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1.发明授权Method of making an electroactive sensing/actuating material for carbon nanotube polymer composite 有权制备用于碳纳米管聚合物复合材料的电活性感应/致动材料的方法公开(公告)号：US07527751B2
公开(公告)日：2009-05-05
申请号：US12109490
申请日：2008-04-25
IPC分类号： H01B1/00
CPC分类号： B82Y30/00 , C01B32/158 , H01L41/183 , Y10S977/783 , Y10S977/832 , Y10T428/25 , Y10T428/252 , Y10T428/256 , Y10T428/258
摘要： An electroactive sensing or actuating material comprises a composite made from a polymer with polarizable moieties and an effective amount of carbon nanotubes incorporated in the polymer for a predetermined electromechanical operation of the composite when such composite is affected by an external stimulus. In another embodiment, the composite comprises a third component of micro-sized to nano-sized particles of an electroactive ceramic that is also incorporated in the polymer matrix. The method for making the three-phase composite comprises either incorporating the carbon nanotubes in the polymer matrix before incorporation of the particles of ceramic or mixing the carbon nanotubes and particles of ceramic together in a solution before incorporation in the polymer matrix.
摘要翻译： 电活性感测或致动材料包括由具有可极化部分的聚合物制成的复合材料，并且当这种复合材料受外部刺激影响时，有效量的纳入聚合物中的碳纳米管用于组合物的预定机电操作。 在另一个实施方案中，所述复合材料包括还掺入聚合物基质中的电活性陶瓷的微尺寸至纳米尺寸颗粒的第三组分。 制备三相复合材料的方法包括在引入陶瓷颗粒之前将碳纳米管掺入聚合物基质中，或者在引入到聚合物基质中之前将碳纳米管和陶瓷颗粒一起混合在溶液中。
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2.发明授权Multilayer electroactive polymer composite material comprising carbon nanotubes 有权包含碳纳米管的多层电活性聚合物复合材料公开(公告)号：US07507472B2
公开(公告)日：2009-03-24
申请号：US11081888
申请日：2005-03-09
IPC分类号： B32B5/16
CPC分类号： B32B27/08 , B32B27/20 , B32B2307/204 , B82Y30/00 , H01L41/183 , Y10S977/783 , Y10S977/832 , Y10T428/24355 , Y10T428/24372 , Y10T428/24942 , Y10T428/25 , Y10T428/252 , Y10T428/256 , Y10T428/258 , Y10T428/31551 , Y10T428/31721 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , Y10T428/31935
摘要： An electroactive material comprises multiple layers of electroactive composite with each layer having unique dielectric, electrical and mechanical properties that define an electromechanical operation thereof when affected by an external stimulus. For example, each layer can be (i) a 2-phase composite made from a polymer with polarizable moieties and an effective amount of carbon nanotubes incorporated in the polymer for a predetermined electomechanical operation, or (ii) a 3-phase composite having the elements of the 2-phase composite and further including a third component of micro-sized to nano-sized particles of an electroactive ceramic incorporated in the polymer matrix.
摘要翻译： 电活性材料包括多层电活性复合材料，每层具有独特的电介质，电学和机械性能，当受到外部刺激的影响时，其定义了机电操作。 例如，每个层可以是（i）由具有可极化部分的聚合物制成的2相复合物，并且在预定的电子机械操作中引入掺入聚合物中的有效量的碳纳米管，或（ii）具有 并且还包括掺入聚合物基质中的电活性陶瓷的微尺寸至纳米尺寸颗粒的第三组分。
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3.发明申请Sensing/Actuating Materials Made From Carbon Nanotube Polymer Composites and Methods for Making Same 有权由碳纳米管聚合物复合材料制成的感应/致动材料及其制造方法公开(公告)号：US20080287589A1
公开(公告)日：2008-11-20
申请号：US12109490
申请日：2008-04-25
IPC分类号： C08K3/04
CPC分类号： B82Y30/00 , C01B32/158 , H01L41/183 , Y10S977/783 , Y10S977/832 , Y10T428/25 , Y10T428/252 , Y10T428/256 , Y10T428/258
摘要： An electroactive sensing or actuating material comprises a composite made from a polymer with polarizable moieties and an effective amount of carbon nanotubes incorporated in the polymer for a predetermined electromechanical operation of the composite when such composite is affected by an external stimulus. In another embodiment, the composite comprises a third component of micro-sized to nano-sized particles of an electroactive ceramic that is also incorporated in the polymer matrix. The method for making the three-phase composite comprises either incorporating the carbon nanotubes in the polymer matrix before incorporation of the particles of ceramic or mixing the carbon nanotubes and particles of ceramic together in a solution before incorporation in the polymer matrix.
摘要翻译： 电活性感测或致动材料包括由具有可极化部分的聚合物制成的复合材料，并且当这种复合材料受外部刺激影响时，有效量的纳入聚合物中的碳纳米管用于组合物的预定机电操作。 在另一个实施方案中，所述复合材料包括还掺入聚合物基质中的电活性陶瓷的微尺寸至纳米尺寸颗粒的第三组分。 制备三相复合材料的方法包括在引入陶瓷颗粒之前将碳纳米管掺入聚合物基质中，或者在引入到聚合物基质中之前将碳纳米管和陶瓷颗粒一起混合在溶液中。
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4.发明授权Sensing/actuating materials made from carbon nanotube polymer composites and methods for making same 有权由碳纳米管聚合物复合材料制成的感应/致动材料及其制造方法公开(公告)号：US07402264B2
公开(公告)日：2008-07-22
申请号：US11076460
申请日：2005-03-03
CPC分类号： B82Y30/00 , C01B32/158 , H01L41/183 , Y10S977/783 , Y10S977/832 , Y10T428/25 , Y10T428/252 , Y10T428/256 , Y10T428/258
摘要： An electroactive sensing or actuating material comprises a composite made from a polymer with polarizable moieties and an effective amount of carbon nanotubes incorporated in the polymer for a predetermined electomechanical operation of the composite when such composite is affected by an external stimulus. In another embodiment, the composite comprises a third component of micro-sized to nano-sized particles of an electroactive ceramic that is also incorporated in the polymer matrix. The method for making the three-phase composite comprises either incorporating the carbon nanotubes in the polymer matrix before incorporation of the particles of ceramic or mixing the carbon nanotubes and particles of ceramic together in a solution before incorporation in the polymer matrix.
摘要翻译： 电活性感测或致动材料包括由具有可极化部分的聚合物制成的复合材料，并且当这种复合材料受外部刺激影响时，将有效量的纳入聚合物中的碳纳米管用于组合物的预定电机操作。 在另一个实施方案中，所述复合材料包括还掺入聚合物基质中的电活性陶瓷的微尺寸至纳米尺寸颗粒的第三组分。 制备三相复合材料的方法包括在引入陶瓷颗粒之前将碳纳米管掺入聚合物基质中，或者在引入到聚合物基质中之前将碳纳米管和陶瓷颗粒一起混合在溶液中。
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公开(公告)号：US07935414B2
公开(公告)日：2011-05-03
申请号：US12406315
申请日：2009-03-18
IPC分类号： B32B5/16
CPC分类号： B32B27/08 , B32B27/20 , B32B2307/204 , B82Y30/00 , H01L41/183 , Y10S977/783 , Y10S977/832 , Y10T428/24355 , Y10T428/24372 , Y10T428/24942 , Y10T428/25 , Y10T428/252 , Y10T428/256 , Y10T428/258 , Y10T428/31551 , Y10T428/31721 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , Y10T428/31935
摘要： An electroactive material comprises multiple layers of electroactive composite with each layer having unique dielectric, electrical and mechanical properties that define an electromechanical operation thereof when affected by an external stimulus. For example, each layer can be (i) a 2-phase composite made from a polymer with polarizable moieties and an effective amount of carbon nanotubes incorporated in the polymer for a predetermined electomechanical operation, or (ii) a 3-phase composite having the elements of the 2-phase composite and further including a third component of micro-sized to nano-sized particles of an electroactive ceramic incorporated in the polymer matrix.
摘要翻译： 电活性材料包括多层电活性复合材料，每层具有独特的电介质，电学和机械性能，当受到外部刺激的影响时，其定义了机电操作。 例如，每个层可以是（i）由具有可极化部分的聚合物制成的2相复合物，并且在预定的电子机械操作中引入掺入聚合物中的有效量的碳纳米管，或（ii）具有 并且还包括掺入聚合物基质中的电活性陶瓷的微尺寸至纳米尺寸颗粒的第三组分。
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6.发明申请公开(公告)号：US20100078600A1
公开(公告)日：2010-04-01
申请号：US12550431
申请日：2009-08-31
申请人： John W. Connell , Joseph G. Smith , Joycelyn S. Harrison , Cheol Park , Kent A. Watson , Zoubeida Ounaies
发明人： John W. Connell , Joseph G. Smith , Joycelyn S. Harrison , Cheol Park , Kent A. Watson , Zoubeida Ounaies
IPC分类号： H01B1/24
CPC分类号： B82Y10/00 , B82Y30/00 , C08F2/44 , C08G73/10 , C08G73/1039 , C08G73/1071 , C08K5/00 , C08K7/24 , C08K2201/011 , C08L71/123 , C09J11/04 , H01B1/24 , Y10T428/25 , Y10T428/29 , Y10T428/2904 , Y10T428/2913 , Y10T428/2918 , Y10T428/2975 , C08L71/12
摘要： The present invention is directed to the effective dispersion of carbon nanotubes (CNTs) into polymer matrices. The nanocomposites are prepared using polymer matrices and exhibit a unique combination of properties, most notably, high retention of optical transparency in the visible range (i.e., 400-800 nm), electrical conductivity, and high thermal stability. By appropriate selection of the matrix resin, additional properties such as vacuum ultraviolet radiation resistance, atomic oxygen resistance, high glass transition (Tg) temperatures, and excellent toughness can be attained. The resulting nanocomposites can be used to fabricate or formulate a variety of articles such as coatings on a variety of substrates, films, foams, fibers, threads, adhesives and fiber coated prepreg. The properties of the nanocomposites can be adjusted by selection of the polymer matrix and CNT to fabricate articles that possess high optical transparency and antistatic behavior.
摘要翻译： 本发明涉及碳纳米管（CNT）在聚合物基质中的有效分散。 使用聚合物基质制备纳米复合材料，并且表现出独特的性质组合，最显着的是在可见光范围（即400-800nm）中高保留光学透明度，导电性和高热稳定性。 通过适当选择基体树脂，可以获得诸如真空紫外线辐射电阻，原子氧电阻，高玻璃化转变温度（Tg）等优异的韧性等附加特性。 所得的纳米复合材料可用于制造或配制各种制品，例如各种基材，薄膜，泡沫，纤维，线，粘合剂和纤维涂层预浸料上的涂层。 可以通过选择聚合物基质和CNT来调节具有高光学透明度和抗静电性能的制品来调节纳米复合材料的性能。
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7.发明授权Electrically conductive, optically transparent polymer/carbon nanotube composites and process for preparation thereof 有权导电，光学透明的聚合物/碳纳米管复合材料及其制备方法公开(公告)号：US07906043B2
公开(公告)日：2011-03-15
申请号：US12550431
申请日：2009-08-31
申请人： John W. Connell , Joseph G. Smith , Joycelyn S. Harrison , Cheol Park , Kent A. Watson , Zoubeida Ounaies
发明人： John W. Connell , Joseph G. Smith , Joycelyn S. Harrison , Cheol Park , Kent A. Watson , Zoubeida Ounaies
CPC分类号： B82Y10/00 , B82Y30/00 , C08F2/44 , C08G73/10 , C08G73/1039 , C08G73/1071 , C08K5/00 , C08K7/24 , C08K2201/011 , C08L71/123 , C09J11/04 , H01B1/24 , Y10T428/25 , Y10T428/29 , Y10T428/2904 , Y10T428/2913 , Y10T428/2918 , Y10T428/2975 , C08L71/12
摘要： The present invention is directed to the effective dispersion of carbon nanotubes (CNTs) into polymer matrices. The nanocomposites are prepared using polymer matrices and exhibit a unique combination of properties, most notably, high retention of optical transparency in the visible range (i.e., 400-800 nm), electrical conductivity, and high thermal stability. By appropriate selection of the matrix resin, additional properties such as vacuum ultraviolet radiation resistance, atomic oxygen resistance, high glass transition (Tg) temperatures, and excellent toughness can be attained. The resulting nanocomposites can be used to fabricate or formulate a variety of articles such as coatings on a variety of substrates, films, foams, fibers, threads, adhesives and fiber coated prepreg. The properties of the nanocomposites can be adjusted by selection of the polymer matrix and CNT to fabricate articles that possess high optical transparency and antistatic behavior.
摘要翻译： 本发明涉及碳纳米管（CNT）在聚合物基质中的有效分散。 使用聚合物基质制备纳米复合材料，并且表现出独特的性能组合，最显着的是在可见光范围（即400-800nm）中的高保留光学透明度，导电性和高热稳定性。 通过适当选择基体树脂，可以获得诸如真空紫外线辐射电阻，原子氧电阻，高玻璃化转变温度（Tg）等优异的韧性等附加特性。 所得的纳米复合材料可用于制造或配制各种制品，例如各种基材，薄膜，泡沫，纤维，线，粘合剂和纤维涂层预浸料上的涂层。 可以通过选择聚合物基质和CNT来调节具有高光学透明度和抗静电性能的制品来调节纳米复合材料的性能。
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8.发明申请Electrically Conductive, Optically Transparent Polymer/Carbon Nanotube Composites 有权导电，光学透明聚合物/碳纳米管复合材料公开(公告)号：US20100084618A1
公开(公告)日：2010-04-08
申请号：US12546724
申请日：2009-08-25
申请人： John W. Connell , Joseph G. Smith, JR. , Joycelyn S. Harrison , Cheol Park , Kent A. Watson , Zoubeida Ounaies
发明人： John W. Connell , Joseph G. Smith, JR. , Joycelyn S. Harrison , Cheol Park , Kent A. Watson , Zoubeida Ounaies
IPC分类号： H01B1/24
CPC分类号： B82Y10/00 , B82Y30/00 , C08F2/44 , C08G73/10 , C08G73/1039 , C08G73/1071 , C08K5/00 , C08K7/24 , C08K2201/011 , C08L71/123 , C09J11/04 , H01B1/24 , Y10T428/25 , Y10T428/29 , Y10T428/2904 , Y10T428/2913 , Y10T428/2918 , Y10T428/2975 , C08L71/12
摘要： The present invention is directed to the effective dispersion of carbon nanotubes (CNTs) into polymer matrices. The nanocomposites are prepared using polymer matrices and exhibit a unique combination of properties, most notably, high retention of optical transparency in the visible range (i.e., 400-800 nm), electrical conductivity, and high thermal stability. By appropriate selection of the matrix resin, additional properties such as vacuum ultraviolet radiation resistance, atomic oxygen resistance, high glass transition (Tg) temperatures, and excellent toughness can be attained. The resulting nanocomposites can be used to fabricate or formulate a variety of articles such as coatings on a variety of substrates, films, foams, fibers, threads, adhesives and fiber coated prepreg. The properties of the nanocomposites can be adjusted by selection of the polymer matrix and CNT to fabricate articles that possess high optical transparency and antistatic behavior.
摘要翻译： 本发明涉及碳纳米管（CNT）在聚合物基质中的有效分散。 使用聚合物基质制备纳米复合材料，并且表现出独特的性能组合，最显着的是在可见光范围（即400-800nm）中的高保留光学透明度，导电性和高热稳定性。 通过适当选择基体树脂，可以获得诸如真空紫外线辐射电阻，原子氧电阻，高玻璃化转变温度（Tg）等优异的韧性等附加特性。 所得的纳米复合材料可用于制造或配制各种制品，例如各种基材，薄膜，泡沫，纤维，线，粘合剂和纤维涂层预浸料上的涂层。 可以通过选择聚合物基质和CNT来调节具有高光学透明度和抗静电性能的制品来调节纳米复合材料的性能。
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9.发明授权Electrically conductive, optically transparent polymer/carbon nanotube composites 有权导电的，光学透明的聚合物/碳纳米管复合材料公开(公告)号：US07972536B2
公开(公告)日：2011-07-05
申请号：US12546724
申请日：2009-08-25
申请人： John W. Connell , Joseph G. Smith, Jr. , Joycelyn S. Harrison , Cheol Park , Kent A. Watson , Zoubeida Ounaies
发明人： John W. Connell , Joseph G. Smith, Jr. , Joycelyn S. Harrison , Cheol Park , Kent A. Watson , Zoubeida Ounaies
CPC分类号： B82Y10/00 , B82Y30/00 , C08F2/44 , C08G73/10 , C08G73/1039 , C08G73/1071 , C08K5/00 , C08K7/24 , C08K2201/011 , C08L71/123 , C09J11/04 , H01B1/24 , Y10T428/25 , Y10T428/29 , Y10T428/2904 , Y10T428/2913 , Y10T428/2918 , Y10T428/2975 , C08L71/12
摘要： The present invention is directed to the effective dispersion of carbon nanotubes (CNTs) into polymer matrices. The nanocomposites are prepared using polymer matrices and exhibit a unique combination of properties, most notably, high retention of optical transparency in the visible range (i.e., 400-800 nm), electrical conductivity, and high thermal stability. By appropriate selection of the matrix resin, additional properties such as vacuum ultraviolet radiation resistance, atomic oxygen resistance, high glass transition (Tg) temperatures, and excellent toughness can be attained. The resulting nanocomposites can be used to fabricate or formulate a variety of articles such as coatings on a variety of substrates, films, foams, fibers, threads, adhesives and fiber coated prepreg. The properties of the nanocomposites can be adjusted by selection of the polymer matrix and CNT to fabricate articles that possess high optical transparency and antistatic behavior.
摘要翻译： 本发明涉及碳纳米管（CNT）在聚合物基质中的有效分散。 使用聚合物基质制备纳米复合材料，并且表现出独特的性能组合，最显着的是在可见光范围（即400-800nm）中的高保留光学透明度，导电性和高热稳定性。 通过适当选择基体树脂，可以获得诸如真空紫外线辐射电阻，原子氧电阻，高玻璃化转变温度（Tg）等优异的韧性等附加特性。 所得的纳米复合材料可用于制造或配制各种制品，例如各种基材，薄膜，泡沫，纤维，线，粘合剂和纤维涂层预浸料上的涂层。 可以通过选择聚合物基质和CNT来调节具有高光学透明度和抗静电性能的制品来调节纳米复合材料的性能。
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10.发明授权Electrically conductive, optically transparent polymer/carbon nanotube composites and process for preparation thereof 失效导电，光学透明的聚合物/碳纳米管复合材料及其制备方法公开(公告)号：US07588699B2
公开(公告)日：2009-09-15
申请号：US10288797
申请日：2002-11-01
申请人： Cheol Park , Kent A. Watson , Zoubeida Ounaies , John W. Connell , Joseph G. Smith , Joycelyn S. Harrison
发明人： Cheol Park , Kent A. Watson , Zoubeida Ounaies , John W. Connell , Joseph G. Smith , Joycelyn S. Harrison
CPC分类号： B82Y10/00 , B82Y30/00 , C08F2/44 , C08G73/10 , C08G73/1039 , C08G73/1071 , C08K5/00 , C08K7/24 , C08K2201/011 , C08L71/123 , C09J11/04 , H01B1/24 , Y10T428/25 , Y10T428/29 , Y10T428/2904 , Y10T428/2913 , Y10T428/2918 , Y10T428/2975 , C08L71/12
摘要： The present invention is directed to the effective dispersion of carbon nanotubes (CNTs) into polymer matrices. The nanocomposites are prepared using polymer matrices and exhibit a unique combination of properties, most notably, high retention of optical transparency in the visible range (i.e., 400–800 nm), electrical conductivity, and high thermal stability. By appropriate selection of the matrix resin, additional properties such as vacuum ultraviolet radiation resistance, atomic oxygen resistance, high glass transition (Tg) temperatures, and excellent toughness can be attained. The resulting nanocomposites can be used to fabricate or formulate a variety of articles such as coatings on a variety of substrates, films, foams, fibers, threads, adhesives and fiber coated prepreg. The properties of the nanocomposites can be adjusted by selection of the polymer matrix and CNT to fabricate articles that possess high optical transparency and antistatic behavior.
摘要翻译： 本发明涉及碳纳米管（CNT）在聚合物基质中的有效分散。 使用聚合物基质制备纳米复合材料，并且表现出独特的性能组合，最显着的是在可见光范围（即400-800nm）中的高保留光学透明度，导电性和高热稳定性。 通过适当选择基体树脂，可以获得诸如真空紫外线辐射电阻，原子氧电阻，高玻璃化转变温度（Tg）等优异的韧性等附加特性。 所得的纳米复合材料可用于制造或配制各种制品，例如各种基材，薄膜，泡沫，纤维，线，粘合剂和纤维涂层预浸料上的涂层。 可以通过选择聚合物基质和CNT来调节具有高光学透明度和抗静电性能的制品来调节纳米复合材料的性能。
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