Polypropylene based heat shrinkable film
    6.
    发明授权
    Polypropylene based heat shrinkable film 有权
    聚丙烯基热收缩膜

    公开(公告)号:US07662888B2

    公开(公告)日:2010-02-16

    申请号:US11410074

    申请日:2006-04-25

    IPC分类号: C08F297/00

    摘要: A polypropylene based heat shrinkable film obtained by using a propylene-ethylene block copolymer (A) which satisfies the following requirements (A-i) to (A-iv), and having heat shrinkability imparted by orientation in at least one direction: (A-i) it is a propylene-ethylene block copolymer obtained through sequential polymerization catalyzed by a metallocene catalyst which is composed of 30 to 95 wt % of a propylene homopolymer or propylene-ethylene random copolymer component (A1) having an ethylene content of at most 7 wt % produced in a first step and 70 to 5 wt % of a propylene-ethylene random copolymer component (A2) produced in a second step having an ethylene content higher by 3 to 20 wt % than that of the component (A1); (A-ii) it has a melt flow rate (MFR: 2.16 kg, 230° C.) within a range of 0.1 to 30 g/10 min; (A-iii) a temperature-loss tangent (tan δ) curve obtained by dynamic mechanical analysis (DMA) has a single peak at a temperature of at most 0° C.; (A-iv) in a temperature rising elution fractionation (TREF) curve obtained as a plot of an elution amount (dwt %/dT) to a temperature by means of temperature rising elution fractionation (TREF) using an o-dichlorobenzene solvent in a temperature range of −15° C. to 140° C., a peak temperature T(A1) observed at a high temperature side is within a range of 60° C. to 88° C., a peak temperature T(A2) observed at a low temperature side is at most 40° C. or a peak temperature T(A2) is not observed, and a temperature T(A4) at which 99 wt % of the total amount of the propylene-ethylene block copolymer is eluted is less than 90° C.

    摘要翻译: 通过使用满足以下要求(A 1)至(A-iv)的丙烯 - 乙烯嵌段共聚物(A),并且具有至少一个方向上的取向赋予热收缩性的聚丙烯基热收缩膜:(Ai) 是通过由金属茂催化剂催化的顺序聚合得到的丙烯 - 乙烯嵌段共聚物,其由30至95重量%的乙烯含量至多为7重量%的丙烯均聚物或丙烯 - 乙烯无规共聚物组分(A1) 在第一步中,70-5重量%的乙烯含量高于组分(A1)的3-20重量%的第二步产生的丙烯 - 乙烯无规共聚物组分(A2); (A-ii),其熔体流动速率(MFR:2.16kg,230℃)在0.1〜30g / 10min的范围内; (A-iii)通过动态力学分析(DMA)获得的温度 - 损耗角正切(tanδ)曲线在至多0℃的温度下具有单峰; (TR-F)曲线中的溶出量(dwt%/ dT)与温度的升高洗脱分级(TREF)曲线的比较(A-iv),使用邻二氯苯溶剂 温度范围为-15℃至140℃,在高温侧观察到的峰值温度T(A1)在60℃至88℃的范围内,观察到峰值温度T(A2) 在低温侧为40℃以下,没有观察到峰值温度T(A2),丙烯 - 乙烯嵌段共聚物总量99重量%的洗脱温度T(A4)为 小于90℃

    Polypropylene based heat shrinkable film
    7.
    发明申请
    Polypropylene based heat shrinkable film 有权
    聚丙烯基热收缩膜

    公开(公告)号:US20060246308A1

    公开(公告)日:2006-11-02

    申请号:US11410074

    申请日:2006-04-25

    IPC分类号: B32B27/00 C08F293/00

    摘要: A polypropylene based heat shrinkable film obtained by using a propylene-ethylene block copolymer (A) which satisfies the following requirements (A-i) to (A-iv), and having heat shrinkability imparted by orientation in at least one direction: (A-i) it is a propylene-ethylene block copolymer obtained through sequential polymerization catalyzed by a metallocene catalyst which is composed of 30 to 95 wt % of a propylene homopolymer or propylene-ethylene random copolymer component (A1) having an ethylene content of at most 7 wt % produced in a first step and 70 to 5 wt % of a propylene-ethylene random copolymer component (A2) produced in a second step having an ethylene content higher by 3 to 20 wt % than that of the component (A1); (A-ii) it has a melt flow rate (MFR: 2.16 kg, 230° C.) within a range of 0.1 to 30 g/10 min; (A-iii) a temperature-loss tangent (tan δ) curve obtained by dynamic mechanical analysis (DMA) has a single peak at a temperature of at most 0° C.; (A-iv) in a temperature rising elution fractionation (TREF) curve obtained as a plot of an elution amount (dwt %/dT) to a temperature by means of temperature rising elution fractionation (TREF) using an o-dichlorobenzene solvent in a temperature range of −15° C. to 140° C., a peak temperature T(A1) observed at a high temperature side is within a range of 60° C. to 88° C., a peak temperature T(A2) observed at a low temperature side is at most 40° C. or a peak temperature T(A2) is not observed, and a temperature T(A4) at which 99 wt % of the total amount of the propylene-ethylene block copolymer is eluted is less than 90° C.

    摘要翻译: 通过使用满足以下要求(A 1)至(A-iv)的丙烯 - 乙烯嵌段共聚物(A),并且具有至少一个方向上的取向赋予热收缩性的聚丙烯基热收缩膜:(Ai) 是通过由金属茂催化剂催化的顺序聚合得到的丙烯 - 乙烯嵌段共聚物,其由30至95重量%的乙烯含量至多为7重量%的丙烯均聚物或丙烯 - 乙烯无规共聚物组分(A1) 在第一步中,70-5重量%的乙烯含量高于组分(A1)的3-20重量%的第二步产生的丙烯 - 乙烯无规共聚物组分(A2); (A-ii),其熔体流动速率(MFR:2.16kg,230℃)在0.1〜30g / 10min的范围内; (A-iii)通过动态力学分析(DMA)获得的温度 - 损耗角正切(tanδ)曲线在至多0℃的温度下具有单峰; (TR-F)曲线中的溶出量(dwt%/ dT)与温度的升高洗脱分级(TREF)曲线的比较(A-iv),使用邻二氯苯溶剂 温度范围为-15℃至140℃,在高温侧观察到的峰值温度T(A1)在60℃至88℃的范围内,观察到峰值温度T(A2) 在低温侧为40℃以下,没有观察到峰值温度T(A2),丙烯 - 乙烯嵌段共聚物总量99重量%的洗脱温度T(A4)为 小于90℃