摘要:
The catalyst-supporting powder is in form of an agglomerate formed by agglomeration of a fluorine atom-containing polymer material, a catalyst metal, a cation exchange resin, and a carbon material and the polymer material is contained in the inside of the agglomerate.
摘要:
A nonaqueous electrolytic solution containing magnesium ions which shows excellent electrochemical characteristics and which can be manufactured in a general manufacturing environment such as a dry room, and an electrochemical device using the same are provided. A Mg battery has a positive-electrode can 1, a positive-electrode pellet 2 made of a positive-electrode active material or the like, a positive electrode 11 composed of a metallic net supporting body 3, a negative-electrode cup 4, a negative electrode 12 made of a negative-electrode active material 5, and a separator 6 impregnated with an electrolytic solution 7 and disposed between the positive-electrode pellet and the negative-electrode active material. Metal Mg, an alkyl trifluoromethanesulfonate, a quaternary ammonium salt or/and a 1,3-alkylmethylimidazolium salt, more preferably, an aluminum halide are added to an ether system organic solvent and are then heated, and thereafter, more preferably, a trifluoroborane-ether complex salt is added thereto, thereby preparing the electrolytic solution. By adopting a structure that copper contacts the positive-electrode active material, the electrochemical device can be given a large discharge capacity.
摘要:
A secondary battery capable of safely improving a battery performance is provided. An electrolyte with which a separator 13 is impregnated contains an alkyl sulfone and a low-polar solvent (a solvent having a relative permittivity of 20 or less) together with an aluminum salt. The alkyl sulfone facilitates the redox reaction of aluminum, and further reduces the reactivity of the electrolyte. Additionally, the low-polar solvent suppresses the block of the redox reaction of aluminum. In charge and discharge, it becomes easy to electrochemically efficiently precipitate and dissolve aluminum, and further to inhibit the corrosion of a metallic exterior package member or the like.
摘要:
A nonaqueous electrolytic solution containing magnesium ions which shows excellent electrochemical characteristics and which can be manufactured in a general manufacturing environment such as a dry room, and an electrochemical device using the same are provided. A Mg battery has a positive-electrode can 1, a positive-electrode pellet 2 made of a positive-electrode active material or the like, a positive electrode 11 composed of a metallic net supporting body 3, a negative-electrode cup 4, a negative electrode 12 made of a negative-electrode active material 5, and a separator 6 impregnated with an electrolytic solution 7 and disposed between the positive-electrode pellet and the negative-electrode active material. Metal Mg, an alkyl trifluoromethanesulfonate, a quaternary ammonium salt or/and a 1,3-alkylmethylimidazolium salt, more preferably, an aluminum halide are added to an ether system organic solvent and are then heated, and thereafter, more preferably, a trifluoroborane-ether complex salt is added thereto, thereby preparing the electrolytic solution. By adopting a structure that copper contacts the positive-electrode active material, the electrochemical device can be given a large discharge capacity.
摘要:
A secondary battery capable of safely improving a battery performance is provided. An electrolyte with which a separator 13 is impregnated contains an alkyl sulfone and a low-polar solvent (a solvent having a relative permittivity of 20 or less) together with an aluminum salt. The alkyl sulfone facilitates the redox reaction of aluminum, and further reduces the reactivity of the electrolyte. Additionally, the low-polar solvent suppresses the block of the redox reaction of aluminum. In charge and discharge, it becomes easy to electrochemically efficiently precipitate and dissolve aluminum, and further to inhibit the corrosion of a metallic exterior package member or the like.
摘要:
In one embodiment, a thin film solid state lithium ion secondary battery is able to be charged and discharged in the air and manufactured stably at a favorable yield. The thin film solid state lithium ion secondary battery has an electric insulating substrate formed from an organic resin, an inorganic insulating film provided on the substrate face, a cathode-side current collector film, a cathode active material film, a solid electrolyte film, an anode potential formation layer, and an anode-side current collector film. The cathode-side current collector film and/or the anode-side current collector film is formed on the inorganic insulating film face. The anode potential formation layer is a layer formed from the same material as that of the cathode active material film or a material different from that of the cathode active material film and is a layer provided for forming anode potential at the time of discharge.
摘要:
Disclosed herein is a secondary battery charge method, including the steps of: conducting a pulsed charge control adapted to conduct a pulsed charge by repeating a cycle of a charge condition and a pause condition of a secondary battery at predetermined intervals; detecting a voltage detection adapted to detect the voltage of the secondary battery; determining a charge termination determination adapted to determine whether to terminate the charge of the secondary battery based on the battery voltage in a pause condition detected by the voltage detection step; and terminating a charge termination control adapted to terminate the pulsed charge when it has been determined by the charge termination determination step that the charge should be terminated.
摘要:
A secondary battery capable of decreasing progression temperature of a precipitation-dissolution reaction of aluminum is provided. A cathode 11 and an anode 12 are separated from each other by a separator 13. An electrolyte with which the separator 13 is impregnated contains an alkyl sulfone (R1—S(═O)2—R2: each of R1 and R2 represents an alkyl group) and a solvent (having a specific dielectric constant of 20 or less) together with an aluminum salt. A content of the solvent is equal to or larger than 30 mol % and is less than 88 mol %, and a mol ratio (a content of the aluminum salt/a content of the alkyl sulfone) is equal to or larger than 4/5 and is less than 7/3.
摘要:
A solid electrolyte cell includes: a positive electrode side layer; a negative electrode side layer; and a solid electrolyte layer disposed between the positive electrode side layer and the negative electrode side layer, wherein the negative electrode side layer includes a negative electrode side current collector layer; the negative electrode side current collector layer includes a first negative electrode side current collector layer disposed on a side close to the solid electrolyte layer, and a second negative electrode side current collector layer disposed on a side remote from the solid electrolyte layer; the first negative electrode side current collector layer includes copper, nickel, or an alloy containing any of copper and nickel, or stainless steel; and the second negative electrode side current collector layer includes aluminum, silver, or an alloy containing any of aluminum and silver.
摘要:
In one embodiment, a thin film solid state lithium ion secondary battery is able to be charged and discharged in the air and manufactured stably at a favorable yield. The thin film solid state lithium ion secondary battery has an electric insulating substrate formed from an organic resin, an inorganic insulating film provided on the substrate face, a cathode-side current collector film, a cathode active material film, a solid electrolyte film, an anode potential formation layer, and an anode-side current collector film. The cathode-side current collector film and/or the anode-side current collector film is formed on the inorganic insulating film face. The anode potential formation layer is a layer formed from the same material as that of the cathode active material film or a material different from that of the cathode active material film and is a layer provided for forming anode potential at the time of discharge.