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    Polymer compositions, method of manufacture, and articles formed therefrom
    1.
    发明授权
    Polymer compositions, method of manufacture, and articles formed therefrom 有权
    聚合物组合物，制造方法和由其形成的制品

    公开(公告)号：US08067493B2

    公开(公告)日：2011-11-29

    申请号：US12116568

    申请日：2008-05-07

    申请人： Yantao Zhu ,  Bernard Schrauwen ,  Jos van Gisbergen

    发明人： Yantao Zhu ,  Bernard Schrauwen ,  Jos van Gisbergen

    IPC分类号： C08K3/30

    CPC分类号： C08L55/02 ,  B82Y30/00 ,  C08K3/013 ,  C08K5/0008 ,  C08L27/00 ,  C08L27/18 ,  C08L51/04 ,  C08L51/06 ,  C08L67/02 ,  C08L69/00 ,  C08L2666/02 ,  C08L2666/14

    摘要： A composition comprises, based on the total weight of the composition: from 10 to 80 wt. % of a modified polybutylene terephthalate copolymer that (1) is derived from polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate and polyethylene terephthalate copolymers and (2) has at least one residue derived from the polyethylene terephthalate component; from 10 to 80 wt. % of a polycarbonate; from 0 to 20 wt. % of an impact modifier; from 1 to less than 25 wt. % of a reinforcing filler; from 0.1 to less than 2.5 wt. % of a fibrillated fluoropolymer; from 0 to 5 wt. % of an additive selected from the group consisting of antioxidants, mold release agents, colorants, quenchers, stabilizers, and combinations thereof. The composition has a heat deflection temperature of at least 110° C., measured in accordance with to ASTM D648 on 3.2 mm thick molded bars at 0.455 MPa.

    摘要翻译： 基于组合物的总重量，组合物包含：10至80wt。 （1）衍生自聚对苯二甲酸乙二醇酯和聚对苯二甲酸乙二醇酯共聚物的聚对苯二甲酸乙二醇酯组分的改性聚对苯二甲酸丁二醇酯共聚物的％;（2）至少一种衍生自聚对苯二甲酸乙二醇酯组分的残基; 10至80wt。 ％的聚碳酸酯; 0至20wt。 ％抗冲改性剂; 1至小于25wt。 ％的增强填料; 从0.1至小于2.5重量％ ％的原纤化含氟聚合物; 0至5wt。 ％的选自抗氧化剂，脱模剂，着色剂，猝灭剂，稳定剂及其组合的添加剂。 该组合物具有至少110℃的热变形温度，根据ASTM D648在0.45mm MPa的3.2mm厚的模制棒上测量。

    Polymer Compositions, Method of Manufacture, and Articles Formed Therefrom
    2.
    发明申请
    Polymer Compositions, Method of Manufacture, and Articles Formed Therefrom 有权
    聚合物组合物，制造方法和形成的制品

    公开(公告)号：US20080246181A1

    公开(公告)日：2008-10-09

    申请号：US12116568

    申请日：2008-05-07

    申请人： Yantao Zhu ,  Bernard Schrauwen ,  Jos van Gisbergen

    发明人： Yantao Zhu ,  Bernard Schrauwen ,  Jos van Gisbergen

    IPC分类号： C08K3/08 ,  C08L69/00 ,  C08L33/08 ,  C08K3/26 ,  C08K3/22 ,  B29C45/00 ,  C08K3/34 ,  C08K3/04 ,  C08K3/30

    CPC分类号： C08L55/02 ,  B82Y30/00 ,  C08K3/013 ,  C08K5/0008 ,  C08L27/00 ,  C08L27/18 ,  C08L51/04 ,  C08L51/06 ,  C08L67/02 ,  C08L69/00 ,  C08L2666/02 ,  C08L2666/14

    摘要： A composition comprises, based on the total weight of the composition: from 10 to 80 wt. % of a modified polybutylene terephthalate copolymer that (1) is derived from polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate and polyethylene terephthalate copolymers and (2) has at least one residue derived from the polyethylene terephthalate component; from 10 to 80 wt. % of a polycarbonate; from 0 to 20 wt. % of an impact modifier; from 1 to less than 25 wt. % of a reinforcing filler; from 0.1 to less than 2.5 wt. % of a fibrillated fluoropolymer; from 0 to 5 wt. % of an additive selected from the group consisting of antioxidants, mold release agents, colorants, quenchers, stabilizers, and combinations thereof. The composition has a heat deflection temperature of at least 110° C., measured in accordance with to ASTM D648 on 3.2 mm thick molded bars at 0.455 MPa.

    摘要翻译： 基于组合物的总重量，组合物包含：10至80wt。 （1）衍生自聚对苯二甲酸乙二醇酯和聚对苯二甲酸乙二醇酯共聚物的聚对苯二甲酸乙二醇酯组分的改性聚对苯二甲酸丁二醇酯共聚物的％;（2）至少一种衍生自聚对苯二甲酸乙二醇酯组分的残基; 10至80wt。 ％的聚碳酸酯; 0至20wt。 ％抗冲改性剂; 1至小于25wt。 ％的增强填料; 从0.1至小于2.5重量％ ％的原纤化含氟聚合物; 0至5wt。 ％的选自抗氧化剂，脱模剂，着色剂，猝灭剂，稳定剂及其组合的添加剂。 该组合物具有至少110℃的热变形温度，根据ASTM D648在0.45mm MPa的3.2mm厚的模制棒上测量。

    Polymer Compositions, Method of Manufacture, and Articles Formed Therefrom
    3.
    发明申请
    Polymer Compositions, Method of Manufacture, and Articles Formed Therefrom 有权
    聚合物组合物，制造方法和形成的制品

    公开(公告)号：US20080242789A1

    公开(公告)日：2008-10-02

    申请号：US12116534

    申请日：2008-05-07

    申请人： Yantao Zhu ,  Bernard Schrauwen ,  Jos van Gisbergen

    发明人： Yantao Zhu ,  Bernard Schrauwen ,  Jos van Gisbergen

    IPC分类号： C08K3/34 ,  C08L67/00 ,  B28B1/00

    CPC分类号： C08L67/02 ,  C08L27/00 ,  C08L51/04 ,  C08L51/06 ,  C08L55/02 ,  C08L69/00 ,  C08L2666/02

    摘要： A composition comprises, based on the total weight of the composition, from 10 to 80 wt. % of a polyester; from 10 to 80 wt. % of a polycarbonate; from 0 to 20 wt. % of an impact modifier; from 1 to less than 25 wt. % of a reinforcing filler; from 0.1 to less than 2.5 wt. % of a fibrillated fluoropolymer; from 0 to 5 wt. % of an additive selected from the group consisting of antioxidants, mold release agents, colorants, quenchers, stabilizers, and combinations thereof, wherein the composition has a heat deflection temperature of at least 110° C., measured in accordance with to ASTM D648 on 3.2 mm thick molded bars at 0.455 MPa.

    摘要翻译： 基于组合物的总重量，组合物包含10至80wt。 ％的聚酯; 10至80wt。 ％的聚碳酸酯; 0至20wt。 ％抗冲改性剂; 1至小于25wt。 ％的增强填料; 从0.1至小于2.5重量％ ％的原纤化含氟聚合物; 0至5wt。 选自抗氧化剂，脱模剂，着色剂，猝灭剂，稳定剂及其组合的添加剂的％，其中该组合物具有至少110℃的热变形温度，根据ASTM D648测量为 厚度为3.2毫米的模压棒，厚度为0.455 MPa。

    Polymer compositions, method of manufacture, and articles formed therefrom
    4.
    发明授权
    Polymer compositions, method of manufacture, and articles formed therefrom 有权
    聚合物组合物，制造方法和由其形成的制品

    公开(公告)号：US08034866B2

    公开(公告)日：2011-10-11

    申请号：US12116534

    申请日：2008-05-07

    申请人： Yantao Zhu ,  Bernard Schrauwen ,  Jos van Gisbergen

    发明人： Yantao Zhu ,  Bernard Schrauwen ,  Jos van Gisbergen

    IPC分类号： C08K3/30

    CPC分类号： C08L67/02 ,  C08L27/00 ,  C08L51/04 ,  C08L51/06 ,  C08L55/02 ,  C08L69/00 ,  C08L2666/02

    摘要： A composition comprises, based on the total weight of the composition, from 10 to 80 wt. % of a polyester; from 10 to 80 wt. % of a polycarbonate; from 0 to 20 wt. % of an impact modifier; from 1 to less than 25 wt. % of a reinforcing filler; from 0.1 to less than 2.5 wt. % of a fibrillated fluoropolymer; from 0 to 5 wt. % of an additive selected from the group consisting of antioxidants, mold release agents, colorants, quenchers, stabilizers, and combinations thereof, wherein the composition has a heat deflection temperature of at least 110° C., measured in accordance with to ASTM D648 on 3.2 mm thick molded bars at 0.455 MPa.

    摘要翻译： 基于组合物的总重量，组合物包含10至80wt。 ％的聚酯; 10至80wt。 ％的聚碳酸酯; 0至20wt。 ％抗冲改性剂; 1至小于25wt。 ％的增强填料; 从0.1至小于2.5重量％ ％的原纤化含氟聚合物; 0至5wt。 选自抗氧化剂，脱模剂，着色剂，猝灭剂，稳定剂及其组合的添加剂的％，其中该组合物具有至少110℃的热变形温度，根据ASTM D648测量为 厚度为3.2毫米的模压棒，厚度为0.455 MPa。

    THERMOFORMABLE POLYCARBONATE/POLYESTER COMPOSITIONS AND USES
    5.
    发明申请
    THERMOFORMABLE POLYCARBONATE/POLYESTER COMPOSITIONS AND USES 有权
    热稳定性聚碳酸酯/聚酯组合物和用途

    公开(公告)号：US20090026663A1

    公开(公告)日：2009-01-29

    申请号：US11782798

    申请日：2007-07-25

    申请人： Donald Ellington ,  Yantao Zhu

    发明人： Donald Ellington ,  Yantao Zhu

    IPC分类号： C08L69/00 ,  B29C45/00 ,  B29C49/00

    CPC分类号： C08L69/00 ,  C08L23/0846 ,  C08L55/00 ,  C08L67/02 ,  C08L2666/18 ,  C08L2666/02

    摘要： The melt strength and hence the processing window of blends of polycarbonate and PBT can be enhanced without degradation in the surface appearance of the article produced when relatively minor amounts of certain selected polymers are added to the blend. For example, a composition that has a thermoforming processing window of at least 15° C. for an article having a weight that is more than 100 grams, may contain 15 to 80% by weight of a polycarbonate resin; 10 to 80% by weight of polybutylene terephthalate, and 1 to 15% by weight of a semicrystalline melt strength enhancer. The meklt strength enhancer is polyethylene terephthalate (PET), polycyclohexane-dimethyl terephthalate (PCT), polycyclohexanedimethyl terephthalate glycol (PCT-G), and (poly)ethylene co 1,4 cyclohexanedimethylene terephthlate (PET-G), or a combination thereof.

    摘要翻译： 当将相对少量的某些选定的聚合物添加到共混物中时，可以增强聚碳酸酯和PBT的共混物的熔体强度，并因此提高所制造的制品的表面外观，而不会降低聚碳酸酯和PBT的共混物的加工窗口。 例如，对于重量大于100克的制品，具有至少15℃的热成型加工窗口的组合物可以含有15至80重量％的聚碳酸酯树脂; 10〜80重量％的聚对苯二甲酸丁二醇酯和1〜15重量％的半结晶熔融强度增强剂。 其特征是强度增强剂是聚对苯二甲酸乙二醇酯（PET），聚环己烷 - 对苯二甲酸二甲酯（PCT），聚对苯二甲酸环己二醇酯二醇（PCT-G）和（聚）乙烯共聚物1,4-环己烷二亚甲基对苯二甲酸酯（PET-G）或其组合。

    Thermoformable polycarbonate/polyester compositions and uses
    7.
    发明授权
    Thermoformable polycarbonate/polyester compositions and uses 有权
    可热成型聚碳酸酯/聚酯组合物和用途

    公开(公告)号：US07687577B2

    公开(公告)日：2010-03-30

    申请号：US11782798

    申请日：2007-07-25

    申请人： Donald Ellington ,  Yantao Zhu

    发明人： Donald Ellington ,  Yantao Zhu

    IPC分类号： C08L67/02

    CPC分类号： C08L69/00 ,  C08L23/0846 ,  C08L55/00 ,  C08L67/02 ,  C08L2666/18 ,  C08L2666/02

    摘要： The melt strength and hence the processing window of blends of polycarbonate and PBT can be enhanced without degradation in the surface appearance of the article produced when relatively minor amounts of certain selected polymers are added to the blend. For example, a composition that has a thermoforming processing window of at least 15° C. for an article having a weight that is more than 100 grams, may contain 15 to 80% by weight of a polycarbonate resin; 10 to 80% by weight of polybutylene terephthalate, and 1 to 15% by weight of a semicrystalline melt strength enhancer. The melt strength enhancer is polyethylene terephthalate (PET), polycyclohexane-dimethyl terephthalate (PCT), polycyclohexanedimethyl terephthalate glycol (PCT-G), and (poly)ethylene co 1,4 cyclohexanedimethylene terephthlate (PET-G), or a combination thereof.

    摘要翻译： 当将相对少量的某些选定的聚合物添加到共混物中时，可以增强聚碳酸酯和PBT的共混物的熔体强度，并因此提高所制造的制品的表面外观，而不会降低聚碳酸酯和PBT的共混物的加工窗口。 例如，对于重量大于100克的制品，具有至少15℃的热成型加工窗口的组合物可以含有15至80重量％的聚碳酸酯树脂; 10〜80重量％的聚对苯二甲酸丁二醇酯和1〜15重量％的半结晶熔融强度增强剂。 熔融强度增强剂是聚对苯二甲酸乙二醇酯（PET），聚环己烷 - 对苯二甲酸二甲酯（PCT），聚对苯二甲酸环己二醇酯二醇（PCT-G）和（聚）乙烯共聚物1,4-环己烷二亚甲基对苯二甲酸酯（PET-G）或其组合。