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公开(公告)号：US08164881B2
公开(公告)日：2012-04-24
申请号：US12302758
申请日：2007-05-25
申请人： Yong-Sheng Hu , Yu-Guo Guo , Lizhen Fan , Joachim Maier , Philipp Adelhelm , Bernd Smarsly , Markus Antonietti
发明人： Yong-Sheng Hu , Yu-Guo Guo , Lizhen Fan , Joachim Maier , Philipp Adelhelm , Bernd Smarsly , Markus Antonietti
IPC分类号： H01G9/00
CPC分类号： H01G11/26 , C01B32/05 , H01G11/24 , H01G11/32 , H01G11/34 , H01G11/48 , H01G11/86 , H01M4/04 , H01M4/583 , H01M4/587 , H01M10/0525 , Y02E60/13 , Y10T428/24998 , Y10T428/249981
摘要： An extremely high-performance polyaniline electrode was prepared by potentiostatic deposition of aniline on hierarchically porous carbon monolith (HPCM), which was carbonized from mesophase pitch. A capacitance value of 2200 F g−1 of polyaniline was obtained at a power density of 0.47 kW kg−1 and an energy density of 300 Wh kg−1. This active material deposited on HPCM also has an advantageous high stability. These superior advantages can be attributed to the backbone role of HPCM. This method also has the advantages of not introducing any binder, thus contributing to the increase of ionic conductivity and power density. High specific capacitance, high power and energy density, high stability, and low cost of active material make it very promising for supercapacitors.
摘要翻译： 通过在分层多孔碳整料（HPCM）上静电沉积苯胺制备了极高性能的聚苯胺电极，其由中间相沥青碳化。 在功率密度为0.47 kW kg-1，能量密度为300 Wh kg-1时，得到聚苯胺的2200 F g-1的电容值。 沉积在HPCM上的这种活性材料也具有有利的高稳定性。 这些优势可以归功于HPCM的骨干作用。 该方法还具有不引入任何粘合剂的优点，因此有助于提高离子电导率和功率密度。 高比电容，高功率和能量密度，高稳定性和低成本的活性材料使其非常有前途的超级电容器。
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公开(公告)号：US20100008021A1
公开(公告)日：2010-01-14
申请号：US12302758
申请日：2007-05-25
申请人： Yong-Sheng Hu , Yu-Guo Guo , Lizhen Fan , Joachim Maier , Philipp Adelhelm , Bernd Smarsly , Markus Antonietti
发明人： Yong-Sheng Hu , Yu-Guo Guo , Lizhen Fan , Joachim Maier , Philipp Adelhelm , Bernd Smarsly , Markus Antonietti
CPC分类号： H01G11/26 , C01B32/05 , H01G11/24 , H01G11/32 , H01G11/34 , H01G11/48 , H01G11/86 , H01M4/04 , H01M4/583 , H01M4/587 , H01M10/0525 , Y02E60/13 , Y10T428/24998 , Y10T428/249981
摘要： An extremely high-performance polyaniline electrode was prepared by potentiostatic deposition of aniline on hierarchically porous carbon monolith (HPCM), which was carbonized from mesophase pitch. A capacitance value of 2200 F g−1 of polyaniline was obtained at a power density of 0.47 kW kg−1 and an energy density of 300 Wh kg−1. This active material deposited on HPCM also has an advantageous high stability. These superior advantages can be attributed to the backbone role of HPCM. This method also has the advantages of not introducing any binder, thus contributing to the increase of ionic conductivity and power density. High specific capacitance, high power and energy density, high stability, and low cost of active material make it very promising for supercapacitors.
摘要翻译： 通过在分层多孔碳整料（HPCM）上静电沉积苯胺制备了极高性能的聚苯胺电极，其由中间相沥青碳化。 在功率密度为0.47 kW kg-1，能量密度为300 Wh kg-1时，得到聚苯胺的2200 F g-1的电容值。 沉积在HPCM上的这种活性材料也具有有利的高稳定性。 这些优势可以归功于HPCM的骨干作用。 该方法还具有不引入任何粘合剂的优点，因此有助于提高离子电导率和功率密度。 高比电容，高功率和能量密度，高稳定性和低成本的活性材料使其非常有前途的超级电容器。
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公开(公告)号：US20090269667A1
公开(公告)日：2009-10-29
申请号：US12302769
申请日：2007-05-25
申请人： Markus Antonietti , Bernd Smarsly , Philipp Adelhelm , Joachim Maier , Sarmimala Hore , Yong-Sheng Hu , Yu-Guo Guo
发明人： Markus Antonietti , Bernd Smarsly , Philipp Adelhelm , Joachim Maier , Sarmimala Hore , Yong-Sheng Hu , Yu-Guo Guo
CPC分类号： H01G11/26 , C01B32/05 , H01G11/24 , H01G11/32 , H01G11/34 , H01G11/48 , H01G11/86 , H01M4/04 , H01M4/583 , H01M4/587 , H01M10/0525 , Y02E60/13 , Y10T428/24998 , Y10T428/249981
摘要： This disclosure relates to a porous electrically conductive carbon material having interconnected pores in first and second size ranges from 10 μm to 100 nm and from less than 100 nm to 3 nm and a graphene structure and to diverse uses of the material such as an electrode in a lithium-ion battery and a catalyst support, e.g. for the oxidation of methanol in a fuel cell. The carbon material has been heat treated to effect conversion to non-graphitic carbon with the required degree of order at a temperature in the range from 600° C. to 1000° C. A lithium-ion battery and an electrode for a lithium-ion battery are also claimed.
摘要翻译： 本公开涉及一种多孔导电碳材料，其具有在10μm至100nm和小于100nm至3nm的第一和第二尺寸范围内的互连孔，以及石墨烯结构以及诸如电极之类的材料的不同用途 锂离子电池和催化剂载体，例如 用于燃料电池中甲醇的氧化。 碳材料已经被热处理以在600℃至1000℃的温度范围内以所需的程度转化为非石墨碳。锂离子电池和锂离子电极 电池也被声称。
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公开(公告)号：US20090176079A1
公开(公告)日：2009-07-09
申请号：US12302403
申请日：2007-04-28
CPC分类号： C04B38/0022 , B01J20/20 , B01J20/28042 , B01J20/28066 , B01J20/28092 , B01J20/282 , B01J20/3007 , B01J2220/82 , C04B35/524 , C04B2111/00793 , C04B2111/0081 , C04B2111/00853 , C04B2235/6021 , C04B2235/6562 , C04B2235/6567 , H01G9/04 , H01G11/34 , Y02E60/13 , Y10T428/249921 , Y10T428/249953 , C04B35/52 , C04B38/0064 , C04B38/0074
摘要： The present invention relates to a process based on phase separation for the production of porous carbon monoliths, to the monoliths produced in accordance with the invention, and to the use thereof.
摘要翻译： 本发明涉及一种用于生产多孔碳整料的相分离方法，本发明涉及根据本发明生产的整料，以及其用途。
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公开(公告)号：US08834748B2
公开(公告)日：2014-09-16
申请号：US12995043
申请日：2009-05-25
申请人： Gero Nordmann , Norbert Wagner , Alexander Traut , Christian Bittner , Ingo Münster , Bernd Smarsly , Yude Wang , Markus Antonietti , Simone Mascotto
发明人： Gero Nordmann , Norbert Wagner , Alexander Traut , Christian Bittner , Ingo Münster , Bernd Smarsly , Yude Wang , Markus Antonietti , Simone Mascotto
CPC分类号： C23C18/1254 , C23C18/1216 , Y10T428/24355 , Y10T428/24364
摘要： The present invention relates to a process for preparing transparent conductive oxides, comprising the following steps in the sequence of a-b-c:(a) reaction of at least one starting compound (A) comprising at least one metal or semimetal M and optionally of a dopant (D) comprising at least one doping element M′, where at least one M′ is different than M, in the presence of a block copolymer (B) and of a solvent (C) to form a composite material (K), (b) optional application of the composite material (K) to a substrate (S) and (c) heating of the composite material (K) to a temperature of at least 350° C., wherein the block copolymer (B) comprises at least one alkylene oxide block (AO) and at least one isobutylene block (IB). The present invention further relates to the transparent conductive oxides thus obtainable, and to their use in electronic components, as an electrode material and as a material for antistatic applications. The present invention finally relates to electronic components comprising the transparent conductive oxides.
摘要翻译： 本发明涉及一种制备透明导电氧化物的方法，包括以下顺序的以下步骤：（a）至少一种包含至少一种金属或半金属M和任选的掺杂剂的起始化合物（A） D）包含至少一种掺杂元素M'，其中至少一个M'不同于M，在嵌段共聚物（B）和溶剂（C）的存在下形成复合材料（K），（b） ）可选地将复合材料（K）施加到基底（S）和（c）将复合材料（K）加热至至少350℃的温度，其中嵌段共聚物（B）包含至少一种 氧化烯嵌段（AO）和至少一种异丁烯嵌段（IB）。 本发明还涉及由此获得的透明导电氧化物及其在电子部件中的用途，作为电极材料和用作抗静电应用的材料。 本发明最终涉及包含透明导电氧化物的电子部件。
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公开(公告)号：US20110073814A1
公开(公告)日：2011-03-31
申请号：US12995043
申请日：2009-05-25
申请人： GERO Nordmann , Norbert Wagner , Alexander Traut , Christian Bittner , Ingo Münster , Bernd Smarsly , Yude Wang , Markus Antonietti , Simone Mascotto
发明人： GERO Nordmann , Norbert Wagner , Alexander Traut , Christian Bittner , Ingo Münster , Bernd Smarsly , Yude Wang , Markus Antonietti , Simone Mascotto
IPC分类号： H01B1/22
CPC分类号： C23C18/1254 , C23C18/1216 , Y10T428/24355 , Y10T428/24364
摘要： The present invention relates to a process for preparing transparent conductive oxides, comprising the following steps in the sequence of a-b-c: (a) reaction of at least one starting compound (A) comprising at least one metal or semimetal M and optionally of a dopant (D) comprising at least one doping element M′, where at least one M′ is different than M, in the presence of a block copolymer (B) and of a solvent (C) to form a composite material (K), (b) optional application of the composite material (K) to a substrate (S) and (c) heating of the composite material (K) to a temperature of at least 350° C., wherein the block copolymer (B) comprises at least one alkylene oxide block (AO) and at least one isobutylene block (IB). The present invention further relates to the transparent conductive oxides thus obtainable, and to their use in electronic components, as an electrode material and as a material for antistatic applications. The present invention finally relates to electronic components comprising the transparent conductive oxides.
摘要翻译： 本发明涉及一种制备透明导电氧化物的方法，包括以下顺序的以下步骤：（a）至少一种包含至少一种金属或半金属M和任选的掺杂剂的起始化合物（A） D）包含至少一种掺杂元素M'，其中至少一个M'不同于M，在嵌段共聚物（B）和溶剂（C）的存在下形成复合材料（K），（b） ）可选地将复合材料（K）施加到基底（S）和（c）将复合材料（K）加热至至少350℃的温度，其中嵌段共聚物（B）包含至少一种 氧化烯嵌段（AO）和至少一种异丁烯嵌段（IB）。 本发明还涉及由此获得的透明导电氧化物及其在电子部件中的用途，作为电极材料和用作抗静电应用的材料。 本发明最终涉及包含透明导电氧化物的电子部件。
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公开(公告)号：US20120217681A1
公开(公告)日：2012-08-30
申请号：US13508268
申请日：2010-10-26
申请人： Roman Zieba , Felix Major , Evgueni Klimov , Alexander Traut , Laurence Pottie , Bernd Smarsly , Rainer Ostermann
发明人： Roman Zieba , Felix Major , Evgueni Klimov , Alexander Traut , Laurence Pottie , Bernd Smarsly , Rainer Ostermann
IPC分类号： B29C47/00
CPC分类号： D01F9/08 , B82Y30/00 , C01G30/00 , C01P2004/16 , C01P2006/22 , C04B35/457 , C04B35/62231 , C04B35/62236 , C04B35/6225 , C04B35/62254 , C04B35/62259 , C04B35/6263 , C04B35/6264 , C04B35/632 , C04B35/63416 , C04B35/63424 , C04B35/63444 , C04B35/63456 , C04B35/63488 , C04B35/636 , C04B2235/3286 , C04B2235/3293 , C04B2235/3294 , C04B2235/441 , C04B2235/444 , C04B2235/5264 , C04B2235/5296 , C04B2235/9661 , D01D1/02 , D01D5/0038
摘要： The present invention relates to a process for producing metal oxide nanofibers using a sol-gel precursor. The nanofibers produced by the process according to the invention are notable for an increased metal oxide content compared to the prior art.
摘要翻译： 本发明涉及使用溶胶 - 凝胶前体制备金属氧化物纳米纤维的方法。 通过根据本发明的方法生产的纳米纤维与现有技术相比，值得注意的是增加的金属氧化物含量。
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公开(公告)号：US20130220178A1
公开(公告)日：2013-08-29
申请号：US13501688
申请日：2010-10-07
申请人： Roman Zieba , Alexander Traut , Cornelia Röger-Göpfert , Torsten Brezesinski , Bernadette Landschreiber , Claudia Grote , Georg Garnweitner , Alexandra Seeber , Bernd Smarsly , Christoph Wiedmann , Till von Graberg , Jan Haetge
发明人： Roman Zieba , Alexander Traut , Cornelia Röger-Göpfert , Torsten Brezesinski , Bernadette Landschreiber , Claudia Grote , Georg Garnweitner , Alexandra Seeber , Bernd Smarsly , Christoph Wiedmann , Till von Graberg , Jan Haetge
IPC分类号： C01B13/32 , C01G33/00 , C01G35/00 , C01G27/02 , C01G25/02 , C01B13/00 , C01F7/02 , C01G49/06 , C01G37/033 , C01G31/02 , C01G55/00 , C01G30/00 , C01G23/053 , C01G45/02
CPC分类号： C01B13/32 , B82Y30/00 , C01B13/00 , C01F7/02 , C01G1/02 , C01G15/00 , C01G19/02 , C01G21/02 , C01G23/047 , C01G23/053 , C01G25/02 , C01G27/02 , C01G30/005 , C01G31/02 , C01G33/00 , C01G35/00 , C01G37/02 , C01G37/033 , C01G45/02 , C01G49/02 , C01G49/06 , C01G55/004 , C01P2004/64 , C01P2006/60
摘要： The current invention relates to a method of making metal oxide nanoparticles comprising the reaction of—at least one metal oxide precursor (P) containing at least one metal (M) with—at least one monofunctional alcohol (A) wherein the hydroxy group is bound to a secondary, tertiary or alpha-unsaturated carbon atom—in the presence of at least one aliphatic compound (F) according to the formula Y1—R1—X—R2—Y2, wherein—R1 and R2 each are the same or different and independently selected from aliphatic groups with from 1 to 20 carbon atoms, —Y1 and Y2 each are the same or different and independently selected from OH, NH2 and SH, and —X is selected from the group consisting of chemical bond, —O—, —S—, —NR3—, and CR4R5, wherein R3, R4 and R5 each are the same or different and represent a hydrogen atom or an aliphatic group with from 1 to 20 carbon atoms which optionally carries functional groups selected from OH, NH2 and SH. This invention also relates to metal oxide nanoparticles, to a method of making dispersions of said nanoparticles and to dispersions containing them.
摘要翻译： 本发明涉及一种制备金属氧化物纳米颗粒的方法，其包括至少一种含有至少一种金属（M）与至少一种单官能醇（A）的金属氧化物前体（P）的反应，其中羟基被结合 在至少一种根据式Y1-R1-X-R2-Y2的脂肪族化合物（F）的存在下，在仲，叔或不饱和碳原子的存在下，R 1和R 2各自相同或不同， 独立地选自具有1至20个碳原子的脂族基团，-Y 1和Y 2各自相同或不同且独立地选自OH，NH 2和SH，并且-X选自化学键，-O-， -S-，-NR 3 - 和CR 4 R 5，其中R 3，R 4和R 5各自相同或不同，并且表示氢原子或具有1至20个碳原子的脂族基团，其任选地携带选自OH，NH 2和 SH。 本发明还涉及金属氧化物纳米颗粒，涉及制备所述纳米颗粒的分散体和含有它们的分散体的方法。
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