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公开(公告)号：US4499313A
公开(公告)日：1985-02-12
申请号：US605574
申请日：1984-04-30
IPC分类号： B01J29/00 , B01J29/08 , B01J29/18 , C07B61/00 , C07C27/00 , C07C29/04 , C07C31/02 , C07C35/08 , C07C67/00 , C07C31/10 , C07C31/12 , C07C31/135
CPC分类号： B01J29/08 , B01J29/18 , C07C29/04 , B01J2229/16 , C07C2101/14 , Y02P20/584
摘要： An improved process for producing an alcohol by hydrating an olefin, wherein the improvement comprises hydrating an olefin in the presence of hydrogen-type mordenite or hydrogen-type zeolite Y as a catalyst each having a silica/alumina molar ratio of 20 to 500.
摘要翻译： 一种改进的通过烯烃水合生产醇的方法，其中改进包括在氢型丝光沸石或氢型沸石Y作为催化剂存在下水合烯烃，所述催化剂的二氧化硅/氧化铝摩尔比为20-500。
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公开(公告)号：US4507512A
公开(公告)日：1985-03-26
申请号：US610045
申请日：1984-05-14
IPC分类号： C07C29/04 , C07C31/10 , C07C31/12 , C07C31/135
CPC分类号： C07C29/04 , C07C2101/14
摘要： An improved process for producing an alcohol by hydrating an olefin wherein the improvement comprises hydrating an olefin in the presence of a hydrogen-type catalyst having a silica/alumina molar ratio of 20 to 500 and a solvent using either:A. hydrogen-type mordenite or hydrogen-type zeolite Y, and a sulfone; orB. hydrogen-type crystalline aluminosilicate in which the entrance of the main void is formed by a 10-membered or 12-membered oxygen ring, and a C.sub.2 to C.sub.5 oxy acid or the lactones, lactides, methyl or ethyl esters thereof.
摘要翻译： 一种改进的通过使烯烃水合生产醇的方法，其中改进包括在二氧化硅/氧化铝/摩尔比为20-500的氢型催化剂存在下使烯烃和溶剂使用：氢氧化铝型丝光沸石 或氢型沸石Y和砜; 或B.氢型结晶硅铝酸盐，其中主空隙的入口由10元或12元氧环形成，以及C 2〜C 5的氧酸或其内酯，丙交酯，甲酯或乙酯。
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公开(公告)号：US4225727A
公开(公告)日：1980-09-30
申请号：US82004
申请日：1979-10-05
IPC分类号： C07C67/055
CPC分类号： C07C67/055
摘要： The invention relates to a process for the production of an unsaturated glycol diester by the reaction of a conjugated diene compound, a carboxylic acid and molecular oxygen in the presence of a solid catalyst. For example, 1,4-diacetoxy-2-butene is prepared at high conversion and high selectivity by reacting butadiene, molecular oxygen and acetic acid in the presence of a solid catalyst containing palladium, tellurium and at least one element selected from the group consisting of tin, germanium and lead. The product is an intermediate for the preparation of 1,4-butanediol.
摘要翻译： 本发明涉及通过共轭二烯化合物，羧酸和分子氧在固体催化剂存在下反应制备不饱和二醇二酯的方法。 例如，在含有钯，碲和至少一种选自以下的元素的固体催化剂的存在下，通过丁二烯，分子氧和乙酸的反应，以高转化率和高选择性制备1,4-二乙酰氧基-2-丁烯。 锡，锗和铅。 该产品是制备1,4-丁二醇的中间体。
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公开(公告)号：US4481373A
公开(公告)日：1984-11-06
申请号：US422684
申请日：1982-09-24
摘要： The invention relates to a method for the manufacture of ketones which comprises oxidizing an n-olefin in the presence of a catalyst containing palladium, copper, a halogen, and at least one of specific tertiary amines.
摘要翻译： 本发明涉及一种制造酮的方法，其包括在含有钯，铜，卤素和至少一种特定叔胺的催化剂存在下氧化正烯烃。
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公开(公告)号：US4327231A
公开(公告)日：1982-04-27
申请号：US126822
申请日：1980-03-03
CPC分类号： C07C29/04
摘要： Tertiary alcohols are produced by the hydration of an isoolefin in the presence as catalyst of an acidic cation exchange resin such as a sulfonated styrene-divinylbenzene copolymer, and a polyhydric neo-type alcohol such as neopentyl glycol. The process is useful for separating isobutylene from a hydrocarbon mixture containing its isomers via preparation of the alcohol, separation from the unreacted hydrocarbons and dehydration of the tertiary butyl alcohol to isobutylene.
摘要翻译： 在作为酸性阳离子交换树脂如磺化苯乙烯 - 二乙烯基苯共聚物和多元新型醇如新戊二醇的催化剂存在下，异构烯烃的水合产生叔醇。 该方法可用于通过醇的制备从含有其异构体的烃混合物中分离异丁烯，从未反应的烃中分离并将叔丁醇脱水成异丁烯。
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公开(公告)号：US4270011A
公开(公告)日：1981-05-26
申请号：US157689
申请日：1980-06-09
申请人： Yoshiharu Okumura , Katsumi Kaneko
发明人： Yoshiharu Okumura , Katsumi Kaneko
IPC分类号： C07C29/04
CPC分类号： C07C29/04
摘要： Isobutylene in a C.sub.4 hydrocarbon mixture with n-butenes and butanes is selectively hydrated to tertiary butyl alcohol by carrying out the reaction with water at a temperature not above 100.degree. C. in the presence of an acidic cation exchange resin and a sulfone.
摘要翻译： 在具有正丁烯和丁烷的C4烃混合物中的异丁烯通过在酸性阳离子交换树脂和砜的存在下在不高于100℃的温度下进行与水反应而选择性水合成叔丁醇。
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公开(公告)号：US4358626A
公开(公告)日：1982-11-09
申请号：US290491
申请日：1981-08-06
CPC分类号： C07C29/04
摘要： Secondary alcohols are produced by the hydration of a n-olefin substantially free from an isoolefin in the presence as catalyst of an acidic cation exchange resin such as a sulfonated styrene-divinylbenzene copolymer and in the presence of an oxy acid or lactone thereof such as .gamma.-valerolactone. The process is especially useful for hydrating a n-butene feed or a feed consisting essentially of n-butenes and butane to produce secondary butyl alcohol.
摘要翻译： 在作为酸性阳离子交换树脂如磺化苯乙烯 - 二乙烯基苯共聚物的催化剂的存在下，在其酸或其内酯如γ的存在下，通过水合基本上不含异烯烃的正烯烃来制备仲醇。 戊酸内酯。 该方法对于使正丁烯进料或基本上由正丁烯和丁烷组成的进料水合以产生仲丁醇是特别有用的。
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公开(公告)号：US4284831A
公开(公告)日：1981-08-18
申请号：US146443
申请日：1980-05-05
申请人： Yoshiharu Okumura , Katsumi Kaneko
发明人： Yoshiharu Okumura , Katsumi Kaneko
CPC分类号： C07C29/04
摘要： Tertiary alcohols are produced by the hydration of an isoolefin in the presence as catalyst of an acidic cation exchange resin such as a sulfonated styrene-divinylbenzene copolymer and in the presence of an oxy acid or lactone thereof such as .gamma.-valerolactone. The process is useful for separating isobutylene from a hydrocarbon mixture containing its isomers via preparation of the alcohol, separation from the unreacted hydrocarbons and dehydration of the tertiary butyl alcohol to isobutylene.
摘要翻译： 在作为酸性阳离子交换树脂如磺化苯乙烯 - 二乙烯基苯共聚物的催化剂存在下，并在其内含有γ-氧代内酯的氧酸或其内酯的存在下，通过异构烯烃的水合产生叔醇。 该方法可用于通过醇的制备从含有其异构体的烃混合物中分离异丁烯，从未反应的烃中分离并将叔丁醇脱水成异丁烯。
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公开(公告)号：US4927953A
公开(公告)日：1990-05-22
申请号：US404964
申请日：1989-09-11
CPC分类号： C07F7/1876
摘要： A process for preparing aminopropyl silanes comprises reacting an allylamine with a hydrosilane in the presence of a ruthenium compound having at least one tertiary phosphine ligand as a catalyst. By the proposed process the corresponding gamma-aminopropyl silane can be prepared in a high yield in a short period of reaction time.
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10.发明授权
公开(公告)号：US4638106A
公开(公告)日：1987-01-20
申请号：US769357
申请日：1985-08-26
CPC分类号： B01J29/87 , B01J29/40 , C07C1/20 , B01J2229/123 , B01J2229/34 , C07C2529/40
摘要： A process for improving the catalyst life of zeolites employed in the conversion of alcohols (e.g. methanol) and/or their ether derivatives (e.g. dimethyl ether) wherein a suitable zeolite is modified in a 2-stage procedure by providing a controlled low amount of a coke precursor deposit on the external surface of the zeolite, and then heating this treated zeolite in an inert gas at specifically controlled temperatures for a minimum time is disclosed. A process of employing this modified zeolite to produce lower olefins is also disclosed.
摘要翻译： 用于改善醇（例如甲醇）和/或其醚衍生物（例如二甲醚）的转化中使用的沸石的催化剂寿命的方法，其中合适的沸石在2阶段程序中通过提供受控的低量的 焦炭前体沉积在沸石的外表面上，然后在特定控制的温度下在惰性气体中加热该处理过的沸石最短时间。 还公开了使用该改性沸石制备低级烯烃的方法。
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