METHOD OF PRODUCTION OF HIGHLY SATURATED NITRILE RUBBER

    公开(公告)号:US20180016360A1

    公开(公告)日:2018-01-18

    申请号:US15544239

    申请日:2015-12-25

    申请人: ZEON CORPORATION

    IPC分类号: C08C19/02 C08F236/12

    摘要: Method of production of highly saturated nitrile rubber, including: polymerization step of polymerizing monomer mixture containing at least α,β-ethylenically unsaturated nitrile monomer and diene monomer in medium to obtain dispersion or solution of nitrile rubber; coagulation step causing the nitrile rubber dispersion or solution to coagulate at 10-60° C. to obtain solid form nitrile rubber; hydrogenation reaction step causing solid form nitrile rubber to disperse or dissolve in medium to obtain the nitrile rubber dispersion or solution and performing hydrogenation reaction of the obtained nitrile rubber dispersion or solution to obtain dispersion or solution of highly saturated nitrile rubber, wherein the hydrogenation reaction, the content of compound having a mercapto group having 9-12 carbon atoms is 50 wt ppm or less and content of compound having a mercapto group having 13-16 carbon atoms is 1-120 wt ppm with respect to 100 wt % of the nitrile rubber content in the nitrile rubber dispersion or solution.

    METHOD FOR MANUFACTURING HYDROGENATED NITRILE RUBBER

    公开(公告)号:US20210179740A1

    公开(公告)日:2021-06-17

    申请号:US16758691

    申请日:2018-11-02

    申请人: ZEON CORPORATION

    发明人: Akito NAKAI

    摘要: A method produces a hydrogenated nitrile rubber having an iodine value of 120 or less, the method having a first coagulation step of adding a halogen atom-free metal salt as a coagulant to a nitrile rubber latex to form a nitrile rubber coagulum; a solution preparation step of dissolving the nitrile rubber coagulum in an organic solvent to prepare a nitrile rubber solution; a hydrogenation step of subjecting the nitrile rubber solution to a hydrogenation reaction to afford a hydrogenated nitrile rubber solution; and a second coagulation step of adding a divalent metal salt as a coagulant to the hydrogenated nitrile rubber solution to form a hydrogenated nitrile rubber coagulum.

    METHOD FOR SEPARATING CATALYST COMPONENT
    9.
    发明申请

    公开(公告)号:US20190241681A1

    公开(公告)日:2019-08-08

    申请号:US16318647

    申请日:2017-07-12

    摘要: Provided is a method of separating a catalyst of a hydrogenated nitrile rubber, the method including: a water-soluble polymer addition step of adding an aqueous solution of a water-soluble polymer to a water-soluble organic solvent solution of the hydrogenated nitrile rubber obtained by hydrogenating a nitrile rubber in the presence of a platinum group element-containing catalyst; and a water-soluble polymer precipitating step of precipitating the water-soluble polymer while incorporating the platinum group element in the water-soluble polymer by stirring the water-soluble organic solvent solution of the hydrogenated nitrile rubber to which the aqueous solution of the water-soluble polymer is added.