摘要:
The invention relates to a curable polyurethane polymer which comprises in copolymerized form A) from 40 to 80% by weight, based on the overall weight of components A) to F), of at least one hydroxyl-containing prepolymer having at least one free-radically or photochemically polymerizable &agr;,&bgr;-ethylenically unsaturated double bond, B) from 0.1 to 20% by weight, based on the overall weight of components A) to F), of at least one compound having at least one isocyanate-reactive hydroxyl group and/or primary or Secondary amino group and, in addition, at least one polar functional group, C) from 0.1 to 10% by weight, based on the overall weight of components A) to F), of at least one compound selected from diamines, polyamines and mixtures thereof, D) from 0 to 20% by weight, based on the overall weight of components A) to F), of at least one further compound other than A), B), C) and E), having at least two isocyanate-reactive groups, which are hydroxyl groups and mixtures of hydroxyl groups and/or primary or secondary amino groups, E) from 0 to 20% by weight, based on the overall weight of components A) to F), of at least one compound having an isocyanate-reactive group, F) from 10 to 50% by weight, based on the overall weight of components A) to F), of at least one polyisocyanate, and the salts thereof, wherein the sum of the hydroxyl numbers of components A) and D) lies within a range from 121 to 300 mg of KOH/g.
摘要:
Compounds having alcoholic hydroxyl groups are esterified with acrylic or methacrylic acid in the presence of copper(II) salts or mixtures thereof as polymerization inhibitors and in the presence of a hydrocarbon as a water-entraining agent with removal of the water of reaction at from 90 to 150° C. After the esterification, the copper salt is precipitated as copper sulfide and is separated off from the ester. The light-color (meth)acrylates resulting in the high yields are particularly suitable for coatings containing colored pigment on substrates such as wood, paper, mineral building materials, plastics or metal.
摘要:
A process for preparing radiation-curable, urethane-functional prepolymers by reacting an isocyanate-functional component A with an OH-containing component B, wherein either component A embraces two different isocyanate compounds A1 or one isocyanate compound A1 and at least one isocyanate compound A2 or component B embraces at least two different compounds B1. Also, the prepolymers obtainable by the process and the radiation-curable formulations comprising them. Furthermore, the use of the radiation-curable formulations for coating substrates, a method of coating substrates, and the coated substrates themselves.
摘要:
The present invention provides a curable polyurethane polymer containing in copolymerized form A) from 10 to 60% by weight of at least one hydroxyl-containing prepolymer having at least one &agr;,&bgr;-ethylenically unsaturated double bond, B) from 0.1 to 30% by weight of at least one compound having at least one isocyanate-reactive hydroxyl group and/or primary or secondary amino group and, in addition, at least one polar functional group per molecule, C) from 0.1 to 30% by weight of at least one compound selected from diamines, polyamines and mixtures thereof, D) from 0 to 10% by weight of at least one further compound other than A), B), C) and E) having at least two isocyanate-reactive groups, which are hydroxyl groups and mixtures of hydroxyl groups with primary and/or secondary amino groups, E) from 0 to 20% by weight of at least one compound having an isocyanate-reactive group, F) from 10 to 65% by weight of at least one compound having at least two isocyanate groups, and the salts thereof, wherein the ratio of isocyanate group equivalents of component F) to equivalents of isocyanate-reactive groups of components A) to E) is in a range from 0.4:1 to 0.9:1, polymer dispersions comprising at least one such polymer, and the use thereof.
摘要:
Radiation-curable formulations based on ethylenically unsaturated prepolymers and difunctional esters of ethylenically unsaturated carboxylic acids with diols having a linear alkylene chain of 7 to 14 carbon atoms, a process for coating substrates using these radiation-curable formulations, and their use as automotive topcoats.
摘要:
The invention relates to a powder-slurry that can be hardened by actinic radiation or by thermal means, comprising (I) components containing functional groups (A) which render them hardenable by actinic radiation and components containing complementary functional groups (B) which render them thermally hardenable, in a weight ratio of 50:1 to 1:50 and/or comprising (II) components containing the functional groups (A) and (B) which render them thermally hardenable and hardenable by actinic radiation in a molar ratio of 100:1 to 1:100.
摘要:
Aqueous dispersions of mixtures of (a) polyurethanes having hydrophilic groups which result in water dispersibility of the polyurethane and (b) radiation-curable (meth)acrylate prepolymers which are dilutable in at least 5% by weight of water, such as hydroxyl-containing polyether acrylates, are suitable, owing to their penetration behavior and their high solids absorption in paper, for use as radiation-curable coating or impregnating materials for paper substrates.
摘要:
A mixture of acrylic or methacrylic compounds, containing from 40 to 95% by weight, based on the total amount of the acrylic or methacrylic compounds, of epoxide (meth)acrylates, is obtainable by a process comprising the process stepsa) esterification of hydroxy compounds with acrylic acid or methacrylic acid,b) if required, subsequent addition of further acrylic acid or methacrylic acid andc) subsequent reaction of the excess acrylic or methacrylic acid with epoxides in the presence of the esterification product of a).
摘要:
Aqueous polymer dispersions comprising a) 50–70% by weight of polymer particles composed of at least two different (co)polymers having glass transition temperatures each above 50° C. and synthesized from at least 80% by weight of at least one principal monomer, 0.1–10% by weight of at least one auxiliary monomer, and 0–3% by weight of at least one crosslinker molecule, the difference in the glass transition temperatures (Tg) of the different polymers being at least 10° C., and b) 30–50% by weight of at least one polyfunctional (meth)acrylate, the dispersion a) being subjected to physical and/or chemical deodorization.
摘要:
The use of an amine with an average pKA of from 1 to 14 as detergency booster, preferably in textile detergents, especially in color detergents, and detergent formulations containing these amines.