摘要:
There is provided a fluorine-containing elastomer composition assuring easy kneading and providing a crosslinked article having improved strength. The fluorine-containing elastomer composition comprises (A) an elastomer of a vinylidene fluoride/hexafluoropropylene copolymer having a branching coefficient of 30 to 300 ppm, a Mooney viscosity (ML1+10: 121° C.) of 7 to 80 and a molecular weight distribution (Mw/Mn) of 1.5 to 4, and (B) an elastomer of a vinylidene fluoride/hexafluoropropylene copolymer having a storage modulus G′ at 180° C. at 500 cpm of 500 to 900, and a mass ratio of (A)/(B) is 70/30 to 90/10.
摘要:
There is provided a fluorine-containing elastomer composition assuring easy kneading and providing a crosslinked article having improved strength. The fluorine-containing elastomer composition comprises (A) an elastomer of a vinylidene fluoride/hexafluoropropylene copolymer having a branching coefficient of 30 to 300 ppm, a Mooney viscosity (ML1+10: 121° C.) of 7 to 80 and a molecular weight distribution (Mw/Mn) of 1.5 to 4, and (B) an elastomer of a vinylidene fluoride/hexafluoropropylene copolymer having a storage modulus G′ at 180° C. at 500 cpm of 500 to 900, and a mass ratio of (A)/(B) is 70/30 to 90/10.
摘要:
A fluoroelastomer mixture, including: a peroxide-vulcanizable fluoroelastomer (A) containing an iodine atom; and a peroxide-vulcanizable fluoroelastomer (B) containing an iodine atom. The fluoroelastomer (A) is a copolymer (a1) consisting of 50 to 85 mol % of a vinylidene fluoride unit and 15 to 50 mol % of a perfluoro(alkyl vinyl ether) unit, or a copolymer (a2) consisting of 45 to 85 mol % of a vinylidene fluoride unit, 1 to 30 mol % of a tetrafluoroethylene unit, and 14 to 30 mol % of a perfluoro(alkyl vinyl ether) unit. Further the fluoroelastomer (B) has a fluorine content of 70.0% or more. Also disclosed is a composition for peroxide vulcanization containing the above fluoroelastomer composition (i), a polyfunctional unsaturated compound (ii) and a peroxide (iii), as well as a method for producing the fluoroelastomer mixture.
摘要:
A curable composition comprising (A) a vinylidene fluoride elastomer which is a copolymer of vinylidene fluoride (a1), at least one kind of perfluoroolefin (a2) selected from the group consisting of tetrafluoroethylene, hexafluoropropylene and perfluoro(alkyl vinyl ether) and a cyano group-containing monomer (a3) (a proportion of the vinylidene fluoride exceeds 20% by mole), (B) a specific curing agent and (C) a compound generating ammonia at 40° to 330° C. The present invention can provide a curable composition of a vinylidene fluoride elastomer assuring improved crosslinking speed, and a molded article obtained from the curable composition. Physical properties under normal conditions are improved by the presence of a solvent having affinity for the compound generating ammonia.
摘要:
A fluoroelastomer mixture, including: a peroxide-vulcanizable fluoroelastomer (A) containing an iodine atom; and a peroxide-vulcanizable fluoroelastomer (B) containing an iodine atom. The fluoroelastomer (A) is a copolymer (a1) consisting of 50 to 85 mol % of a vinylidene fluoride unit and 15 to 50 mol % of a perfluoro(alkyl vinyl ether) unit, or a copolymer (a2) consisting of 45 to 85 mol % of a vinylidene fluoride unit, 1 to 30 mol % of a tetrafluoroethylene unit, and 14 to 30 mol % of a perfluoro(alkyl vinyl ether) unit. Further the fluoroelastomer (B) has a fluorine content of 70.0% or more. Also disclosed is a composition for peroxide vulcanization containing the above fluoroelastomer composition (i), a polyfunctional unsaturated compound (ii) and a peroxide (iii), as well as a method for producing the fluoroelastomer mixture.
摘要:
A curable composition comprising (A) a vinylidene fluoride type elastomer which is a copolymer of vinylidene fluoride (a1), at least one perfluoroolefin (a2) selected from the group consisting of tetrafluoroethylene, hexafluoropropylene and perfluoro(alkyl vinyl ether) and a cyano group-containing monomer (a3) (the proportion of vinylidene fluoride exceeds 20% by mole), and (B) a compound generating ammonia at 40° to 330° C. alone as a curing agent. The present invention can provide a curable composition of a vinylidene fluoride type elastomer assuring improved crosslinking speed and making it possible to use a cheap curing agent, and a molded article obtained from the curable composition. Physical properties under normal conditions can also be improved by the presence of the solvent having affinity for the compound generating ammonia.
摘要:
To provide a sealing material which is excellent in sealability under high-temperature conditions as well as crack resistance at high temperatures and high compression. A sealing material comprising a cross-linked fluororubber layer obtainable by cross-linking a fluororubber composition containing a fluororubber (A) and a carbon black (B), the cross-linked fluororubber layer having a loss modulus E″ of 600 kPa or higher and 6,000 kPa or lower determined by a dynamic viscoelasticity test under conditions of measurement temperature: 160° C., tensile strain: 1%, initial force: 157 cN, and frequency: 10 Hz.
摘要:
The present invention provides a complex-shaped fluororubber formed product having excellent demoldability in molding. The complex-shaped fluororubber formed product of the present invention comprises a cross-linked fluororubber layer obtainable by cross-linking a fluororubber composition containing a fluororubber (A) and a carbon black (B). The cross-linked fluororubber layer has a loss modulus E″ of 400 kPa or higher and 6,000 kPa or lower determined by a dynamic viscoelasticity test (measurement temperature: 160° C., tensile strain: 1%, initial force: 157 cN, frequency: 10 Hz).
摘要:
The present invention provides a hose excellent in mechanical properties at high temperatures. The hose of the present invention comprises a cross-linked fluororubber layer obtainable by cross-linking a fluororubber composition containing a fluororubber (A) and a carbon black (B). The cross-linked fluororubber layer has a loss modulus E″ of 400 kPa or higher and 6,000 kPa or lower determined by a dynamic viscoelasticity test (measurement temperature: 160° C., tensile strain: 1%, initial force: 157 cN, frequency: 10 Hz).
摘要:
The present invention provides a vibration isolation rubber excellent not only in heat-aging resistance and oil resistance but also in mechanical properties at high temperatures. The vibration isolation rubber of the present invention comprises a cross-linked fluororubber layer obtainable by cross-linking a fluororubber composition containing a fluororubber (A) and a carbon black (B). The cross-linked fluororubber layer has a loss modulus E″ of 400 kPa or higher and 6,000 kPa or lower determined by a dynamic viscoelasticity test (measurement temperature: 160° C., tensile strain: 1%, initial force: 157 cN, and frequency: 10 Hz).