摘要:
Porous materials are fabricated using interpenetrating inorganic-organic composite gels. A mixture or precursor solution including an inorganic gel precursor, an organic polymer gel precursor, and a solvent is treated to form an inorganic wet gel including the organic polymer gel precursor and the solvent. The inorganic wet gel is then treated to form a composite wet gel including an organic polymer network in the body of the inorganic wet gel, producing an interpenetrating inorganic-organic composite gel. The composite wet gel is dried to form a composite material including the organic polymer network and an inorganic network component. The composite material can be treated further to form a porous composite material, a porous polymer or polymer composite, a porous metal oxide, and other porous materials.
摘要:
Methods of producing a metal oxide are disclosed. The method comprises dissolving a metal salt in a reaction solvent to form a metal salt/reaction solvent solution. The metal salt is converted to a metal oxide and a caustic solution is added to the metal oxide/reaction solvent solution to adjust the pH of the metal oxide/reaction solvent solution to less than approximately 7.0. The metal oxide is precipitated and recovered. A method of producing adsorption media including the metal oxide is also disclosed, as is a precursor of an active component including particles of a metal oxide.
摘要:
The current invention relates to a method of making metal oxide nanoparticles comprising the reaction of—at least one metal oxide precursor (P) containing at least one metal (M) with—at least one monofunctional alcohol (A) wherein the hydroxy group is bound to a secondary, tertiary or alpha-unsaturated carbon atom—in the presence of at least one aliphatic compound (F) according to the formula Y1—R1—X—R2—Y2, wherein—R1 and R2 each are the same or different and independently selected from aliphatic groups with from 1 to 20 carbon atoms, —Y1 and Y2 each are the same or different and independently selected from OH, NH2 and SH, and —X is selected from the group consisting of chemical bond, —O—, —S—, —NR3—, and CR4R5, wherein R3, R4 and R5 each are the same or different and represent a hydrogen atom or an aliphatic group with from 1 to 20 carbon atoms which optionally carries functional groups selected from OH, NH2 and SH. This invention also relates to metal oxide nanoparticles, to a method of making dispersions of said nanoparticles and to dispersions containing them.
摘要:
An optical material is provided. The optical material includes a nanoparticle-resin composite material in which metal oxide nanoparticles are dispersed in a polymer, wherein the metal oxide nanoparticles are crystalline and have a particle diameter of 1×10−8 m or less, wherein surfaces of the metal oxide nanoparticles are coated with a surfactant, and wherein the metal oxide nanoparticles are crystallized at a temperature greater than or equal to 200° C. and less than or equal to 400° C. A light assembly including the nanoparticle-resin composite material is also provided.
摘要:
A method of preparing a wet-processible metal oxide solution and a method of fabricating a film using the same are provided. A metal oxide that has been widely used as a photocatalyst is improved and a metal oxide solution having new functionality is formed. The metal oxide solution is transparent, wet-processible, and facilitates electron transfer. The metal oxide solution can be applied in various ways to an electronic device and is well-suited for application to an electronic device using organic materials. Also, a titanium oxide solution functions to remove and block oxygen and moisture. Thus, when it is applied to an electronic device using organic materials that are vulnerable to oxygen and moisture, the lifetime of the device can be increased.
摘要:
Dispersoids having metal-oxygen groups that are suitable for the production of metal oxide thin-films at a low temperature of 200° C. or below and for the production of homogeneous organic-inorganic hybrid materials. The dispersoid having metal-oxygen bonds may be obtained by mixing a metal compound having at least three hydrolyzable groups with at least 0.5 mole but less than 2 moles of water per mole of the metal compound in an organic solvent, in the absence of an acid, a base, and/or a dispersion stabilizer, and at a temperature at or below the temperature at which the metal compound begins to hydrolyze, then raising the temperature to at least the temperature at which hydrolysis begins.
摘要:
A zinc oxide polymer nanocomposite composed of zinc oxide nanoparticles. The zinc oxide nanoparticles of the nanocomposite have an average particle size of about 1 nanometer to about 20 nanometers. Suitable polymers of the nanocomposites have less than about 500 ppm alkali metal. A process is provided for preparing the zinc oxide polymer nanocomposites comprising a) preparing a first combination comprising zinc oxide nanoparticles and a polymer; b) preparing a second combination comprising the first combination and an organic solvent; and c) precipitating the zinc oxide nanoparticles and the polymer out of the second combination. The zinc oxide nanoparticles of the first combination have an average particle size of between about 1 nanometer and about 20 nanometers.
摘要:
The present invention relates to a preparation method of metal oxide, and more specifically to a preparation method of metal oxide comprising the steps of: a) dissolving metal halide in a solvent; b) adding and reacting water or metal hydroxide having strong basicity; c) adding base to the reaction solution and then raising a temperature thereof to form the metal oxide-carbon complex; d) stopping the reaction by inputting a large amount of water or metal hydroxide and raising the temperature thereof; and e) obtaining the metal oxide-carbon complex by a separation and a cleaning.
摘要:
A multi-phase catalyst for the simultaneous conversion of oxides of nitrogen, carbon monoxide, and hydrocarbons is provided. A catalyst composition comprising the multi-phase catalyst and methods of making the catalyst composition are also provided. The multi-phase catalyst may be represented by the general formula of CeyLn1-xAx+sMOZ, wherein Ln is a mixture of elements originally in the form of single-phase mixed lanthanides collected from natural ores, a single lanthanide, or a mixture of lanthanides; A is an element selected from a group consisting of Mg, Ca, Sr, Ba, Li, Na, K, Cs, Rb, or any combination thereof; and M is an element selected from the group consisting of Fe, Mn, Cr, Ni, Co, Cu, V, Zr, Pt, Pd, Rh, Ru, Ag, Au, Al, Ga, Mo, W, Ti, or any combination thereof; x is a number defined by 0≦x 0 and y=0 only when s>0. The multi-phase catalyst can have an overlayer of an oxide having the fluorite structure with a combination of platinum and/or rhodium.
摘要翻译:提供了用于同时转化氮,一氧化碳和烃的氧化物的多相催化剂。 还提供了包含多相催化剂的催化剂组合物和制备催化剂组合物的方法。 多相催化剂可以由CeyLn1-xAx + sMOZ的通式表示,其中Ln是原始以从天然矿石,单一镧系元素或镧系元素混合物的单相混合镧系元素形式的元素的混合物 ; A是选自Mg,Ca,Sr,Ba,Li,Na,K,Cs,Rb或其任何组合的元素; 并且M是选自Fe,Mn,Cr,Ni,Co,Cu,V,Zr,Pt,Pd,Rh,Ru,Ag,Au,Al,Ga,Mo,W,Ti或 其任何组合; x是由0 <= x <1.0定义的数字; y是由0 <= y <10定义的数字; s是由0 <= s <10定义的数字; 其中s = 0,只有当y> 0且y = 0时,只有当s> 0时。 多相催化剂可以具有具有萤石结构的氧化物与铂和/或铑的组合的覆盖层。
摘要:
Exchangeable metal ions are removed from an amorphous composite metal oxide and different metal ions are introduced to manufacture a nanomaterial of composite metal oxide. Based on this method, it is possible to reliably form composite metal oxide nanomaterials over a wide range of compositions.