摘要:
The present invention pertains to a compound represented by a formula (I) and a method for producing thereof (in the formula, Ax is an organic group having 2 to 30 carbon atoms that includes at least one aromatic ring selected from a group consisting of an aromatic hydrocarbon ring and an aromatic hetero ring, Ay is a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, a cycloalkyl group, an alkenyl group having 2 to 18 carbon atoms, an organic group having 2 to 30 carbon atoms that includes at least one aromatic ring selected from a group consisting of an aromatic hydrocarbon ring and an aromatic hetero ring, or the like. Ax and Ay optionally bond to each other to form a ring, and Q is a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or the like.). According to the invention, provided are a novel compound that makes it possible to produce an optical film that achieves uniform conversion of polarized light over a wide wavelength band can be inexpensively produced in high yield by utilizing the compound according to one aspect of the invention as an intermediate for producing the polymerizable compound, and a method for producing thereof.
摘要:
Disclosed are a novel asymmetric azine compound (I) and a method for producing an asymmetric azine compound (I) which is characterized in that an aldehyde compound (III) and hydrazine are reacted in an alcohol solvent at a molar ratio (aldehyde compound (III)):(hydrazine) of from 2:1 to 1:2, thereby obtaining a reaction solution including a hydrazone compound (IV), and then an aldehyde compound (V) is added for a reaction into the thus-obtained reaction solution at a molar ratio (aldehyde compound (V)):(hydrazone compound (IV)) of from 2:1 to 1:2. The method can commercially advantageously produce an asymmetric azine compound having a polar group such as a hydroxyl group or a carboxyl group in each molecule. The novel asymmetric azine compound can be obtained by this production method. (In the formulae, R1 and R2 each represents a hydroxyl group or a carboxyl group, X1 to X8 each represents a hydrogen atom, —C(═O)—OR3 or the like; and R3 represents an alkyl group having 1 to 10 carbon atoms or the like.)
摘要:
The present invention pertains to a compound represented by a formula (I) and a method for producing thereof (in the formula, Ax is an organic group having 2 to 30 carbon atoms that includes at least one aromatic ring selected from a group consisting of an aromatic hydrocarbon ring and an aromatic hetero ring, Ay is a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, a cycloalkyl group, an alkenyl group having 2 to 18 carbon atoms, an organic group having 2 to 30 carbon atoms that includes at least one aromatic ring selected from a group consisting of an aromatic hydrocarbon ring and an aromatic hetero ring, or the like. Ax and Ay optionally bond to each other to form a ring, and Q is a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or the like.). According to the invention, provided are a novel compound that makes it possible to produce an optical film that achieves uniform conversion of polarized light over a wide wavelength band can be inexpensively produced in high yield by utilizing the compound according to one aspect of the invention as an intermediate for producing the polymerizable compound, and a method for producing thereof.
摘要:
The present invention relates to a polymerizable compound represented by a formula (I). The present invention provides a polymerizable compound, a polymerizable composition, a polymer, and an optically anisotropic article that are capable of obtaining an optical film having a low melting point, having excellent solubility, capable of being manufactured at low cost, and capable of uniform polarized light conversion across a broad wavelength region. [In formula: Y1 to Y6 are independently a chemical single bond, —O—, —O—C(═O)—, —C(═O)—O— etc.; G1 and G2 are independently a divalent C1-C20 aliphatic group etc.; Z1 and Z2 are independently C2-C10 alkenyl group that is substituted with a halogen atom etc.; Ax is a C2-C30 organic group that includes at least one aromatic ring selected from a group consisting of an aromatic hydrocarbon ring and an aromatic hetero ring; Ay is a hydrogen atom, a C1-C20 alkyl group, a C2-C20 alkenyl group, a C3-C12 cycloalkyl group etc.; A1 is a trivalent aromatic group etc.; A2 and A3 are independently a divalent C6-C30 aromatic group etc.; and Q1 is a hydrogen atom, or a C1-C6 alkyl group etc.]
摘要:
A nonvolatile semiconductor memory device includes a memory cell array including cells provided at each of intersections of first and second lines and each having a variable resistance element and a first diode connected in series; a first line control circuit for supplying voltages to the first lines; and a second line control circuit for supplying voltages to the second lines, the cells each having one of the second lines connected to an anode side of the first diode and one of the first lines connected to a cathode side of the first diode, and the memory cell array including a second diode inserted in each of the second lines between the second line control circuit and the cells and each having a side of the second line control circuit as an anode and a side of the cells as a cathode.
摘要:
The present inventions to provide a novel polymerizable chiral compound (chiral agent) having high helical twisting power, a polymerizable liquid crystal composition comprising the polymerizable chiral compound and a polymerizable liquid crystal compound, a liquid crystal polymer, and an optically anisotropic body. The object was achieved by a polymerizable chiral compound represented by the following formula (I), a polymerizable liquid crystal composition comprising the polymerizable chiral compound and a polymerizable liquid crystal compound, a liquid crystal polymer, and an optically anisotropic body: wherein Y1 to Y8 are each —O—, —O—C(═O)—, —C(═O)—O— or the like; G1 and G2 are each a divalent aliphatic group having 1 to 20 carbon atoms or the like; Z1 and Z2 are each an alkenyl group having 2 to 10 carbon atoms or the like; Q1 to Q4 are each a hydrogen atom or the like; A1 to A6 are each a divalent aromatic group A having 6 to 30 carbon atoms; and X is any of groups represented by the following (X-i) to (X-vi): wherein * represents a bond and L1 to L4 are each an alkyl group having 1 to 4 carbon atoms or the like; and wherein, in the formula (I), a and b are each 0 or 1.
摘要:
An ether compound represented by the following formula and its use: wherein n represents 0 or 1, m represents an integer of 0 to 2, Y represents —O—, —S—, —C(═O)—O—, and —O—C(═O)—, X1 and X2 represent a hydrogen atom or a fluorine atom, and R represents an aliphatic hydrocarbon group having 1 to 20 carbon atoms and substituted with one or more fluorine atoms, with a proviso that, when m is 0, R has 3 to 20 carbon atoms. R may have in the bond thereof intervening oxygen atom, sulfur atom, and carbonyl group.
摘要:
A nonvolatile semiconductor memory device includes a memory cell array including cells provided at each of intersections of first and second lines and each having a variable resistance element and a first diode connected in series; a first line control circuit for supplying voltages to the first lines; and a second line control circuit for supplying voltages to the second lines, the cells each having one of the second lines connected to an anode side of the first diode and one of the first lines connected to a cathode side of the first diode, and the memory cell array including a second diode inserted in each of the second lines between the second line control circuit and the cells and each having a side of the second line control circuit as an anode and a side of the cells as a cathode.
摘要:
An acrylic rubber composition which contains, with respect to 100 parts by weight of acrylic rubber, a compound which is expressed by the following general formula (1) in 0.1 to 50 parts by weight and a cross-linking agent in 0.05 to 20 parts by weight is provided. (where, in said general formula (1), Y indicates a chemical single bond or —SO2—. Ra and Rb respectively independently indicate substitutable C1 to C30 organic groups. Za and Zb respectively independently indicate chemical single bonds or —SO2—. n and m respectively independently are 0 or 1, at least one of n and m being 1)
摘要:
A polymerizable liquid crystal compound shown by the following formula (I), a polymerizable liquid crystal composition that includes the polymerizable liquid crystal compound and a chiral compound polymerizable with the polymerizable liquid crystal compound, a liquid crystalline polymer obtained by polymerizing the polymerizable liquid crystal compound or the polymerizable liquid crystal composition, and an optical anisotropic article that includes the liquid crystalline polymer. The polymerizable liquid crystal compound shows a liquid crystal phase over a wider temperature range, is chemically stable, can be inexpensively produced, and has a wide selective reflection wavelength band Δλ (i.e., a large value Δn). The polymerizable liquid crystal composition includes the polymerizable liquid crystal compound, the liquid crystalline polymer is obtained by polymerizing the polymerizable liquid crystal compound or the polymerizable liquid crystal composition, and the optical anisotropic article includes the liquid crystalline polymer. wherein Y1 to Y6 represent —O—, —O—C(═O)—, —C(═O)—O—, or the like, G1 and G2 represent divalent aliphatic groups having 1 to 20 carbon atoms, Z1 and Z2 represent an alkenyl group having 2 to 10 carbon atoms or the like, A1 and A2 represent divalent organic groups A having 1 to 30 carbon atoms, X1 to X8 represent a hydrogen atom or the like, and a and b represent 0 or 1.