公开(公告)号：US09353191B2

公开(公告)日：2016-05-31

申请号：US13491197

申请日：2012-06-07

Applicant: Alessandro Sannino ,  Christian Demitri ,  Yishai Zohar ,  Barry Joseph Hand ,  Eyal S. Ron

Inventor： Alessandro Sannino ,  Christian Demitri ,  Yishai Zohar ,  Barry Joseph Hand ,  Eyal S. Ron

IPC: C08B3/12 ,  C08B15/00 ,  C08J3/075 ,  C08L1/28 ,  C08B11/12 ,  C08B11/08 ,  C08B11/20 ,  C08L1/08

CPC classification number: C08B3/12 ,  C08B11/08 ,  C08B11/12 ,  C08B11/20 ,  C08B15/005 ,  C08J3/075 ,  C08J2301/00 ,  C08J2301/08 ,  C08J2301/26 ,  C08J2301/28 ,  C08L1/08 ,  C08L1/284 ,  C08L1/286 ,  Y10T428/2982

Abstract: The present invention provides a method of producing a polymer hydrogel comprising the steps of: (1) preparing an aqueous solution of a water soluble polysaccharide derivative and a polycarboxylic acid; (2) optionally agitating the solution, for example, by stirring; (3) isolating a polysaccharide derivative/polycarboxylic acid composite from the solution; and (4) heating the polysaccharide derivative/polycarboxylic acid composite at a temperature of at least about 80° C., thereby cross-linking the polysaccharide with the polycarboxylic acid. The invention also provides polymer hydrogels produced by the methods of the invention.

Abstract translation: 本发明提供一种制备聚合物水凝胶的方法，包括以下步骤：（1）制备水溶性多糖衍生物和多元羧酸的水溶液; （2）任选地搅拌溶液，例如通过搅拌; （3）从溶液中分离多糖衍生物/多元羧酸复合物; 和（4）在至少约80℃的温度下加热多糖衍生物/多元羧酸复合物，从而使多糖与多元羧酸交联。 本发明还提供了通过本发明的方法制备的聚合物水凝胶。

公开(公告)号：US20130089737A1

公开(公告)日：2013-04-11

申请号：US13491197

申请日：2012-06-07

Applicant: Alessandro Sannino ,  Christian Demitri ,  Yishai Zohar ,  Barry Joseph Hand ,  Eyal S. Ron

Inventor： Alessandro Sannino ,  Christian Demitri ,  Yishai Zohar ,  Barry Joseph Hand ,  Eyal S. Ron

IPC: C08B3/12

CPC classification number: C08B3/12 ,  C08B11/08 ,  C08B11/12 ,  C08B11/20 ,  C08B15/005 ,  C08J3/075 ,  C08J2301/00 ,  C08J2301/08 ,  C08J2301/26 ,  C08J2301/28 ,  C08L1/08 ,  C08L1/284 ,  C08L1/286 ,  Y10T428/2982

Abstract: The present invention provides a method of producing a polymer hydrogel comprising the steps of: (1) preparing an aqueous solution of a water soluble polysaccharide derivative and a polycarboxylic acid; (2) optionally agitating the solution, for example, by stirring; (3) isolating a polysaccharide derivative/polycarboxylic acid composite from the solution; and (4) heating the polysaccharide derivative/polycarboxylic acid composite at a temperature of at least about 80° C., thereby cross-linking the polysaccharide with the polycarboxylic acid. The invention also provides polymer hydrogels produced by the methods of the invention.

Abstract translation: 本发明提供一种制备聚合物水凝胶的方法，包括以下步骤：（1）制备水溶性多糖衍生物和多元羧酸的水溶液; （2）任选地搅拌溶液，例如通过搅拌; （3）从溶液中分离多糖衍生物/多元羧酸复合物; 和（4）在至少约80℃的温度下加热多糖衍生物/多元羧酸复合物，从而使多糖与多元羧酸交联。 本发明还提供了通过本发明的方法制备的聚合物水凝胶。

公开(公告)号：US06599327B2

公开(公告)日：2003-07-29

申请号：US10190188

申请日：2002-07-05

Applicant: David S. Soane ,  David A. Offord

Inventor： David S. Soane ,  David A. Offord

IPC: D06M13322

CPC classification number: C08B3/12 ,  C08B3/10 ,  C08B3/14 ,  C08B15/00 ,  D06M13/184 ,  D06M13/513 ,  D06M15/03 ,  D06M15/05 ,  D06M15/11 ,  D06M15/227 ,  D06M15/263 ,  D06M15/277 ,  D06M15/285 ,  D06M15/333 ,  D06M15/347 ,  D06M15/3562 ,  D06M15/643 ,  D06M23/00 ,  D06M23/005 ,  D06M2101/06 ,  D06M2101/12 ,  D06M2101/34 ,  D06M2400/01 ,  D06P1/653 ,  D06P5/04 ,  Y10T442/2164

Abstract: Provided are compounds and methods for modifying a material to change properties of the material, as well as a variety of products obtained using the methods. In one embodiment, a material comprising one or more modifiable functional groups is reacted with an activated hydrophobic acyl group in the presence of a hindered base, thereby to covalently attach the hydrophobic acyl group to the modifiable functional groups on the material. The material which is modified may be, for example, a carbohydrate, and the modifiable functional groups on the material may be hydroxyls. For example, materials such as cellulose may be modified by reacting it with an acid chloride or acid anhydride including a hydrophobic acyl group, in the presence of a hindered base, such as tripentylamine, to attach the hydrophobic acyl groups to the hydroxyls on the cellulose, thereby to increase the hydrophobicity of the cellulose. The methods and compounds disclosed herein may be used to modify materials to improve properties such as resistance, grease repellency, soil resistance and permanent press properties.

公开(公告)号：US20030005857A1

公开(公告)日：2003-01-09

申请号：US10223364

申请日：2002-08-20

Inventor： Masato Minami ,  Chieko Mihara ,  Toshihiko Takeda ,  Yoshihiko Kikuchi

IPC: B32B023/04

CPC classification number: C08B3/12 ,  C08G63/672 ,  C08L1/02 ,  Y10T428/3179 ,  Y10T428/31975 ,  C08L2666/02

Abstract: The present invention relates to a cellulose derivative having biodegradability, recycling properties, excellent mechanical strength and mold processability. The cellulose derivative is a product of a monosaccharide derivative or oligosaccharide derivative and cellulose. The monosaccharide derivative or oligosaccharide derivative is a copolymer of a saccharide and dicarboxylic acid.

Abstract translation: 本发明涉及具有生物降解性，再循环性，优异的机械强度和成型加工性的纤维素衍生物。 纤维素衍生物是单糖衍生物或寡糖衍生物与纤维素的产物。 单糖衍生物或寡糖衍生物是糖和二羧酸的共聚物。

公开(公告)号：US20020155771A1

公开(公告)日：2002-10-24

申请号：US10059657

申请日：2002-01-29

Applicant: Nano-Tex, LLC

Inventor： David S. Soane ,  David A. Offord

IPC: B32B009/00 ,  B32B003/00 ,  B32B005/02

CPC classification number: C08B3/12 ,  C08B3/10 ,  C08B3/14 ,  C08B15/00 ,  D06M13/184 ,  D06M13/513 ,  D06M15/03 ,  D06M15/05 ,  D06M15/11 ,  D06M15/227 ,  D06M15/263 ,  D06M15/277 ,  D06M15/285 ,  D06M15/333 ,  D06M15/347 ,  D06M15/3562 ,  D06M15/643 ,  D06M23/00 ,  D06M23/005 ,  D06M2101/06 ,  D06M2101/12 ,  D06M2101/34 ,  D06M2400/01 ,  D06P1/653 ,  D06P5/04 ,  Y10T442/2164

Abstract: Provided are compounds and methods for modifying a material to change properties of the material, as well as a variety of products obtained using the methods. The material which is modified may be, for example, a carbohydrate, and the modifiable functional groups on the material may be hydroxyls. Multifunctional molecules for use in modifying the surfaces of materials such as textile fibers, yams and other fabrics made of or, including cotton, wool and nylon, are provided. The multifunctional molecules can include hydrophobic regions and/or hydrophilic regions. The multifunctional molecules also may include binding functional groups that permit either non-covalent or covalent binding to the material being modified, thus permitting the multifunctional molecule to form a non-covalent or covalent coating on the material. The methods and compounds disclosed herein may be used to modify materials to improve properties such as resistance, grease repellency, soil resistance permanent press properties, and quickness of drying.

Abstract translation: 提供了用于改变材料以改变材料性质的化合物和方法，以及使用这些方法获得的各种产品。 被修饰的材料可以是例如碳水化合物，并且材料上的可修饰的官能团可以是羟基。 提供了用于改变材料表面的多功能分子，例如纺织纤维，纱线和由（或）棉，羊毛和尼龙制成的其它织物。 多官能分子可以包括疏水区和/或亲水区。 多官能分子还可以包括结合官能团，其允许与被修饰的材料非共价或共价结合，从而允许多官能分子在材料上形成非共价或共价涂层。 本文公开的方法和化合物可以用于改性材料以改善诸如电阻，拒油性，耐土壤永久性压制性能和干燥速度等性能。

公开(公告)号：US06468668B1

公开(公告)日：2002-10-22

申请号：US09394418

申请日：1999-09-13

Applicant: Masato Minami ,  Chieko Mihara ,  Toshihiko Takeda ,  Yoshihiko Kikuchi

Inventor： Masato Minami ,  Chieko Mihara ,  Toshihiko Takeda ,  Yoshihiko Kikuchi

IPC: B32B2710

CPC classification number: C08B3/12 ,  C08G63/672 ,  C08L1/02 ,  Y10T428/3179 ,  Y10T428/31975 ,  C08L2666/02

Abstract: The present invention relates to a cellulose derivative having biodegradability, recycling properties, excellent mechanical strength and mold processability. The cellulose derivative is a product of a monosaccharide derivative or oligosaccharide derivative and cellulose. The monosaccharide derivative or oligosaccharide derivative is a copolymer of a saccharide and dicarboxylic acid.

Abstract translation: 本发明涉及具有生物降解性，再循环性，优异的机械强度和成型加工性的纤维素衍生物。 纤维素衍生物是单糖衍生物或寡糖衍生物与纤维素的产物。 单糖衍生物或寡糖衍生物是糖和二羧酸的共聚物。

公开(公告)号：US4443595A

公开(公告)日：1984-04-17

申请号：US503677

申请日：1983-06-13

Applicant: Hajime Namikoshi ,  Yoshiaki Okumura ,  Tsuyoshi Sei

Inventor： Hajime Namikoshi ,  Yoshiaki Okumura ,  Tsuyoshi Sei

IPC: C08B3/00 ,  C08B3/12 ,  C08B3/14 ,  C08B15/00

CPC classification number: C08B3/12 ,  C08B3/14

Abstract: Novel cellulose ester derivatives having good solubility which are useful for coating agent, thickening agent, protective colloid, etc.; and a method for the preparation of said cellulose ester derivatives wherein cellulose is reacted with a specific lactone such as glycolide, lactide or .epsilon.-caprolactone in a solvent and in the presence of a catalyst for esterification.

Abstract translation: 具有良好溶解性的新型纤维素酯衍生物，可用于包衣剂，增稠剂，保护胶体等; 以及制备所述纤维素酯衍生物的方法，其中纤维素与特定内酯如乙交酯，丙交酯或ε-己内酯在溶剂中和在用于酯化的催化剂的存在下反应。

公开(公告)号：US3629237A

公开(公告)日：1971-12-21

申请号：US3629237D

申请日：1969-09-02

Applicant: SHINETSU CHEMICAL CO

Inventor： KOYANAGI SHUNICHI ,  OGAWA KINYA ,  YAMAMOTO AKIRA

IPC: A61K9/26 ,  A61K9/28 ,  A61K9/30 ,  A61K9/32 ,  C08B3/12 ,  C08B11/08 ,  C08B11/193 ,  C08B13/00 ,  C08B11/00

CPC classification number: C08B11/08 ,  A61K9/2866 ,  C08B3/12 ,  C08B11/193 ,  C08B13/00 ,  Y10S514/96

Abstract: ACID PHTHALATE OF CELLULOSE ETHERS REPRESENTED BY THE GENERAL FORMULA:

R1MR2NA

WHERE R1 IS A HYDROXYALKYL GROUP OF 3 OR 4 CARBON ATOMS, R2, HYDROGEN OR AN ALKYL GROUP OF 1 OR 2 CARBON ATOMS, M AND N ARE POSITIVE INTEGERS, AND A IS RESIDUAL CELLULOSE STRUCTURE WHICH ETHERS ARE READILY SOLUBLE IN WEAK ALKALINE SOLUTION, BESIDES POSSESSING HIGH SOLUBILITY IN ORGANIC SOLVENTS AND EXCELLENT RESISTANCE TO WATER; THEY ARE USEFUL AS ENTERIC COATINGS, AND DRUGS COATED WITH THEM CAN STAND LONG STORAGE AND ARE READILY SOLUBLE UPON PASSING INTO THE INTESTINES, THEREBY ENHANCING THE EFFECT OF THE DRUGS.

公开(公告)号：US3012952A

公开(公告)日：1961-12-12

申请号：US83686959

申请日：1959-08-31

Applicant: DU PONT

Inventor： WALTER SMITH CHARLES

IPC: C08B3/00 ,  C08B3/12 ,  C08B3/22 ,  C08B15/00 ,  C08F2/46 ,  C08F251/02 ,  C08L1/10 ,  G03F7/027 ,  G03F7/032

CPC classification number: C08B3/12 ,  C08B3/00 ,  C08B3/22 ,  C08B15/00 ,  C08F2/46 ,  C08F251/02 ,  C08L1/10 ,  G03F7/027 ,  G03F7/0325

公开(公告)号：US2856399A

公开(公告)日：1958-10-14

申请号：US63923357

申请日：1957-02-11

Applicant: EASTMAN KODAK CO

Inventor： MENCH JOHN W ,  LAPHAM GEORGE B

IPC: C08B3/00 ,  C08B3/12 ,  C08B13/00

CPC classification number: C08B3/00 ,  C08B3/12 ,  C08B13/00