) surfactants; and D) isocyanates, wherein the isocyanate-reactive compounds A) are present in the first phase of the emulsion and the blowing agent B) is present in the second phase. The blowing agent B) is present in the near-critical or supercritical state and the isocyanate D) is present in the second phase in a proportion of ≧10% by weight of the total amount of isocyanate D) in the composition. The invention further relates to a method of producing polyurethane foams by providing such a reaction mixture, wherein a polymerization takes place at the freshly formed interface between the polyol phase and the blowing agent phase, to the use of such a reaction mixture for producing polyurethane foams and also to the polyurethane foams obtained.
摘要:
The invention relates to microemulsions which comprise, as oil phase, a polysiloxane containing at least one quaternary ammonium group, methods for production thereof and also to the use of such microemulsions.
摘要:
A process for isolating rhamnolipids is provided. The process includes providing an aqueous medium containing at least one rhamnolipid and having a pH of less than 6. Next, the aqueous medium is brought into contact with at least one organic solvent to provide a multiphase system and then the aqueous phase is separated off. The pH is then increased to a value of 6 or more to provide a multiphase organic system. Next, a rhamnolipid-enriched organic phase is separated off. An optional step of further purifying the rhamnolipid may be performed.
摘要:
The present invention relates to a PEG free, stable, low viscosity classic oil-in-water emulsion and the use and preparation thereof. The oil-in-water emulsion comprises, A) a primary emulsifier selected from alkyl polyglucosides and long chained polyglycerol esters, B) a secondary emulsifier selected from short chained polyglycerol esters and short chained sorbitan esters, and optionally a thickener if the amount of secondary emulsifier is below 2.5 wt. %. The emulsion is a classic emulsion and can be sprayable. The emulsion is suitable to prepare spray or foam emulsion products with good application effect.
摘要:
The invention relates to microemulsions which comprise, as oil phase, a polysiloxane containing at least one quaternary ammonium group, methods for production thereof and also to the use of such microemulsions.
摘要:
A process for isolating rhamnolipids is provided. The process includes providing an aqueous medium containing at least one rhamnolipid and having a pH of less than 6. Next, the aqueous medium is brought into contact with at least one organic solvent to provide a multiphase system and then the aqueous phase is separated off. The pH is then increased to a value of 6 or more to provide a multiphase organic system. Next, a rhamnolipid-enriched organic phase is separated off. An optional step of further purifying the rhamnolipid may be performed.