公开(公告)号：US20050154221A1

公开(公告)日：2005-07-14

申请号：US10508805

申请日：2003-04-17

申请人： Zenon Lysenko ,  Bob Maughon ,  Josef Bicerano ,  Kenneth Burdett ,  Christopher Christenson ,  Clark Cummins ,  Marvin Dettloff ,  Alan Schrock ,  P. J. Thomas ,  Richard Varjian ,  Jerry White ,  John Maher

发明人： Zenon Lysenko ,  Bob Maughon ,  Josef Bicerano ,  Kenneth Burdett ,  Christopher Christenson ,  Clark Cummins ,  Marvin Dettloff ,  Alan Schrock ,  P. J. Thomas ,  Richard Varjian ,  Jerry White ,  John Maher

IPC分类号： B01J31/24 ,  C07B61/00 ,  C07C6/04 ,  C07C11/02 ,  C07C67/333 ,  C07C67/347 ,  C07C67/475 ,  C07C67/56 ,  C07C69/533 ,  C07C69/58 ,  C07C227/08 ,  C07C227/18 ,  C07C229/08 ,  C07D303/42 ,  C07C51/43

CPC分类号： C07D303/42 ,  C07C67/31 ,  C07C67/333 ,  C07C67/347 ,  C07C67/56 ,  C07C69/533 ,  C07C227/08 ,  C07C227/18 ,  C07C229/08 ,  Y02P20/125 ,  C07C69/716 ,  C07C69/675

摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,Ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,Ω-hydroxy acid or α,Ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,Ωpolyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,Ω-amino acid or α,Ω-amino ester, which may be (trans)esterified to form an α,Ωpolyester polyamine.

摘要翻译： 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链α-烯烃和还原链不饱和酸或酯，优选还原链α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原反应加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。

公开(公告)号：US20070129556A1

公开(公告)日：2007-06-07

申请号：US10588623

申请日：2005-03-24

申请人： Marvin Dettloff ,  Marty Null

发明人： Marvin Dettloff ,  Marty Null

IPC分类号： C07D301/24 ,  C07C45/63

CPC分类号： C07C29/145 ,  C07C45/63 ,  C07C45/72 ,  C07D301/26 ,  C07D303/08 ,  C07C49/16 ,  C07C49/08 ,  C07C31/36

摘要： Epichlorohydrin is produced from acetone by (1) chlorinating acetone to form monochloroacetone; (2) disproportionating the monochloroacetone in the presence of a platinum catalyst, a strong acid and preferably a chloride source (for example, added as a salt or from hydrolysis of monochloroacetone) and some water to produce acetone and 1,3-dichloroacetone; (3) hydrogenating the 1,3-dichloroacetone in the presence of a catalyst to produce 1,3-dichlorohydrin; and (4) cyclizing the 1,3-dichlorohydrin with a base to produce epichlorohydrin.

摘要翻译： （1）氯化丙酮以形成一氯丙酮，由丙酮生成表氯醇; （2）在铂催化剂，强酸，优选氯化物源（例如以盐或加入一氯丙酮的水溶液）存在下歧化单氯代丙酮和一些水以产生丙酮和1,3-二氯丙酮; （3）在催化剂存在下氢化1,3-二氯丙酮以制备1,3-二氯丙醇; 和（4）用碱环化1,3-二氯丙醇以制备表氯醇。