摘要:
Acylic or cyclic epoxyalcohols can be prepared by direct oxidation of an olefin when there is employed an ion-exchanged bimetallic catalyst, wherein one metal is from Groups IB or VIII, and the other from Group V.
摘要:
Novel block copolymer formed by melting blending a melt spinnable polyamide such as nylon-6 and a poly(oxa-amide) such as poly(4-oxaheptamethylene adipamide) (also known as N-303-6) is disclosed. Said copolymer has utility as a fiber. The fiber of copolymer, for example of nylon-6 and said poly-(oxa-amide) has superior absorption characteristics than that of nylon-6. Furthermore, resulting fiber (N-303-6//6) still substantially maintains the other desirable properties of the major constituent, for example nylon-6.
摘要:
Novel insecticidal compositions of matter having the formula: ##STR1## or mixtures thereof, wherein R.sub.1 and R.sub.2 are C.sub.1-20 hydrocarbyl groups which may be the same or different, or one of R.sub.1 and R.sub.2 may be hydrogen, and R.sub.3 and R.sub.4 are methyl or hydrogen and may be the same or different, can be prepared by the reaction of an alkyl ester, preferably the methyl ester, of polymethylmuconic acid with (C.sub.2 H.sub.5 O).sub.2 PSSH, the reaction product of ethanol and phosphorus pentasulfide.
摘要:
A friction or tractive drive comprises at least two relatively rotatable members in torque transmitting relationship, the tractive surfaces of the members having disposed thereon a tractant selected from the following groups (A) or (B):A. a tractant comprising a hydrocarbon dimer of an alkyladamantane and/or alkyladamantanol of the C.sub.12 -C.sub.19 range containing 1-3 alkyl groups of the C.sub.1 -C.sub.3 range, the dimer containing two adamantane nuclei which are linked to each other through an alkylene radical derived from and having the same number of carbon atoms as an alkyl group of the starting material; andB. an ether analogous to a hydrocarbon dimer from group (A) but in which there are two linkages between nuclei, one being an oxymethylene or oxyethylene radical, the other being a methylene or ethylene radical.
摘要:
Novel, highly fluorinated hydrocarbons derived from the fluorination of alkyladamantanes, may be produced by known means, as for example by the process comprising contacting an alkyladamantane hydrocarbon, in vapor phase, with a fluoride of a transition metal (e.g., CoF.sub.3, MnF.sub.3, AgF.sub.2) at 200.degree.-400.degree. C. The preferred adamantane hydrocarbons contain in the range of 11-30 (more preferred 12 to 14) carbon atoms and contain methyl and/or ethyl groups.
摘要:
An ammoxidation process for the preparation of nitriles by reaction of m- or p-xylene with ammonia and oxygen using as catalyst an .alpha.-alumina supported vanadiumalkali metal bronze promoted with niobium, whereby a high proportion of dinitrile product is obtained. The invention also embodies the niobium promoted catalyst.
摘要:
A process for the preparation of 1,3 or 1,4-bis (aminomethyl)cyclohexane by hydrogenating a solvent solution of iso- or terephthalonitrile at a temperature between about 50.degree. and about 150.degree. C., at a pressure of between about 500 and about 1500 psig., and in the presence of a supported rhodium catalyst.
摘要:
A 4-stage process for the production of catechol, starting with a mixture of cyclohexanol-cyclohexanone ("KA-oil"), is provided herein whereby the starting mixture is first hydrotreated to convert the cyclohexanone to cyclohexanol, the cyclohexanol dehydrated to form cyclohexene which, in turn, is oxidized to 1,2-epoxy-3-hydroxy-cyclohexane. Dehydrogenation of this latter compound yields catechol. Volatiles and residue from the second stage are advantageously recycled to the KA-oil feed stream, and H.sub.2 from the last stage recycled to the hydrotreating step.
摘要:
In an ammoxidation system where hydrocarbon, oxygen and ammonia are reacted at a temperature of from about 375.degree.C. to about 450.degree.C. in the presence of a vanadium bronze catalyst, the improvement of regenerating heat damaged catalyst by cooling the catalyst to below about 400.degree.C. and then reheating it to a temperature of from about 510.degree.C. to about 530.degree.C. in the presence of oxygen.
摘要:
This invention relates to novel liquid tertiary diamides having the following structural formula: ##EQU1## wherein n = 0 - 10 R = --(CH.sub.2).sub.m --CH.sub.3 wherein m = 4 - 12One such diamide is N,N'-2,2,5,5-tetramethylhexamethylene-N,N'-dimethylpelargonamide. The diamides have utility as heat transfer fluids and plasticizers.