公开(公告)号：US20110313162A1

公开(公告)日：2011-12-22

申请号：US13219754

申请日：2011-08-29

申请人： Yun CHI ,  Pi-Tai Chou ,  Yi-Hwa Song ,  Yuan-Chieh Chiu ,  Chiung-Fang Chang

发明人： Yun CHI ,  Pi-Tai Chou ,  Yi-Hwa Song ,  Yuan-Chieh Chiu ,  Chiung-Fang Chang

IPC分类号： C07F15/00

CPC分类号： C07F15/0033

摘要： The present invention discloses a phosphorescent tris-chelated transition metal complex comprising i) two identical non-conjugated cyclometalated ligands being incorporated into a coordination sphere thereof with a transition metal, and one ligated chromophore being incorporated into the coordination sphere; or ii) one non-conjugated cyclometalated ligand forming a coordination sphere thereof with a transition metal, and two ligated chromophores being incorporated into the coordination sphere, wherein the metal is iridium, platinum, osmium or ruthenium, and the ligated chromophore possesses a relatively lower energy gap in comparison with that of the non-conjugated cyclometalated ligand, the latter afforded an effective barrier for inhibiting the ligand-to-ligand charge transfer process, so that a subsequent radiative decay from an excited state of these transition complexes will be confined to the single ligated chromophore. The architecture and energy gap of the ligated chromophore are suitable for generation of high efficiency blue, green and even red emissions.

摘要翻译： 本发明公开了一种磷光三螯合过渡金属络合物，其包括i）两个相同的非共轭环金属化配体与过渡金属掺入其配位球中，并将一个连接的发色团并入配位球; 或ii）一种非共轭环金属化配体与过渡金属形成配位球，并且将两个连接的发色团掺入配位球中，其中金属是铱，铂，锇或钌，并且连接的发色团具有相对较低的 能量间隙与非共轭环金属配体相比，后者为抑制配体 - 配体电荷转移过程提供了有效的屏障，使得随后从这些过渡配合物的激发态的辐射衰减将被限制在 单连结发色团。 连结发色团的结构和能隙适合于产生高效率的蓝，绿，甚红色发射。

公开(公告)号：US08030490B2

公开(公告)日：2011-10-04

申请号：US12000035

申请日：2007-12-07

申请人： Yun Chi ,  Pi-Tai Chou ,  Yi-Hwa Song ,  Yuan-Chieh Chiu ,  Chiung-Fang Chang

发明人： Yun Chi ,  Pi-Tai Chou ,  Yi-Hwa Song ,  Yuan-Chieh Chiu ,  Chiung-Fang Chang

IPC分类号： C07F15/00

CPC分类号： C07F15/0033

摘要： The present invention discloses a phosphorescent tris-chelated transition metal complex comprising i) two identical non-conjugated cyclometalated ligands being incorporated into a coordination sphere thereof with a transition metal, and one ligated chromophore being incorporated into the coordination sphere; or ii) one non-conjugated cyclometalated ligand forming a coordination sphere thereof with a transition metal, and two ligated chromophores being incorporated into the coordination sphere, wherein the metal is iridium, platinum, osmium or ruthenium, and the ligated chromophore possesses a relatively lower energy gap in comparison with that of the non-conjugated cyclometalated ligand, the latter afforded an effective barrier for inhibiting the ligand-to-ligand charge transfer process, so that a subsequent radiative decay from an excited state of these transition complexes will be confined to the single ligated chromophore. The architecture and energy gap of the ligated chromophore are suitable for generation of high efficiency blue, green and even red emissions.

摘要翻译： 本发明公开了一种磷光三螯合过渡金属络合物，其包括i）两个相同的非共轭环金属化配体与过渡金属掺入其配位球中，并将一个连接的发色团并入配位球; 或ii）一种非共轭环金属化配体与过渡金属形成配位球，并且将两个连接的发色团掺入配位球中，其中金属是铱，铂，锇或钌，并且连接的发色团具有相对较低的 能量间隙与非共轭环金属配体相比，后者为抑制配体 - 配体电荷转移过程提供了有效的屏障，使得随后从这些过渡配合物的激发态的辐射衰减将被限制在 单连结发色团。 连结发色团的结构和能隙适合于产生高效率的蓝，绿，甚红色发射。

公开(公告)号：US20080161568A1

公开(公告)日：2008-07-03

申请号：US12000035

申请日：2007-12-07

申请人： Yun Chi ,  Pi-Tai Chou ,  Yi-Hwa Song ,  Yuan-Chieh Chiu ,  Chiung-Fang Chang

发明人： Yun Chi ,  Pi-Tai Chou ,  Yi-Hwa Song ,  Yuan-Chieh Chiu ,  Chiung-Fang Chang

IPC分类号： C07F15/00

CPC分类号： C07F15/0033

摘要： The present invention discloses a phosphorescent tris-chelated transition metal complex comprising i) two identical non-conjugated cyclometalated ligands being incorporated into a coordination sphere thereof with a transition metal, and one ligated chromophore being incorporated into the coordination sphere; or ii) one non-conjugated cyclometalated ligand forming a coordination sphere thereof with a transition metal, and two ligated chromophores being incorporated into the coordination sphere, wherein the metal is iridium, platinum, osmium or ruthenium, and the ligated chromophore possesses a relatively lower energy gap in comparison with that of the non-conjugated cyclometalated ligand, the latter afforded an effective barrier for inhibiting the ligand-to-ligand charge transfer process, so that a subsequent radiative decay from an excited state of these transition complexes will be confined to the single ligated chromophore. The architecture and energy gap of the ligated chromophore are suitable for generation of high efficiency blue, green and even red emissions.

摘要翻译： 本发明公开了一种磷光三螯合过渡金属络合物，其包括i）两个相同的非共轭环金属化配体与过渡金属掺入其配位球中，并将一个连接的发色团并入配位球; 或ii）一种非共轭环金属化配体与过渡金属形成配位球，并且将两个连接的发色团掺入配位球中，其中金属是铱，铂，锇或钌，并且连接的发色团具有相对较低的 能量间隙与非共轭环金属配体相比，后者为抑制配体 - 配体电荷转移过程提供了有效的屏障，使得随后从这些过渡配合物的激发态的辐射衰减将被限制在 单连结发色团。 连结发色团的结构和能隙适合于产生高效率的蓝，绿，甚红色发射。

公开(公告)号：US08592585B2

公开(公告)日：2013-11-26

申请号：US13219754

申请日：2011-08-29

申请人： Yun Chi ,  Pi-Tai Chou ,  Yi-Hwa Song ,  Yuan-Chieh Chiu ,  Chiung-Fang Chang

发明人： Yun Chi ,  Pi-Tai Chou ,  Yi-Hwa Song ,  Yuan-Chieh Chiu ,  Chiung-Fang Chang

IPC分类号： C07F15/00 ,  C07F9/28

CPC分类号： C07F15/0033

摘要： The present invention discloses a phosphorescent tris-chelated transition metal complex comprising i) two identical non-conjugated cyclometalated ligands being incorporated into a coordination sphere thereof with a transition metal, and one ligated chromophore being incorporated into the coordination sphere; or ii) one non-conjugated cyclometalated ligand forming a coordination sphere thereof with a transition metal, and two ligated chromophores being incorporated into the coordination sphere, wherein the metal is iridium, platinum, osmium or ruthenium, and the ligated chromophore possesses a relatively lower energy gap in comparison with that of the non-conjugated cyclometalated ligand, the latter afforded an effective barrier for inhibiting the ligand-to-ligand charge transfer process, so that a subsequent radiative decay from an excited state of these transition complexes will be confined to the single ligated chromophore. The architecture and energy gap of the ligated chromophore are suitable for generation of high efficiency blue, green and even red emissions.

摘要翻译： 本发明公开了一种磷光三螯合过渡金属络合物，其包括i）两个相同的非共轭环金属化配体与过渡金属掺入其配位球中，并将一个连接的发色团并入配位球; 或ii）一种非共轭环金属化配体与过渡金属形成配位球，并且将两个连接的发色团掺入配位球中，其中金属是铱，铂，锇或钌，并且连接的发色团具有相对较低的 能量间隙与非共轭环金属配体相比，后者为抑制配体 - 配体电荷转移过程提供了有效的屏障，使得随后从这些过渡配合物的激发态的辐射衰减将被限制在 单连结发色团。 连结发色团的结构和能隙适合于产生高效率的蓝，绿，甚红色发射。

公开(公告)号：US08410269B2

公开(公告)日：2013-04-02

申请号：US13219757

申请日：2011-08-29

申请人： Yun Chi ,  Pi-Tai Chou ,  Yi-Hwa Song ,  Yuan-Chieh Chiu ,  Chiung-Fang Chang

发明人： Yun Chi ,  Pi-Tai Chou ,  Yi-Hwa Song ,  Yuan-Chieh Chiu ,  Chiung-Fang Chang

IPC分类号： C07F15/00 ,  C07F9/28

CPC分类号： C07F15/0033

摘要： The present invention discloses a phosphorescent tris-chelated transition metal complex comprising i) two identical non-conjugated cyclometalated ligands being incorporated into a coordination sphere thereof with a transition metal, and one ligated chromophore being incorporated into the coordination sphere; or ii) one non-conjugated cyclometalated ligand forming a coordination sphere thereof with a transition metal, and two ligated chromophores being incorporated into the coordination sphere, wherein the metal is iridium, platinum, osmium or ruthenium, and the ligated chromophore possesses a relatively lower energy gap in comparison with that of the non-conjugated cyclometalated ligand, the latter afforded an effective barrier for inhibiting the ligand-to-ligand charge transfer process, so that a subsequent radiative decay from an excited state of these transition complexes will be confined to the single ligated chromophore. The architecture and energy gap of the ligated chromophore are suitable for generation of high efficiency blue, green and even red emissions.

公开(公告)号：US20110313161A1

公开(公告)日：2011-12-22

申请号：US13219757

申请日：2011-08-29

申请人： Yun CHI ,  Pi-Tai Chou ,  Yi-Hwa Song ,  Yuan-Chieh Chiu ,  Chiung-Fang Chang

发明人： Yun CHI ,  Pi-Tai Chou ,  Yi-Hwa Song ,  Yuan-Chieh Chiu ,  Chiung-Fang Chang

IPC分类号： C07F15/00

CPC分类号： C07F15/0033

摘要： The present invention discloses a phosphorescent tris-chelated transition metal complex comprising i) two identical non-conjugated cyclometalated ligands being incorporated into a coordination sphere thereof with a transition metal, and one ligated chromophore being incorporated into the coordination sphere; or ii) one non-conjugated cyclometalated ligand forming a coordination sphere thereof with a transition metal, and two ligated chromophores being incorporated into the coordination sphere, wherein the metal is iridium, platinum, osmium or ruthenium, and the ligated chromophore possesses a relatively lower energy gap in comparison with that of the non-conjugated cyclometalated ligand, the latter afforded an effective barrier for inhibiting the ligand-to-ligand charge transfer process, so that a subsequent radiative decay from an excited state of these transition complexes will be confined to the single ligated chromophore. The architecture and energy gap of the ligated chromophore are suitable for generation of high efficiency blue, green and even red emissions.

公开(公告)号：US20080217582A1

公开(公告)日：2008-09-11

申请号：US11683547

申请日：2007-03-08

申请人： Yun Chi ,  Pi-Tai Chou ,  Yi-Hwa Song ,  Yuan-Chieh Chiu ,  Chiung-Fang Chang

发明人： Yun Chi ,  Pi-Tai Chou ,  Yi-Hwa Song ,  Yuan-Chieh Chiu ,  Chiung-Fang Chang

IPC分类号： C07F15/00 ,  C09K11/06

CPC分类号： C07F15/0033 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/185

摘要： A new class of luminescent iridium(III) complexes, luminescent material and organic electroluminescent device thereof had been disclosed. The novel luminescent iridium(III) complexes comprises the formula [(ĈN)2Ir(P̂O)] with 2-(diphenylphosphino)phenolate as the ancillary chelate. The iridium complexes of the present invention can be used as the red, blue or green-emitting dopants. These luminescent materials can be applied in the fabrication of light-emitting layer of organic electroluminescent devices and providing the high efficiently red, blue or green light organic electroluminescent devices of commercial pursuits.

摘要翻译： 已经公开了一类新型的发光铱（III）络合物，发光材料及其有机电致发光器件。 新型发光铱（III）络合物包含式（ĈN）2 Ir（PO）]与2-（二苯基膦基）酚盐作为辅助螯合物。 本发明的铱络合物可以用作红色，蓝色或绿色发射掺杂剂。 这些发光材料可以应用于制造有机电致发光器件的发光层，并提供高效率的商业追求的红，蓝或绿光有机电致发光器件。

公开(公告)号：US07112690B2

公开(公告)日：2006-09-26

申请号：US10495073

申请日：2002-11-08

申请人： Yun Chi ,  Yao-Lun Chen ,  Chao-Shiuan Liu ,  Yi-Hwa Song ,  Ying-Hui Lai ,  Arthur J. Carty

发明人： Yun Chi ,  Yao-Lun Chen ,  Chao-Shiuan Liu ,  Yi-Hwa Song ,  Ying-Hui Lai ,  Arthur J. Carty

IPC分类号： C07F15/00 ,  C23C16/00

CPC分类号： C07F15/004 ,  C07F15/002 ,  C07F15/0026 ,  C07F15/0033 ,  C07F15/0046 ,  C07F15/0053

摘要： A series of noble metal organometallic complexes of the general formula (I): MLaXb(FBC)c, wherein M is a noble metal such as iridium, ruthenium or osmium, and L is a neutral ligand such as carbonyl, alkene or diene; X is an anionic ligand such as chloride, bromide, iodide and trifluoroacetate group; and FBC is a fluorinated bidentate chelate ligand such as beta diketonate, beta-ketoiminate, amino-alcoholate and amino-alcoholate ligand, wherein a is an integer of from zero (0) to three (3), b is an integer of from zero (0) to one (1) and c is an 10 integer of from one (1) to three (3). The resulting noble metal complexes possess enhanced volatility and thermal stability characteristics, and are suitable for chemical vapor deposition(CVD) applications. The corresponding noble metal complex is formed by treatment of the FBC ligand with a less volatile metal halide. Also disclosed are CVD methods for using the noble metal complexes as source reagents for deposition of noble metal-containing films such as Ir, Ru and Os, or even metal oxide film materials IrO2, OsO2 and RuO2.

摘要翻译： 一系列通式（I）的贵金属有机金属络合物：其中M是贵金属（I） 金属如铱，钌或锇，L是中性配体如羰基，烯烃或二烯; X是阴离子配体，如氯化物，溴化物，碘化物和三氟乙酸盐基团; 并且FBC是氟化双齿螯合配体，例如β-二酮酸酯，β-酮亚胺酸酯，氨基醇化物和氨基醇化物配体，其中a是从零（0）到三（3）的整数，b是零的整数 （0）〜（1），c为1（3）的10个整数。 所得到的贵金属络合物具有增强的挥发性和热稳定性特性，并且适用于化学气相沉积（CVD）应用。 通过用不太易挥发的金属卤化物处理FBC配体形成相应的贵金属络合物。 还公开了使用贵金属络合物作为用于沉积含有贵金属的膜如Ir，Ru和Os，或甚至金属氧化物膜材料IrO 2，OsO 2， 2＆lt; 2＆gt;和RuO 2＆lt; 2＆gt ;.

公开(公告)号：US20050033075A1

公开(公告)日：2005-02-10

申请号：US10495073

申请日：2002-11-08

申请人： Yun Chi ,  Yao-Lun Chen ,  Chao-Shiuan Liu ,  Yi-Hwa Song ,  Ying-Hui Lai ,  Arthur Carty

发明人： Yun Chi ,  Yao-Lun Chen ,  Chao-Shiuan Liu ,  Yi-Hwa Song ,  Ying-Hui Lai ,  Arthur Carty

IPC分类号： C07F15/00 ,  C07F1/08 ,  C07F1/10 ,  C07F1/12

CPC分类号： C07F15/004 ,  C07F15/002 ,  C07F15/0026 ,  C07F15/0033 ,  C07F15/0046 ,  C07F15/0053

摘要： A series of noble metal organometallic complexes of the general formula (I): MLaXb(FBC)c, wherein M is a noble metal such as iridium, ruthenium or osmium, and L is a neutral ligand such as carbonyl, alkene or diene; X is an anionic ligand such as chloride, bromide, iodide and trifluoroacetate group; and FBC is a fluorinated bidentate chelate ligand such as beta diketonate, beta-ketoiminate, amino-alcoholate and amino-alcoholate ligand, wherein a is an integer of from zero (0) to three (3), b is an integer of from zero (0) to one (1) and c is an 10 integer of from one (1) to three (3). The resulting noble metal complexes possess enhanced volatility and thermal stability characteristics, and are suitable for chemical vapor deposition(CVD) applications. The corresponding noble metal complex is formed by treatment of the FBC ligand with a less volatile metal halide. Also disclosed are CVD methods for using the noble metal complexes as source reagents for deposition of noble metal-containing films such as Ir, Ru and Os, or even metal oxide film materials IrO2, OsO2 and RuO2.

摘要翻译： 一系列通式（I）的贵金属有机金属络合物：MLaXb（FBC）c，其中M是贵金属如铱，钌或锇，L是中性配体如羰基，烯烃或二烯; X是阴离子配体，如氯化物，溴化物，碘化物和三氟乙酸盐基团; 并且FBC是氟化双齿螯合配体，例如β-二酮酸酯，β-酮亚胺酸酯，氨基醇化物和氨基醇化物配体，其中a是从零（0）到三（3）的整数，b是零的整数 （0）〜（1），c为1（3）的10个整数。 所得到的贵金属络合物具有增强的挥发性和热稳定性特性，并且适用于化学气相沉积（CVD）应用。 通过用不太易挥发的金属卤化物处理FBC配体形成相应的贵金属络合物。 还公开了使用贵金属络合物作为用于沉积含有贵金属的膜如Ir，Ru和Os，或甚至金属氧化物膜材料IrO 2，OsO 2和RuO 2的源试剂的CVD方法。

公开(公告)号：US20110159774A1

公开(公告)日：2011-06-30

申请号：US12957422

申请日：2010-12-01

申请人： Yi-Hwa Song ,  Shih-Feng Hsu

发明人： Yi-Hwa Song ,  Shih-Feng Hsu

IPC分类号： H01J9/00 ,  B23P11/00

CPC分类号： C23C14/042 ,  H01L51/56 ,  Y10T29/4984

摘要： A shadow mask includes a frame, at least a support structure and at least a mask. The frame substantially defines a central opening region. The support structure is substantially disposed in the central opening region, and the support structure is connected to the frame in a movable manner. The mask is substantially disposed in the central opening region, and supported by the support structure.

摘要翻译： 荫罩包括框架，至少支撑结构和至少掩模。 框架基本上限定了中心开口区域。 支撑结构基本上设置在中央开口区域中，并且支撑结构以可移动的方式连接到框架。 掩模基本上设置在中心开口区域中，由支撑结构支撑。