Polymerization catalysts
    4.
    发明授权
    Polymerization catalysts 失效
    聚合催化剂

    公开(公告)号:US07144839B2

    公开(公告)日:2006-12-05

    申请号:US10548275

    申请日:2004-03-18

    IPC分类号: C08F4/622 C08F4/623 C08F4/68

    摘要: A transition metal complex having the following Formula (A): wherein the monovalent groups R1 and R2 are —Ra, —ORb, —NRcRd, and —NHRe; the monovalent groups Ra, Rb, Rc, Rd and Re, and the divalent group R3 are (i) aliphatic hydrocarbon, (ii) alicyclic hydrocarbon, (iii) aromatic hydrocarbon, (iv) alkyl substituted aromatic hydrocarbon (v) heterocyclic groups and (vi) heterosubstituted derivatives of said groups (i) to (v); M is a Group (3) to (11) or lanthanide metal; E is phosphorus or arsenic; X is an anionic group, L is a neutral donor group; n is (1) or (2), y and z are independently zero or integers, such that the number of X and L groups satisfy the valency and oxidation state of the metal M. n is preferably (2) and the two resulting R1 groups are preferably linked. The complex can be used with optional activator to polymerise olefins

    摘要翻译: 具有下式(A)的过渡金属络合物:其中一价基团R 1和R 2是-R a,O, 其中R 1,R 2,R d,R d,R d, 一价基团R a a,R b,R c,R d,R d和R e, 并且二价基团R 3是(i)脂族烃,(ii)脂环族烃,(iii)芳族烃,(iv)烷基取代的芳族烃(v)杂环基和(vi )所述基团(i)至(v)的杂取代衍生物; M是第(3) - (11)族或镧系元素金属; E是磷或砷; X是阴离子基团,L是中性给体基团; n是(1)或(2),y和z独立地为0或整数,使得X和L基团的数量满足金属的价态和氧化态.n优选为(2),并且得到的两个R 优选连接1个以上的基团。 络合物可以与任选的活化剂一起使用以聚合烯烃

    Transition metal compound, polymerization catalysts for olefins, olefin polymers and process for their production
    5.
    发明申请
    Transition metal compound, polymerization catalysts for olefins, olefin polymers and process for their production 失效
    过渡金属化合物,烯烃聚合催化剂,烯烃聚合物及其生产方法

    公开(公告)号:US20020193536A1

    公开(公告)日:2002-12-19

    申请号:US10130306

    申请日:2002-05-31

    摘要: Useful as a catalyst component for polymerizing olefin is the transition metal compound of the present invention represented by Formula (I): 1 wherein M represents a transition metal compound of the fourth group in the periodic table; X represents a null bonding ligand; Y represents a Lewis base; T represents a group containing a null bonding atom; E is a specific group containing an atom which can coordinate with M via null lone pair; q is 1 or 2 and represents null(valency of M)null2null; r represents an integer of 0 to 3; R1 to R4 represent a hydrogen atom, a halogen atom, a hydrocarbon group, a halogen-containing hydrocarbon group, a silicon-containing group or a hetero atom-containing group.

    摘要翻译: 作为用于聚合烯烃的催化剂组分有用的是由式(I)表示的本发明的过渡金属化合物:其中M表示周期表中第四组的过渡金属化合物; X表示σ键配体; Y代表路易斯碱; T表示含有σ键原子的基团; E是一个特定的组,其中包含一个可以通过西格玛孤岛与M配合的原子; q为1或2,表示[(M的化合价)-2]; r表示0〜3的整数, R 1〜R 4表示氢原子,卤素原子,烃基,含卤素的烃基,含硅基团或含杂原子的基团。

    METHOD FOR SYNTHESIS OF MONOCYCLOPENTADIENYL COMPLEXES OF ZIRCONIUM AND HAFNIUM

    公开(公告)号:US20190194238A1

    公开(公告)日:2019-06-27

    申请号:US16287147

    申请日:2019-02-27

    发明人: C. Jeff Harlan

    摘要: Catalyst systems and methods for making and using the same are disclosed. In an example, a method of synthesizing a monocyclopentadienyl compound is provided. The method includes melting a dicyclopentadienyl compound including the following structure: As used herein, M is hafnium or zirconium. Each R is independently an H, a hydrocarbyl group, a substituted hydrocarbyl group, a heteroatom group. Each X is a leaving group selected from a halogen or a heteroatom group. A reaction melt is formed by adding a metal salt including the following structure: A monocyclopentadienyl compound is deposited from a vapor formed over the reaction melt, wherein the monocyclopentadienyl compound includes the following structure:

    Transition metal compounds, polymerization catalysts for olefins, olefin polymers and process for their production
    7.
    发明授权
    Transition metal compounds, polymerization catalysts for olefins, olefin polymers and process for their production 失效
    过渡金属化合物,烯烃聚合催化剂,烯烃聚合物及其生产方法

    公开(公告)号:US06730626B2

    公开(公告)日:2004-05-04

    申请号:US10130306

    申请日:2002-05-31

    IPC分类号: B01J3138

    摘要: Useful as a catalyst component for polymerizing olefin is the transition metal compound of the present invention represented by Formula (I): wherein M represents a transition metal compound of the fourth group in the periodic table; X represents a &sgr; bonding ligand; Y represents a Lewis base; T represents a group containing a &sgr; bonding atom; E is a specific group containing an atom which can coordinate with M via a lone pair; q is 1 or 2 and represents [(valency of M)−2]; r represents an integer of 0 to 3; R1 to R4 represent a hydrogen atom, a halogen atom, a hydrocarbon group, a halogen-containing hydrocarbon group, a silicon-containing group or a hetero atom-containing group.

    摘要翻译: 作为用于聚合烯烃的催化剂组分有用的是由式(I)表示的本发明的过渡金属化合物:其中M表示周期表中第四组的过渡金属化合物; X表示σ键配体; Y代表路易斯碱; T表示含有σ键原子的基团; E是一个特定的组,它包含一个可以通过一对孤立对与M配合的原子; q为1或2,表示[(M的化合价)-2]; r表示0〜3的整数, R 1至R 4表示氢原子,卤素原子,烃基,含卤素的烃基,含硅基团或含杂原子的基团。