Moulding materials and spinning materials containing cellulose
    4.
    发明授权
    Moulding materials and spinning materials containing cellulose 失效
    含纤维素的成型材料和纺丝材料

    公开(公告)号:US5679146A

    公开(公告)日:1997-10-21

    申请号:US644260

    申请日:1996-05-10

    CPC分类号: C08L1/02 D01F2/00

    摘要: Moulding material and spinning material respectively containing cellulose, an aqueous tertiary amine-oxide, a non-solvent and a stabiliser, characterised in that, one or more stabilisers are provided which altogether have a basic and antioxidant action with the proviso that the basic stabiliser is not phosphate. The moulding material and spinning material respectively according to the invention are thermally stabilised against a runaway of the decomposition reaction. The degradation of the cellulose and of the amine-oxide is also largely prevented.

    摘要翻译: 分别含有纤维素,叔胺氧化物,非溶剂和稳定剂的成型材料和纺丝材料,其特征在于,提供一种或多种稳定剂,其总共具有碱性和抗氧化作用,条件是碱性稳定剂是 不是磷酸盐。 分别根据本发明的成型材料和纺丝材料对于分解反应的失控而进行热稳定化。 纤维素和氧化胺的降解也大大地被防止。

    Process for the purification of aqueous solutions of amine-oxides
    5.
    发明授权
    Process for the purification of aqueous solutions of amine-oxides 失效
    纯化氧化胺水溶液的方法

    公开(公告)号:US5503749A

    公开(公告)日:1996-04-02

    申请号:US424266

    申请日:1995-04-19

    IPC分类号: B01D61/24 D01F13/02 B01D15/04

    摘要: A process for the purification of aqueous solutions of amine-oxides, characterized in that said solutions are contacted with an aqueous purification solution of an alkali hydroxide and/or ion pair reagent by means of an anion active membrane. By means of the process according to the invention, an efficient separation, particularly of anions of lower carboxylic acids and inorganic acids, can be achieved.

    摘要翻译: PCT No.PCT / AT94 / 00105 Sec。 371日期1995年04月19日 102(e)1995年4月19日PCT PCT 1994年8月2日PCT公布。 出版物WO95 / 05888 日本1993年3月2日。一种用于纯化氧化胺水溶液的方法,其特征在于所述溶液通过阴离子活性膜与碱金属氢氧化物和/或离子对试剂的水性纯化溶液接触。 通过本发明的方法,可以实现有效的分离,特别是低级羧酸和无机酸的阴离子。

    Process for the production of cellulose moulded bodies
    6.
    发明授权
    Process for the production of cellulose moulded bodies 失效
    生产纤维素成型体的方法

    公开(公告)号:US5766530A

    公开(公告)日:1998-06-16

    申请号:US471842

    申请日:1995-06-06

    IPC分类号: D01D4/02 D01F2/00 B29C47/00

    CPC分类号: D01F2/00

    摘要: The invention is concerned with a process for the production of cellulose moulded bodies wherein a suspension of cellulose in an aqueous solution of a tertiary amine-oxide is transformed into a mouldable solution, said solution being extruded by means of a forming tool and conducted into a precipitation bath. The process is characterized in that at least part of the materials in devices and pipes for the transportation and processing of the solution, which material is in contact with the mouldable solution contains at a minimum of 90% up to a depth of at least 0,5 .mu.m, preferably more than 1 .mu.m, at least one element of the group consisting of titanium, zirconium, chromium and nickel in elementary form and/or in the form of compounds provided that the remaining of the material does not contain any of the elements of the group consisting of copper, molybdenum, tungsten or cobalt. By means of the use of certain elements and compounds according to the invention, it is possible to control the occurrence and the extent of exothermal degradation reactions in the cellulose solution.

    摘要翻译: 本发明涉及生产纤维素模塑体的方法,其中将纤维素在叔胺氧化物的水溶液中的悬浮液转化成可模制的溶液,所述溶液通过成形工具挤出并进入 沉淀浴 该方法的特征在于,用于运输和处理溶液的装置和管道中的至少一部分材料,该材料与可成型溶液接触,包含至少90%,至少为0的深度, 5微米,优选大于1微米,元素形式和/或化合物形式的钛,锆,铬和镍中的至少一种元素,条件是剩余的材料不含任何 由铜,钼,钨或钴组成的组元素。 通过使用根据本发明的某些元素和化合物,可以控制纤维素溶液中放热降解反应的发生和程度。

    Moulding materials and spinning materials containing cellulose
    7.
    发明授权
    Moulding materials and spinning materials containing cellulose 失效
    含纤维素的成型材料和纺丝材料

    公开(公告)号:US5556452A

    公开(公告)日:1996-09-17

    申请号:US293056

    申请日:1994-08-19

    CPC分类号: C08L1/02 D01F2/00

    摘要: Moulding material and spinning material respectively containing cellulose, an aqueous tertiary amine-oxide, a non-solvent and a stabiliser, characterised in that, one or more stabilisers are provided which altogether have a basic and antioxidant action with the proviso that the basic stabiliser is not phosphate. The moulding material and spinning material respectively according to the invention are thermally stabilised against a runaway of the decomposition reaction. The degradation of the cellulose and of the amine-oxide is also largely prevented.

    摘要翻译: 分别含有纤维素,叔胺氧化物,非溶剂和稳定剂的成型材料和纺丝材料,其特征在于提供一种或多种稳定剂,其总共具有碱性和抗氧化作用,条件是碱性稳定剂是 不是磷酸盐。 分别根据本发明的成型材料和纺丝材料对于分解反应的失控而进行热稳定化。 纤维素和氧化胺的降解也大大地被防止。

    Process for selective separation of morpholine
    10.
    发明授权
    Process for selective separation of morpholine 失效
    选择性分离吗啉的方法

    公开(公告)号:US6113799A

    公开(公告)日:2000-09-05

    申请号:US843850

    申请日:1997-04-17

    CPC分类号: C07D295/023 C07D295/28

    摘要: The invention is concerned with a process for the selective separation of morpholine from an aqueous solution containing morpholine, N-methylmorpholine and N-methylmorpholine-N-oxide, characterized by the following steps:(A) passing said aqueous solution over a cation exchanger capable of adsorbing morpholine in such an amount until it cannot be charged substantially with morpholine any more and an eluate substantially free from morpholine but containing N-methyhnorpholine and N-methylmorpholine-N-oxide is obtained, and(B) regenerating the cation exchanger charged with morpholine and reusing it in step (A).

    摘要翻译: 本发明涉及从含有吗啉,N-甲基吗啉和N-甲基吗啉-N-氧化物的水溶液中选择性分离吗啉的方法,其特征在于以下步骤:(A)使所述水溶液通过具有阳离子交换能力 吸附吗啉直到不能充分地加入吗啉,得到基本上不含吗啉但含有N-甲基吗啉-N-甲基吗啉-N-氧化物的洗脱液,(B)再生阳离子交换剂, 吗啉并在步骤(A)中重复使用。