摘要:
Disclosed is an alkaline storage battery comprising a negative electrode, a positive electrode, a separator and an alkaline electrolyte solution in a package can. The negative electrode contains a hydrogen storage alloy represented by the following general formula: Ln1-xMgx(Ni1-yTy)z (wherein Ln represents at least one element selected from lanthanoid elements, Ca, Sr, Sc, Y, Ti, Zr and Hf; T represents at least one element selected from V, Nb, Ta, Cr, Mo, Mn, Fe, Co, Al, Ga, Zn, Sn, In, Cu, Si, P and B; and 0
摘要:
Disclosed is an alkaline storage battery comprising a negative electrode, a positive electrode, a separator and an alkaline electrolyte solution in a package can. The negative electrode contains a hydrogen storage alloy represented by the following general formula: Ln1-xMgx(Ni1-yTy)z (wherein Ln represents at least one element selected from lanthanoid elements, Ca, Sr, Sc, Y, Ti, Zr and Hf; T represents at least one element selected from V, Nb, Ta, Cr, Mo, Mn, Fe, Co, Al, Ga, Zn, Sn, In, Cu, Si, P and B; and 0
摘要:
In the alkaline storage battery system, zinc (Zn) is added to a nickel positive electrode 11 with an addition amount of 8% by mass or less with respect to the mass of nickel. A hydrogen storage alloy of a negative electrode 12 has an A5B19 type crystal structure, with a stoichiometric ratio (B/A) representing the molar ratio of component B to component A ranging from 3.6 to 3.9, inclusive, and is represented by a general formula of Ln1-xMgxNiy-aMa (where Ln is an element selected from rare earth elements including Y, and M is at least one kind of element selected from Al, Co, Mn, and Zn) in which the content of the element M is 1.0% by mass or less. An electrolyte has a concentration of 6.5 mol/L or less and contains Li of 0.3 mol/L or more, and the alkaline storage battery system is arranged to control partial charging-discharging.
摘要:
To provide a hydrogen storage alloy for an alkaline storage battery that improves output power by pulverization of the alloy in the initial stage of partial charge and discharge cycles and that maintains its surface condition to improve the amount of lifetime work (Wh), and an alkaline storage battery and battery system. A hydrogen storage alloy for an alkaline storage battery includes a composition expressed by LaxReyMg1-x-yNin-m-vAlmTv (Re: rare earth element(s) including Y; T: Co, Mn, Zn; 0.17≦x≦0.64, 3.5≦n≦3.8, 0.06≦m≦0.22, v≧0), and a main phase of an A5B19 type crystal structure. A ratio of X/Y of the concentration ratio X of Al to Ni in a surface layer and the concentration ratio Y of Al to Ni in a bulk layer is 0.36≦X/Y≦0.85. An alkaline storage battery includes the hydrogen storage alloy in its negative electrode. An alkaline storage battery system performs partial charge and discharge control.
摘要:
To provide a hydrogen storage alloy for an alkaline storage battery that improves output power by pulverization of the alloy in the initial stage of partial charge and discharge cycles and that maintains its surface condition to improve the amount of lifetime work (Wh), and an alkaline storage battery and battery system. A hydrogen storage alloy for an alkaline storage battery includes a composition expressed by LaxReyMg1-x-yNin-m-vAlmTv (Re; rare earth element(s) including Y; T: Co, Mn, Zn; 0.17≦x≦0.64, 3.5≦n≦3.8, 0.06≦m≦0.22, v≧0), and a main phase of an A5B19 type crystal structure. A ratio of X/Y of the concentration ratio X of Al to Ni in a surface layer and the concentration ratio Y of Al to Ni in a bulk layer is 0.36≦X/Y≦0.85. An alkaline storage battery includes the hydrogen storage alloy in its negative electrode. An alkaline storage battery system performs partial charge and discharge control.
摘要:
An alkaline storage battery system according to an aspect of the present invention, with which a partial charging-discharging is performed, includes an alkaline storage battery 10 including an electrode group having a nickel positive electrode 11, a hydrogen storage alloy negative electrode 12, a separator 13; an alkaline electrolyte; and an outer can 14 accommodating the electrode group and the alkaline electrolyte, and further includes a partial charge-discharge control unit for controlling charging-discharging of the battery 10. In addition, zinc (Zn) is added to nickel hydroxide that is a main positive electrode active material in the nickel positive electrode 11 with an addition amount of 5% by mass or less with respect to the mass of nickel in the positive electrode active material. The concentration of the alkaline electrolyte is 6.5 mol/L or less and the content of lithium in the alkaline electrolyte is 0.3 mol/L or more.
摘要:
A negative electrode plate of a nickel hydrogen storage battery includes a nonaqueous polymer binder and has an effective surface area per unit capacity of 70 cm2/Ah or more. The density of the first and second separators between positive and negative electrode plates ranges from 450 kg/m3 to 600 kg/m3. The nonwoven fabrics of the separators are formed by combining microfibers and compound fibers through melting portions of the compound fibers. The fibers have a virtually circular cross-section. The microfibers and the compound fibers have a diameter ranging from 1 μm to less than 5 μm and a diameter ranging from 5 μm to 15 μm, respectively. The proportion of the microfibers to whole fibers ranges from 10 percent by mass to 20 percent by mass. At least one of the nonwoven fabrics of the separators is subjected to sulfonation treatment.
摘要翻译:镍氢蓄电池的负极板包括非水性聚合物粘合剂,并且每单位容量的有效表面积为70cm 2 / Ah以上。 正极板和负极板之间的第一和第二隔板的密度范围为450kg / m 3至600kg / m 3。 分离器的非织造织物通过将复合纤维的熔融部分结合在一起而形成微纤维和复合纤维。 纤维具有实质上圆形的横截面。 微纤维和复合纤维的直径分别为1μm至小于5μm,直径范围为5μm至15μm。 微纤维与全纤维的比例为10质量%〜20质量%。 分离器中的至少一个非织造织物经受磺化处理。
摘要:
A negative electrode plate of a nickel hydrogen storage battery includes a nonaqueous polymer binder and has an effective surface area per unit capacity of 70 cm2/Ah or more. The density of the first and second separators between positive and negative electrode plates ranges from 450 kg/m3 to 600 kg/m3. The nonwoven fabrics of the separators are formed by combining microfibers and compound fibers through melting portions of the compound fibers. The fibers have a virtually circular cross-section. The microfibers and the compound fibers have a diameter ranging from 1 μm to less than 5 μm and a diameter ranging from 5 μm to 15 μm, respectively. The proportion of the microfibers to whole fibers ranges from 10 percent by mass to 20 percent by mass. At least one of the nonwoven fabrics of the separators is subjected to sulfonation treatment.
摘要翻译:镍氢蓄电池的负极板包括非水性聚合物粘合剂,每单位容积的有效表面积为70cm 2 / Ah以上。 正极板和负极板之间的第一和第二分离器的密度范围为450kg / m 3至600kg / m 3。 分离器的非织造织物通过将复合纤维的熔融部分结合在一起而形成微纤维和复合纤维。 纤维具有实质上圆形的横截面。 微纤维和复合纤维的直径分别为1μm至小于5μm,直径范围为5μm至15μm。 微纤维与全纤维的比例为10质量%〜20质量%。 分离器中的至少一个非织造织物经受磺化处理。
摘要:
The current-collecting lead for being welded to a collector welded to an upper portion of an electrode group and also to a sealing assembly of an cylindrical secondary battery includes: a flat surface part welded to the collector, and a top part formed to be curved and protrude approximately in the shape of a dome from the flat surface part and welded to the sealing assembly. A central opening is formed at a central portion of the top part. Around the central opening, a plurality of welding projections are formed to protrude toward the sealing assembly. The welding projections serve as welding spots to the sealing assembly. The top part is deformed by a pressing force from the sealing assembly to be brought into surface contact with a corner portion of a convex portion formed on a lower surface of the sealing assembly.
摘要:
To aim to provide a cylindrical secondary battery comprising a current collector assembly that is inserted between the electrode assembly and the sealing cover, and electrically connects the sealing cover with a core of one of the positive electrode plate and the negative electrode plate, wherein the current collector assembly is composed of a combination of (i) a current collector plate having a plate shape that is provided on an upper part of the electrode assembly and (ii) a current collector lead that includes a cylindrical part having an axis in a direction along a main surface of the current collector plate, the cylindrical part includes a top part and a bottom part whose peripheral surfaces oppose each other, the top part is welded and joined to a sealing plate that is a bottom surface of the sealing cover, and the bottom part is welded and joined to the current collector plate, the current collector lead further includes at least one tab part having a rectangle shape that extends from an opening edge of the cylindrical part in a direction of the axis, and the tab part is at least partially electrically connected with the current collector plate at a region from a root portion to a tip portion thereof.