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    LEATHER-LIKE SHEET
    1.
    发明申请
    LEATHER-LIKE SHEET 有权
    皮革样片

    公开(公告)号：US20100068499A1

    公开(公告)日：2010-03-18

    申请号：US12447704

    申请日：2007-11-19

    申请人： Yoshinori Kanagawa ,  Toshio Niwa ,  Toshifumi Tamaki ,  Minoru Takahashi

    发明人： Yoshinori Kanagawa ,  Toshio Niwa ,  Toshifumi Tamaki ,  Minoru Takahashi

    IPC分类号： B32B5/18 ,  C08L75/00 ,  C08L63/00 ,  B32B27/40

    CPC分类号： D06N3/14 ,  D06N3/0056 ,  D06N3/0063 ,  D06N3/0065 ,  D06N3/145 ,  D06N3/146 ,  D06N2211/28 ,  Y10T428/249988 ,  Y10T428/269 ,  Y10T428/31551

    摘要： A leather-like sheet is provided having a substrate layer and a surface skin layer in which the surface skin layer is composed of a cross-linked product of a polyurethane hot-melt composition containing 100 parts by mass of a urethane prepolymer, 5 parts by mass to 40 parts by mass of a coloring agent containing a polyol, 5 parts by mass to 50 parts by mass of multi-functional (meth)acrylate, and 0.5 parts by mass to 5 parts by mass of a photopolymerization initiator, wherein the urethane prepolymer can be obtained by reacting 5% to 50% of the number of isocyanate groups in a urethane prepolymer containing isocyanate groups that is obtained by reacting a polyol containing 40% by mass or more of polytetramethylene glycol and a polyisocyanate with a (meth)acrylate containing a hydroxyl group. This leather-like sheet has an excellent surface grade while maintaining excellent suppleness and bending resistance.

    摘要翻译： 提供了一种皮革状片材，其具有基材层和表皮层，其中表皮层由包含100质量份氨基甲酸酯预聚物的聚氨酯热熔组合物的交联产物组成，其中5份由 将质量为40质量份的含有多元醇的着色剂，5质量份〜50质量份多官能（甲基）丙烯酸酯，以及0.5质量份〜5质量份的光聚合引发剂，其中，聚氨酯 预聚物可以通过使含有40质量％以上的聚四亚甲基二醇的多元醇与多异氰酸酯与（甲基）丙烯酸酯反应而得到的含有异氰酸酯基的氨基甲酸酯预聚物中的异氰酸酯基数的5〜50％ 含有羟基。 这种皮革状片材具有优异的表面等级，同时保持优异的柔软性和抗弯曲性。

    Leather-like sheet
    2.
    发明授权
    Leather-like sheet 有权
    皮革样片材

    公开(公告)号：US07767293B2

    公开(公告)日：2010-08-03

    申请号：US12447704

    申请日：2007-11-19

    申请人： Yoshinori Kanagawa ,  Toshio Niwa ,  Toshifumi Tamaki ,  Minoru Takahashi

    发明人： Yoshinori Kanagawa ,  Toshio Niwa ,  Toshifumi Tamaki ,  Minoru Takahashi

    IPC分类号： B32B5/18 ,  B32B27/40 ,  C08L75/00 ,  C08L63/00

    CPC分类号： D06N3/14 ,  D06N3/0056 ,  D06N3/0063 ,  D06N3/0065 ,  D06N3/145 ,  D06N3/146 ,  D06N2211/28 ,  Y10T428/249988 ,  Y10T428/269 ,  Y10T428/31551

    摘要： A leather-like sheet is provided having a substrate layer and a surface skin layer in which the surface skin layer is composed of a cross-linked product of a polyurethane hot-melt composition containing 100 parts by mass of a urethane prepolymer, 5 parts by mass to 40 parts by mass of a coloring agent containing a polyol, 5 parts by mass to 50 parts by mass of multi-functional (meth)acrylate, and 0.5 parts by mass to 5 parts by mass of a photopolymerization initiator, wherein the urethane prepolymer can be obtained by reacting 5% to 50% of the number of isocyanate groups in a urethane prepolymer containing isocyanate groups that is obtained by reacting a polyol containing 40% by mass or more of polytetramethylene glycol and a polyisocyanate with a (meth)acrylate containing a hydroxyl group. This leather-like sheet has an excellent surface grade while maintaining excellent suppleness and bending resistance.

    摘要翻译： 提供了一种皮革状片材，其具有基材层和表皮层，其中表皮层由包含100质量份氨基甲酸酯预聚物的聚氨酯热熔组合物的交联产物组成，其中5份由 将质量为40质量份的含有多元醇的着色剂，5质量份〜50质量份多官能（甲基）丙烯酸酯，以及0.5质量份〜5质量份的光聚合引发剂，其中，所述聚氨酯 预聚物可以通过使含有40质量％以上的聚四亚甲基二醇的多元醇与多异氰酸酯与（甲基）丙烯酸酯反应而得到的含有异氰酸酯基的氨基甲酸酯预聚物中的异氰酸酯基数的5〜50％ 含有羟基。 这种皮革状片材具有优异的表面等级，同时保持优异的柔软性和抗弯曲性。

    Moisture-curable polyurethane hot melt adhesive and multilayer sheet using the same
    4.
    发明授权
    Moisture-curable polyurethane hot melt adhesive and multilayer sheet using the same 有权
    水溶性聚氨酯热熔胶和使用其的多层片

    公开(公告)号：US07641968B2

    公开(公告)日：2010-01-05

    申请号：US12302237

    申请日：2007-11-19

    申请人： Yoshinori Kanagawa ,  Toshio Niwa ,  Toshifumi Tamaki

    发明人： Yoshinori Kanagawa ,  Toshio Niwa ,  Toshifumi Tamaki

    IPC分类号： B32B7/12 ,  C09J4/00

    CPC分类号： B32B5/26 ,  B32B7/12 ,  B32B27/12 ,  B32B27/40 ,  B32B2262/0261 ,  B32B2262/0276 ,  C08G18/12 ,  C08G18/4018 ,  C08G18/4252 ,  C08G18/44 ,  C08G18/4829 ,  C08G18/4854 ,  C08G2170/20 ,  Y10T428/2852 ,  Y10T428/2896 ,  Y10T428/31551 ,  Y10T428/31554 ,  Y10T428/31565 ,  C08G18/307

    摘要： There are provided a moisture-curable polyurethane hot melt adhesive containing a urethane prepolymer obtained by reacting a polyol (A) with a polyisocyanate (B), wherein the polyol (A) contains 40 to 80 mass % of a polycarbonate polyol (a1), 5 to 40 mass % of polytetramethylene glycol (a2), and 5 to 40 mass % of a polyester polyol (a3) obtained by reacting a polycarboxylic acid containing an aliphatic polycarboxylic acid and an aromatic polycarboxylic acid with a polyether polyol obtained by adding an alkylene oxide to bisphenol A, based on the total amount of the polyol (A), and a multilayer sheet using this adhesive. This adhesive can maintain excellent adhesion strength even after washing is repeatedly performed under stringent washing conditions without impairing soft texture of a multilayer sheet.

    摘要翻译： 提供含有通过使多元醇（A）与多异氰酸酯（B）反应得到的氨基甲酸酯预聚物的湿固化性聚氨酯热熔粘合剂，其中多元醇（A）含有40〜80质量％的聚碳酸酯多元醇（a1） 5〜40质量％的聚四亚甲基二醇（a2）和5〜40质量％的通过使含有脂肪族多元羧酸和芳香族多元羧酸的多元羧酸与聚醚多元醇反应得到的聚酯多元醇（a3） 基于多元醇（A）的总量和使用该粘合剂的多层片材，氧化物与双酚A的摩尔比。 即使在严格的洗涤条件下重复进行洗涤也不会损害多层片材的柔软质地，该粘合剂可以保持优异的粘附强度。

    Process for producing leather-like sheet
    7.
    发明授权
    Process for producing leather-like sheet 有权
    生产皮革样片材的方法

    公开(公告)号：US07431794B2

    公开(公告)日：2008-10-07

    申请号：US10590142

    申请日：2005-02-23

    申请人： Yoshinori Kanagawa ,  Toshio Niwa ,  Toshifumi Tamaki ,  Hisao Yoneda

    发明人： Yoshinori Kanagawa ,  Toshio Niwa ,  Toshifumi Tamaki ,  Hisao Yoneda

    IPC分类号： C09J4/00 ,  C09J101/00 ,  C09J201/00 ,  A01N1/00 ,  B32B27/14 ,  B32B3/00 ,  B05D5/00 ,  C08G18/00 ,  C08G18/28

    CPC分类号： D06N3/14 ,  D06N3/0063 ,  D06N3/0065 ,  D06N3/0088 ,  D06N3/0097 ,  D06N3/143 ,  Y10T428/24826 ,  Y10T428/249979

    摘要： A process for producing a leather-like sheet, wherein a skin-like layer composed of a resin composition (C) is formed on top of a fibrous substrate (E), comprising; heating and melting a moisture-curable polyurethane hot-melt resin composition (C) which contains a hot-melt urethane prepolymer (A) having isocyanate groups at molecular terminal ends and a colorant (B), and applying said heated and melted resin composition (C) to either [1] a releasable substrate (D) and then bonding the coated surface to a fibrous substrate (E), or [2] a fibrous substrate (E) and then bonding the coated surface to a releasable substrate (D); wherein the colorant (B) contains a polyol with a number average molecular weight within a range from 1,000 to 20,000 as a vehicle (B-1), and a pigment (B-2).

    摘要翻译： 一种皮革状片材的制造方法，其特征在于，在纤维基材（E）的上部形成有由树脂组合物（C）构成的皮肤状的层， 加热熔融含有在分子末端具有异氰酸酯基的热熔氨基甲酸酯预聚物（A）和着色剂（B）的湿固性聚氨酯热熔树脂组合物（C），并将所述加热熔融的树脂组合物 C）至[1]一个可释放的基材（D），然后将涂覆的表面粘合到纤维基材（E）或[2]纤维基材（E）上，然后将涂覆的表面粘合到可释放的基材（D） ; 其中着色剂（B）含有数均分子量为1000〜20,000的多元醇作为载体（B- 1）和颜料（B-2）。

    Process for producing leather-like sheet
    8.
    发明申请
    Process for producing leather-like sheet 有权
    生产皮革样片材的方法

    公开(公告)号：US20070169887A1

    公开(公告)日：2007-07-26

    申请号：US10590142

    申请日：2005-02-23

    申请人： Yoshinori Kanagawa ,  Toshio Niwa ,  Toshifumi Tamaki ,  Hisao Yoneda

    发明人： Yoshinori Kanagawa ,  Toshio Niwa ,  Toshifumi Tamaki ,  Hisao Yoneda

    IPC分类号： C09J175/00

    CPC分类号： D06N3/14 ,  D06N3/0063 ,  D06N3/0065 ,  D06N3/0088 ,  D06N3/0097 ,  D06N3/143 ,  Y10T428/24826 ,  Y10T428/249979

    摘要： A process for producing a leather-like sheet, wherein a skin-like layer composed of a resin composition (C) is formed on top of a fibrous substrate (E), comprising; heating and melting a moisture-curable polyurethane hot-melt resin composition (C) which contains a hot-melt urethane prepolymer (A) having isocyanate groups at molecular terminal ends and a colorant (B), and applying said heated and melted resin composition (C) to either [1] a releasable substrate (D) and then bonding the coated surface to a fibrous substrate (E), or [2] a fibrous substrate (E) and then bonding the coated surface to a releasable substrate (D); wherein the colorant (B) contains a polyol with a number average molecular weight within a range from 1,000 to 20,000 as a vehicle (B-1), and a pigment (B-2).

    摘要翻译： 一种皮革状片材的制造方法，其特征在于，在纤维基材（E）的上部形成有由树脂组合物（C）构成的皮肤状的层， 加热熔融含有在分子末端具有异氰酸酯基的热熔氨基甲酸酯预聚物（A）和着色剂（B）的湿固性聚氨酯热熔树脂组合物（C），并将所述加热熔融的树脂组合物 C）至[1]一个可释放的基材（D），然后将涂覆的表面粘合到纤维基材（E）或[2]纤维基材（E）上，然后将涂覆的表面粘合到可释放的基材（D） ; 其中着色剂（B）含有数均分子量为1000〜20,000的多元醇作为载体（B- 1）和颜料（B-2）。

    Water-base coating material
    9.
    发明申请
    Water-base coating material 有权

    公开(公告)号：US20060217497A1

    公开(公告)日：2006-09-28

    申请号：US10552251

    申请日：2004-05-20

    申请人： Mitsuru Kitada ,  Kazuo Kuba ,  Toshifumi Tamaki

    发明人： Mitsuru Kitada ,  Kazuo Kuba ,  Toshifumi Tamaki

    IPC分类号： C08L75/04 ,  B32B27/40

    CPC分类号： C08G18/0823 ,  C08G18/4263 ,  C08G18/6659 ,  C08G18/758 ,  C08J7/047 ,  C08J2475/00 ,  C09D175/06

    摘要： Disclosed is an aqueous coating agent comprising a water dispersion (C) prepared by dispersing resin particles containing a water-dispersible polyurethane resin (A) and at least one compound selected from a hydrophobic polyester polyol (B-1) and a hydrophobic polyether polyol (B-2) in water, and a crosslinking agent (D) capable of reacting with a hydroxyl group, wherein the water-dispersible polyurethane resin (A) is obtained by reacting a polyester polyol (a-1), which is obtained by condensing a dicarboxylic acid containing an aromatic dicarboxylic acid as a main component with a polyol, with a polyisocyanate, and also contains 15 to 35% by weight of an aromatic cyclic structural unit, and wherein the hydrophobic polyester polyol (B-1) and/or the hydrophobic polyether polyol (B-2) are liquid at normal temperature and contain 20 to 50% by weight of an aromatic cyclic structural unit.

    Water-borne urethane resin composition for forming microporous layer, method of producing fibrous sheet-like composite, and artificial leather
    10.
    发明授权
    Water-borne urethane resin composition for forming microporous layer, method of producing fibrous sheet-like composite, and artificial leather 有权
    用于形成微孔层的水性聚氨酯树脂组合物，纤维状片状复合材料的制造方法和人造革

    公开(公告)号：US06794446B1

    公开(公告)日：2004-09-21

    申请号：US09889570

    申请日：2001-07-30

    申请人： Shingo Takeda ,  Hideyuki Takeuchi ,  Eiji Satake ,  Toshifumi Tamaki

    发明人： Shingo Takeda ,  Hideyuki Takeuchi ,  Eiji Satake ,  Toshifumi Tamaki

    IPC分类号： C08L7500

    CPC分类号： D06N3/14 ,  C08G18/12 ,  C08G18/283 ,  C08G18/4808 ,  C08G18/4833 ,  C08G18/4854 ,  C08G18/6644 ,  C08L75/04 ,  D04H1/42 ,  D04H1/587 ,  D04H1/64 ,  C08G18/3246

    摘要： An object of the present invention is to provide a water-borne urethane resin composition for forming a microporous layer, which is suited for use in a fibrous material substrate, especially an artificial leather, and which has well-defined heat-sensitive coagulation properties and is capable of being uniformly filled into a fibrous material substrate without causing migration, forming a micrporous layer after drying and imparting a feel equivalent to that obtained in a solvent-based urethane resin composition, i.e., an elastic and genuine feel, by impregnating or coating the fibrous material substrate with the water-borne urethane resin composition; a method of producing a fibrous sheet-like composite using the water-borne urethane resin composition; and an artificial leather obtained by the method. The water-borne urethane resin composition of the present invention comprises (1) a water-borne urethane resin having a heat-sensitive coagulation temperature of 40 to 90° C. and (2) an associated type thickener. In the method of producing a fibrous sheet-like composite according to the present invention, (i) a fibrous material substrate is impregnated or coated with (ii) the water-borne resin composition and then (iii) heat-sensitive coagulation is performed using steam.

    摘要翻译： 本发明的目的是提供一种用于形成微孔层的水性聚氨酯树脂组合物，其适用于纤维材料基材，特别是人造革，其具有明确的热敏凝固性能， 能够均匀地填充到纤维材料基材中而不会引起迁移，在干燥后形成多层，并且通过浸渍或涂布赋予与在溶剂型聚氨酯树脂组合物中获得的感觉相当的感觉，即弹性和真实感觉 具有水性聚氨酯树脂组合物的纤维材料基材; 使用该水性聚氨酯树脂组合物制造纤维状片状复合体的方法; 和通过该方法获得的人造革。 本发明的水性聚氨酯树脂组合物包含（1）热敏凝固温度为40〜90℃的水性聚氨酯树脂和（2）相关型增稠剂。 在本发明的纤维状片状复合体的制造方法中，（i）纤维材料基材浸渍或涂布（ii）水性树脂组合物，然后（iii）热敏凝固使用 蒸汽。