ACTIVE ENERGY RAY-CURABLE RESIN COMPOSITION, AND PRODUCTION METHOD FOR PRODUCTS WITH SURFACES OF FINE CONCAVE-CONVEX STRUCTURES
    1.
    发明申请
    ACTIVE ENERGY RAY-CURABLE RESIN COMPOSITION, AND PRODUCTION METHOD FOR PRODUCTS WITH SURFACES OF FINE CONCAVE-CONVEX STRUCTURES 有权
    活性能量可固化树脂组合物,以及具有精细凹凸结构表面的产品的生产方法

    公开(公告)号:US20130011572A1

    公开(公告)日:2013-01-10

    申请号:US13635318

    申请日:2011-03-24

    IPC分类号: B29C33/58

    摘要: The present invention relates to a production method for a product having a cured resin layer with a fine concave-convex structure formed on the surface of a substrate, the method including filling the space between a mold having a fine concave-convex structure composed of anodized alumina on the surface and a substrate with an active energy ray-curable resin composition, and curing the composition by irradiation with active energy rays, thereby forming a cured resin layer into which the fine concave-convex structure has been transferred on the surface of the substrate, wherein (A) the method includes treating the surface of the mold with a release agent, at least at transfer initiation, and (B) the active energy ray-curable resin composition includes a polymerizable compound, a polymerization initiator and a (poly)oxyethylene alkyl phosphate ester compound.

    摘要翻译: 本发明涉及一种具有形成在基材表面上的具有细凹凸结构的固化树脂层的产品的制造方法,该方法包括填充具有由阳极氧化处理的细凹凸结构的模具之间的空间 氧化铝和具有活性能量射线固化树脂组合物的基材,通过用活性能量射线照射固化该组合物,从而形成在该表面上转印有微细凹凸结构的固化树脂层 基材,其中(A)所述方法包括至少在转移开始时用脱模剂处理模具的表面,和(B)活性能量射线固化树脂组合物包括可聚合化合物,聚合引发剂和(聚 )氧乙烯烷基磷酸酯化合物。

    Method for producing product having uneven microstructure on surface thereof
    2.
    发明授权
    Method for producing product having uneven microstructure on surface thereof 有权
    在其表面上生产具有不均匀微观结构的产品的方法

    公开(公告)号:US09494857B2

    公开(公告)日:2016-11-15

    申请号:US13702307

    申请日:2011-06-07

    摘要: A method for producing a product having an uneven microstructure on a surface thereof includes: a step (I) which treats a surface of a roll mold (20) having an uneven microstructure thereon with an external release agent containing a fluorine and not containing a functional group (B) which reacts with a functional group (A) existing on the surface of the product; and a step (II) which obtains the product having the uneven microstructure on the surface thereof (40) by inserting an active energy ray curable resin composition (38) including an internal release agent between the roll mold (20) and a film (substrate) (42) after the step (I). Then, the composition is hardened by being irradiated with an active energy ray and a cured resin layer (44) having a surface, onto which the uneven microstructure is transferred, is formed on the surface of the film (42).

    摘要翻译: 一种在其表面上具有不均匀微结构的产品的制造方法包括:步骤(I),其使用含有氟的外部脱模剂处理具有不均匀微观结构的辊模(20)的表面,并且不含有功能性 (B)与产品表面上存在的官能团(A)发生反应; 以及通过将包含内部脱模剂的活性能量射线固化性树脂组合物(38)在辊模(20)和膜(基材)之间插入来获得其表面上具有不均匀微结构的产品(40)的工序(II) )(42)。 然后,通过用活性能量射线照射组合物,并且在膜(42)的表面上形成具有表面的固化树脂层(44),在其上转印有不平坦的微结构。

    METHOD FOR PRODUCING PRODUCT HAVING UNEVEN MICROSTRUCTURE ON SURFACE THEREOF
    4.
    发明申请
    METHOD FOR PRODUCING PRODUCT HAVING UNEVEN MICROSTRUCTURE ON SURFACE THEREOF 有权
    在其表面上生产具有无法显微组织的产品的方法

    公开(公告)号:US20130140744A1

    公开(公告)日:2013-06-06

    申请号:US13702307

    申请日:2011-06-07

    IPC分类号: B29C59/16

    摘要: A method for producing a product having an uneven microstructure on a surface thereof includes: a step (I) which treats a surface of a roll mold (20) having an uneven microstructure thereon with an external release agent containing a fluorine and not containing a functional group (B) which reacts with a functional group (A) existing on the surface of the product; and a step (II) which obtains the product having the uneven microstructure on the surface thereof (40) by inserting an active energy ray curable resin composition (38) including an internal release agent between the roll mold (20) and a film (substrate) (42) after the step (I). Then, the composition is hardened by being irradiated with an active energy ray and a cured resin layer (44) having a surface, onto which the uneven microstructure is transferred, is formed on the surface of the film (42).

    摘要翻译: 一种在其表面上具有不均匀微结构的产品的制造方法包括:步骤(I),其使用含有氟的外部脱模剂处理具有不均匀微观结构的辊模(20)的表面,并且不含有功能性 (B)与产品表面上存在的官能团(A)发生反应; 以及通过将包含内部脱模剂的活性能量射线固化性树脂组合物(38)在辊模(20)和膜(基材)之间插入来获得其表面上具有不均匀微结构的产品(40)的工序(II) )(42)。 然后,通过用活性能量射线照射组合物,并且在膜(42)的表面上形成具有表面的固化树脂层(44),在其上转印有不平坦的微结构。

    METHOD FOR PRODUCING PRODUCT HAVING UNEVEN MICROSTRUCTURE ON SURFACE THEREOF, MOLD RELEASE TREATMENT METHOD, AND ACTIVE ENERGY RAY CURABLE RESIN COMPOSITION FOR MOLD SURFACE RELEASE TREATMENT
    5.
    发明申请
    METHOD FOR PRODUCING PRODUCT HAVING UNEVEN MICROSTRUCTURE ON SURFACE THEREOF, MOLD RELEASE TREATMENT METHOD, AND ACTIVE ENERGY RAY CURABLE RESIN COMPOSITION FOR MOLD SURFACE RELEASE TREATMENT 有权
    用于生产具有表面无法显微组织的产品的方法,模具释放处理方法和用于模具表面释放处理的活性能量可固化树脂组合物

    公开(公告)号:US20130075962A1

    公开(公告)日:2013-03-28

    申请号:US13702075

    申请日:2011-06-07

    IPC分类号: B29C41/42

    摘要: The producing method includes: (I) providing an active energy ray curable resin composition for mold surface release treatment between a mold having uneven microstructure on its surface and a substrate, and after curing the resin composition by irradiation with an active energy ray, peeling off the substrate together with a cured article of the active energy ray curable resin composition from the surface of the mold, thereby performing a release treatment to the surface of the mold; and (II), after step (I), providing an active energy ray curable resin composition for shaping between the substrate and the mold, the surface of which has been treated by the release treatment, and after curing the resin composition by an active energy ray, peeling off the substrate together with a cured article of the active energy ray curable resin composition for shaping from the surface of the mold.

    摘要翻译: 该制造方法包括:(I)在表面具有不均匀微结构的模具与基板之间提供用于模具表面剥离处理的活性能量射线固化性树脂组合物,并且通过用活性能量射线照射固化树脂组合物后,剥离 所述基材与所述活性能量射线固化型树脂组合物的固化物从所述模具的表面一起进行,从而对所述模具的表面进行脱模处理; 和(II)中,在步骤(I)之后,提供用于在基材和模具之间成形的活性能量射线固化树脂组合物,其表面已通过脱模处理处理,并且通过活性能量固化树脂组合物 与用于从模具表面成型的活性能量射线固化树脂组合物的固化物一起剥离基底。

    Plastic optical fiber, plastic optical fiber cables, optical fiber cables with plugs with copolymer
    7.
    发明授权
    Plastic optical fiber, plastic optical fiber cables, optical fiber cables with plugs with copolymer 有权
    塑料光纤,塑料光纤电缆,带有共聚物插头的光纤电缆

    公开(公告)号:US07142754B2

    公开(公告)日:2006-11-28

    申请号:US10169126

    申请日:2000-12-27

    IPC分类号: G02B6/16

    摘要: This invention relates to a copolymer prepared by polymerizing at least a vinyl compound (A) which gives a homopolymer with a refractive index of 1.50 or more, a fluoroalkyl (meth)acrylate (B) represented by the following formula (1) and methyl methacrylate (C), wherein a weight ratio of monomer (A) component/monomer (B) component ((A)/(B)) in the copolymer is within the range of 0.2 to 1; as well as a plastic optical fiber and a plastic optical fiber cable comprising a clad made of the copolymer. This invention can provide a plastic optical fiber and a plastic optical fiber cable exhibiting a reduced transmission loss, minimizing increase in a transmission loss even when being held as a bobbin-wound form, exhibiting a reduced bend loss and can transmit a wide-band data. (In the above formula, X represents H or CH3; and Rf represents fluoroalkyl having 7 to 14 carbon atoms both inclusive and 13 to 25 fluorine atoms both inclusive.).

    摘要翻译: 本发明涉及通过聚合至少一种得到折射率为1.50以上的均聚物的乙烯基化合物(A),由下式(1)表示的(甲基)丙烯酸氟烷基酯(B)和甲基丙烯酸甲酯 (C),其中共聚物中单体(A)成分/单体(B)成分((A)/(B))的重量比在0.2〜1的范围内; 以及包括由共聚物制成的包层的塑料光纤和塑料光缆。 本发明可以提供塑料光纤和塑料光纤电缆,其表现出降低的传输损耗,即使当被保持为绕线形式时,传输损耗的增加最小化,弯曲损耗减小并且可以传输宽带数据 。 (在上式中,X表示H或CH 3,Rf表示碳原子数为7〜14的氟代烷基,含有13〜25个氟原子。