Curable polyurethane polymer dispersion based on this polymer, processing for preparing the dispersion, and its use
    1.
    发明授权
    Curable polyurethane polymer dispersion based on this polymer, processing for preparing the dispersion, and its use 有权
    可固化聚氨酯聚合物,基于该聚合物的分散体,制备分散体的方法及其用途

    公开(公告)号:US06207744B1

    公开(公告)日:2001-03-27

    申请号:US09267139

    申请日:1999-03-11

    IPC分类号: C08J300

    摘要: The invention relates to a curable polyurethane polymer which comprises in copolymerized form A) from 40 to 80% by weight, based on the overall weight of components A) to F), of at least one hydroxyl-containing prepolymer having at least one free-radically or photochemically polymerizable &agr;,&bgr;-ethylenically unsaturated double bond, B) from 0.1 to 20% by weight, based on the overall weight of components A) to F), of at least one compound having at least one isocyanate-reactive hydroxyl group and/or primary or Secondary amino group and, in addition, at least one polar functional group, C) from 0.1 to 10% by weight, based on the overall weight of components A) to F), of at least one compound selected from diamines, polyamines and mixtures thereof, D) from 0 to 20% by weight, based on the overall weight of components A) to F), of at least one further compound other than A), B), C) and E), having at least two isocyanate-reactive groups, which are hydroxyl groups and mixtures of hydroxyl groups and/or primary or secondary amino groups, E) from 0 to 20% by weight, based on the overall weight of components A) to F), of at least one compound having an isocyanate-reactive group, F) from 10 to 50% by weight, based on the overall weight of components A) to F), of at least one polyisocyanate, and the salts thereof, wherein the sum of the hydroxyl numbers of components A) and D) lies within a range from 121 to 300 mg of KOH/g.

    摘要翻译: 本发明涉及可固化的聚氨酯聚合物,其包含共聚形式,A)40至80重量%,基于组分A)至F)的总重量,至少一种含羟基的预聚物具有至少一个自由基 或光化学可聚合的α,β-烯属不饱和双键,B)基于组分A)至F)的总重量为0.1至20重量%的至少一种具有至少一个异氰酸酯反应性羟基的化合物和 或至少一种极性官能团,C)0.1至10重量%,基于组分A)至F)的总重量,至少一种选自二胺的化合物 ,多胺及其混合物,D)基于组分A)至F)的总重量为0至20重量%的除A),B),C)和E)之外的至少一种其它化合物,其具有 至少两个异氰酸酯反应性基团,它们是羟基和羟基的混合物 基于组分A)至F)的总重量为0至20重量%的至少一种具有异氰酸酯反应性基团的化合物,F)为10至10重量% 50重量%,基于组分A)至F)的总重量,至少一种多异氰酸酯及其盐,其中组分A)和D)的羟基数之和位于121至 300mg KOH / g。

    Preparation of (meth)acrylates
    2.
    发明授权
    Preparation of (meth)acrylates 失效
    (甲基)丙烯酸酯的制备

    公开(公告)号:US06458991B1

    公开(公告)日:2002-10-01

    申请号:US09592736

    申请日:2000-06-13

    IPC分类号: C07C6952

    摘要: Compounds having alcoholic hydroxyl groups are esterified with acrylic or methacrylic acid in the presence of copper(II) salts or mixtures thereof as polymerization inhibitors and in the presence of a hydrocarbon as a water-entraining agent with removal of the water of reaction at from 90 to 150° C. After the esterification, the copper salt is precipitated as copper sulfide and is separated off from the ester. The light-color (meth)acrylates resulting in the high yields are particularly suitable for coatings containing colored pigment on substrates such as wood, paper, mineral building materials, plastics or metal.

    摘要翻译: 具有醇羟基的化合物在作为聚合抑制剂的铜(II)盐或其混合物的存在下,用丙烯酸或甲基丙烯酸酯化,并且在作为加水剂的烃存在下,从90℃除去反应水 至150℃。酯化后,铜盐以硫化铜的形式析出,并与酯分离。 导致高产率的浅色(甲基)丙烯酸酯特别适用于在木材,纸,矿物建筑材料,塑料或金属等基材上含有着色颜料的涂料。

    Preparing radiation-curable, urethane-functional prepolymers
    3.
    发明授权
    Preparing radiation-curable, urethane-functional prepolymers 有权
    制备可辐射固化的氨基甲酸酯官能预聚物

    公开(公告)号:US06177535B1

    公开(公告)日:2001-01-23

    申请号:US09157615

    申请日:1998-09-21

    IPC分类号: C08G1808

    摘要: A process for preparing radiation-curable, urethane-functional prepolymers by reacting an isocyanate-functional component A with an OH-containing component B, wherein either component A embraces two different isocyanate compounds A1 or one isocyanate compound A1 and at least one isocyanate compound A2 or component B embraces at least two different compounds B1. Also, the prepolymers obtainable by the process and the radiation-curable formulations comprising them. Furthermore, the use of the radiation-curable formulations for coating substrates, a method of coating substrates, and the coated substrates themselves.

    摘要翻译: 通过使异氰酸酯官能的组分A与含OH的组分B反应制备可辐射固化的氨基甲酸酯官能的预聚物的方法,其中组分A包含两种不同的异氰酸酯化合物A1或一种异氰酸酯化合物A1和至少一种异氰酸酯化合物A2 或组分B包含至少两种不同的化合物B1。 此外,可通过该方法获得的预聚物和包含它们的可辐射固化制剂。 此外,使用用于涂布基材的可辐射固化制剂,涂布基材的方法和涂布的基材本身。

    Curable polyurethane polymer
    4.
    发明授权
    Curable polyurethane polymer 有权
    固化聚氨酯聚合物

    公开(公告)号:US06538046B1

    公开(公告)日:2003-03-25

    申请号:US09614169

    申请日:2000-07-11

    IPC分类号: C08J300

    摘要: The present invention provides a curable polyurethane polymer containing in copolymerized form A) from 10 to 60% by weight of at least one hydroxyl-containing prepolymer having at least one &agr;,&bgr;-ethylenically unsaturated double bond, B) from 0.1 to 30% by weight of at least one compound having at least one isocyanate-reactive hydroxyl group and/or primary or secondary amino group and, in addition, at least one polar functional group per molecule, C) from 0.1 to 30% by weight of at least one compound selected from diamines, polyamines and mixtures thereof, D) from 0 to 10% by weight of at least one further compound other than A), B), C) and E) having at least two isocyanate-reactive groups, which are hydroxyl groups and mixtures of hydroxyl groups with primary and/or secondary amino groups, E) from 0 to 20% by weight of at least one compound having an isocyanate-reactive group, F) from 10 to 65% by weight of at least one compound having at least two isocyanate groups, and the salts thereof, wherein the ratio of isocyanate group equivalents of component F) to equivalents of isocyanate-reactive groups of components A) to E) is in a range from 0.4:1 to 0.9:1, polymer dispersions comprising at least one such polymer, and the use thereof.

    摘要翻译: 本发明提供了一种包含共聚形式的可固化聚氨酯聚合物,A)10-60重量%的至少一种含有至少一个α,β-烯属不饱和双键的含羟基预聚物,B)0.1-30重量% 的至少一种具有至少一个异氰酸酯反应性羟基和/或伯或仲氨基的化合物,另外每分子具有至少一个极性官能团,C)0.1至30重量%的至少一种化合物 选自二胺,多胺及其混合物,D)0至10重量%的至少一种除了A),B),C)和C)以外的至少一种其它化合物,其具有至少两个为羟基的异氰酸酯反应性基团 和羟基与伯氨基和/或仲氨基的混合物,E)0至20重量%的至少一种具有异氰酸酯反应性基团的化合物,F)10至65重量%的至少一种具有 至少两个异氰酸酯基团,以及其中的盐 其中组分F的异氰酸酯基当量比与组分A)至E)的异氰酸酯反应性基团的当量相对于0.4:1至0.9:1的范围内,包含至少一种这样的聚合物的聚合物分散体和 其使用。

    Aqueous dispersion of a mixture of a polyurethane with a radiation-curable (meth)acrylate prepolymer
    7.
    发明授权
    Aqueous dispersion of a mixture of a polyurethane with a radiation-curable (meth)acrylate prepolymer 失效
    聚氨酯与可辐射固化的(甲基)丙烯酸酯预聚物的混合物的水分散体

    公开(公告)号:US06479577B1

    公开(公告)日:2002-11-12

    申请号:US09617111

    申请日:2000-07-14

    IPC分类号: C08L7500

    CPC分类号: C09D175/16 C08G18/0823

    摘要: Aqueous dispersions of mixtures of (a) polyurethanes having hydrophilic groups which result in water dispersibility of the polyurethane and (b) radiation-curable (meth)acrylate prepolymers which are dilutable in at least 5% by weight of water, such as hydroxyl-containing polyether acrylates, are suitable, owing to their penetration behavior and their high solids absorption in paper, for use as radiation-curable coating or impregnating materials for paper substrates.

    摘要翻译: (a)具有导致聚氨酯的水分散性的亲水基团的聚氨酯的混合物的水分散体和(b)可在至少5重量%水中稀释的可辐射固化的(甲基)丙烯酸酯预聚物,例如含羟基的 聚醚丙烯酸酯,由于它们的渗透行为和它们在纸中的高固体吸收,适用于用作纸基材的可辐射固化涂料或浸渍材料。

    Radiation-curable aqueous dispersions
    9.
    发明授权
    Radiation-curable aqueous dispersions 有权
    可辐射固化的水性分散体

    公开(公告)号:US07193005B2

    公开(公告)日:2007-03-20

    申请号:US10512853

    申请日:2003-05-21

    摘要: Aqueous polymer dispersions comprising a) 50–70% by weight of polymer particles composed of at least two different (co)polymers having glass transition temperatures each above 50° C. and synthesized from at least 80% by weight of at least one principal monomer, 0.1–10% by weight of at least one auxiliary monomer, and 0–3% by weight of at least one crosslinker molecule, the difference in the glass transition temperatures (Tg) of the different polymers being at least 10° C., and b) 30–50% by weight of at least one polyfunctional (meth)acrylate, the dispersion a) being subjected to physical and/or chemical deodorization.

    摘要翻译: 含水聚合物分散体包含a)50-70%(重量)由至少两种不同(共)聚合物组成的聚合物颗粒,其玻璃化转变温度各自高于50℃,并由至少一种主要单体至少80%重量合成 ,0.1-10重量%的至少一种辅助单体和0-3重量%的至少一种交联剂分子,不同聚合物的玻璃化转变温度(T N) 至少10℃,和b)30-50重量%的至少一种多官能(甲基)丙烯酸酯,所述分散体a)进行物理和/或化学除臭。