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    SOLID CATALYST COMPONENT AND CATALYST FOR OLEFIN POLYMERIZATION
    4.
    发明申请
    SOLID CATALYST COMPONENT AND CATALYST FOR OLEFIN POLYMERIZATION 有权
    用于烯烃聚合的固体催化剂组分和催化剂

    公开(公告)号：US20130324682A1

    公开(公告)日：2013-12-05

    申请号：US13980359

    申请日：2012-01-19

    申请人： Zhong TAN ,  Lunjia Xie ,  Xiudong Xu ,  Yu Tian ,  Qilong Zhou ,  Zaixing Feng ,  Li'an Yan ,  Siyuan Zhao ,  Jinhua Yu ,  Zhufang Sun ,  Fengkui Li ,  Shanshan Yin ,  Weiwei Song

    发明人： Zhong TAN ,  Lunjia Xie ,  Xiudong Xu ,  Yu Tian ,  Qilong Zhou ,  Zaixing Feng ,  Li'an Yan ,  Siyuan Zhao ,  Jinhua Yu ,  Zhufang Sun ,  Fengkui Li ,  Shanshan Yin ,  Weiwei Song

    IPC分类号： C08F110/06

    CPC分类号： C08F110/06 ,  C08F10/06 ,  C08F4/651 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6548

    摘要： Disclosed is a solid catalyst component for olefin polymerization. The catalyst component comprises a dialkoxy magnesium carrier, a titanium compound, and a product from an internal electron donor reacting in an inert solvent. Said internal electron donor compound comprises a 2,3-di-non-linear-alkyl-2-cyano succinic acid diester compound as presented in formula I: as in formula I, R1 and R2 radicals are independently chosen from linear or branched C1-C4 alkyl groups; R is chosen from C3-C6 iso-alkyl, sec-alkyl, or cycloalkyl groups. Also disclosed is another solid catalyst component. The catalyst component comprises a dialkoxy magnesium carrier, a titanium compound, and a product from an internal electron donor reacting in an inert solvent. In addition to a 2,3-di-non-linear-alkyl-2-cyano succinic acid diester compound as presented in formula I, the internal electron donor compound can also comprise 2-isopropyl-2-(3-methylbutyl)-1,3-dimethoxy propane and/or a carboxylic ester compound. Also disclosed is a catalyst containing the solid catalyst component. The catalyst is used for olefin polymerization, particularly propylene polymerization, and is relatively active during polymerization. The obtained polymer has the advantages of wide molecular weight distribution, high molecular bulk density, good hydrogen regulation sensitivity, good stereospecificity, good particle shape, and small fine powder content.

    摘要翻译： 公开了用于烯烃聚合的固体催化剂组分。 催化剂组分包括二烷氧基镁载体，钛化合物和在惰性溶剂中反应的内电子给体的产物。 所述内电子给体化合物包含式I所示的2,3-二 - 非线性 - 烷基-2-氰基琥珀酸二酯化合物：如式I所示，R 1和R 2基团独立地选自直链或支链C1- C4烷基; R选自C 3 -C 6异烷基，仲烷基或环烷基。 还公开了另一种固体催化剂组分。 催化剂组分包括二烷氧基镁载体，钛化合物和在惰性溶剂中反应的内电子给体的产物。 除了式I所示的2,3-二 - 非线性 - 烷基-2-氰基琥珀酸二酯化合物之外，内电子给体化合物还可以包含2-异丙基-2-（3-甲基丁基）-1 ，3-二甲氧基丙烷和/或羧酸酯化合物。 还公开了含有固体催化剂组分的催化剂。 该催化剂用于烯烃聚合，特别是丙烯聚合，并且在聚合期间相对有活性。 得到的聚合物具有分子量分布宽，分子体积密度高，调节灵敏度好，立体定向性好，粒子形状好，细粉含量低的优点。

    CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, PREPARATION METHOD THEREFOR AND CATALYST THEREOF
    6.
    发明申请
    CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, PREPARATION METHOD THEREFOR AND CATALYST THEREOF 审中-公开
    烯烃聚合催化剂组分及其制备方法及其催化性能

    公开(公告)号：US20140163185A1

    公开(公告)日：2014-06-12

    申请号：US14235340

    申请日：2012-07-24

    申请人： Qilong Zhou ,  Zhong Tan ,  Xiudong Xu ,  Li'an Yan ,  Weiwei Song ,  Fengkui Li ,  Shanshan Yin ,  Jinhua Yu

    发明人： Qilong Zhou ,  Zhong Tan ,  Xiudong Xu ,  Li'an Yan ,  Weiwei Song ,  Fengkui Li ,  Shanshan Yin ,  Jinhua Yu

    IPC分类号： C08F4/646 ,  C08F110/08 ,  C08F110/06

    CPC分类号： C08F4/6465 ,  C08F110/06 ,  C08F110/08 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/18 ,  C08F10/00 ,  C08F4/6565

    摘要： A catalyst component (A) for olefin polymerization is prepared by contacting a solid component (a) containing magnesium, titanium, halogen and an internal electron donor compound with an organosilicon compound (b), wherein the organosilicon compound (b) is one or more selected from a Si—H functional group containing chainlike polysiloxane (b1) represented by formula (Ix), a cyclic polysiloxane (b2) represented by formula (Iy) and a Si—H functional group containing organosilicon compound (b3) represented by formula (Iz). In addition, a process for preparing the catalyst component and the corresponding catalyst is described. The catalyst component and its catalyst have high catalytic activity, good hydrogen response, and good stereospecificity, the catalyst can release its activity more evenly, and the obtained polymer has significantly increased bulk density. The definitions of R1 to R10, n and z in the formulae (Ix), (ly) and (Iz) are as described in the specification.

    摘要翻译： 通过使含有镁，钛，卤素和内电子给体化合物的固体组分（a）与有机硅化合物（b）接触来制备用于烯烃聚合的催化剂组分（A），其中有机硅化合物（b）是一种或多种 选自由式（Ix）表示的含链状聚硅氧烷（b1）的Si-H官能团，由式（Iy）表示的环状聚硅氧烷（b2）和由式（Iy）表示的含有机硅化合物（b3）的Si-H官能团 Iz）。 此外，描述了制备催化剂组分和相应的催化剂的方法。 催化剂组分及其催化剂具有较高的催化活性，良好的氢响应和良好的立体定向性，催化剂可以更均匀地释放其活性，得到的聚合物体积密度明显增加。 式（Ix），（ly）和（Iz）中R1至R10，n和z的定义如说明书中所述。