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公开(公告)号:US07998895B2
公开(公告)日:2011-08-16
申请号:US12184467
申请日:2008-08-01
申请人: Lin Wang , Elisabeth M. Hauptman , Lynda Kaye Johnson , Elizabeth Forrester McCord , Stephan J. McLain , Ying Wang
发明人: Lin Wang , Elisabeth M. Hauptman , Lynda Kaye Johnson , Elizabeth Forrester McCord , Stephan J. McLain , Ying Wang
CPC分类号: C08F10/00 , B01J31/1805 , B01J31/2282 , B01J2231/122 , B01J2531/847 , C07F9/46 , C07F9/5004 , C07F9/5009 , C07F15/0066 , C07F15/04 , C07F15/045 , C08F4/619 , C08F110/02 , C08F210/02 , C08F2500/04 , C08F2500/10 , C08F2500/20 , C08F220/10 , C08F2500/03 , C08F220/12 , C08F4/6028 , C08F4/64065 , C08F4/7031 , C08F4/7029 , C08F4/7019 , C08F4/7022 , C08F4/7014 , C08F4/7008 , C08F4/7006 , C08F4/40
摘要: Transition metal complexes of selected monoanionic phosphine ligands, which also contain a selected Group 15 or 16 (IUPAC) element and which are coordinated to a Group 3 to 11 (IUPAC) transition metal or a lanthanide metal, are polymerization catalysts for the (co)polymerization of olefins such as ethylene and α-olefins, and the copolymerization of such olefins with polar group-containing olefins. These and other nickel complexes of neutral and monoanionic bidentate ligands copolymerize ethylene and polar comonomers, especially acrylates, at relatively high ethylene pressures and surprisingly high temperatures, and give good incorporation of the polar comonomers and good polymer productivity. These copolymers are often unique structures, which are described.
摘要翻译: 还包含选定的第15或16族(IUPAC)元素并且与第3至11族(IUPAC)过渡金属或镧系元素金属配位的选择性单阴离子膦配体的过渡金属络合物是用于(共) 烯烃如乙烯和α-烯烃的聚合,以及这些烯烃与极性基团烯烃的共聚。 中性和单阴离子双齿配体的这些和其它镍配合物在相对高的乙烯压力和惊人的高温下共聚乙烯和极性共聚单体,特别是丙烯酸酯,并且使极性共聚单体具有良好的掺入性和良好的聚合物生产率。 这些共聚物通常是独特的结构,其被描述。
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公开(公告)号:US20100222531A1
公开(公告)日:2010-09-02
申请号:US12779182
申请日:2010-05-13
申请人: Lin Wang , Elisabeth M. Hauptman , Lynda Kaye Johnson , Elizabeth Forrester McCord , Stephan J. McLain , Ying Wang
发明人: Lin Wang , Elisabeth M. Hauptman , Lynda Kaye Johnson , Elizabeth Forrester McCord , Stephan J. McLain , Ying Wang
IPC分类号: C08F4/42 , B01J31/02 , C08F118/02 , C07F9/28
CPC分类号: C08F10/00 , B01J31/1805 , B01J31/2282 , B01J2231/122 , B01J2531/847 , C07F9/46 , C07F9/5004 , C07F9/5009 , C07F15/0066 , C07F15/04 , C07F15/045 , C08F4/619 , C08F110/02 , C08F210/02 , C08F2500/04 , C08F2500/10 , C08F2500/20 , C08F220/10 , C08F2500/03 , C08F220/12 , C08F4/6028 , C08F4/64065 , C08F4/7031 , C08F4/7029 , C08F4/7019 , C08F4/7022 , C08F4/7014 , C08F4/7008 , C08F4/7006 , C08F4/40
摘要: Transition metal complexes of selected monoanionic phosphine ligands, which also contain a selected Group 15 or 16 (IUPAC) element and which are coordinated to a Group 3 to 11 (IUPAC) transition metal or a lanthanide metal, are polymerization catalysts for the (co)polymerization of olefins such as ethylene and α-olefins, and the copolymerization of such olefins with polar group-containing olefins. These and other nickel complexes of neutral and monoanionic bidentate ligands copolymerize ethylene and polar comonomers, especially acrylates, at relatively high ethylene pressures and surprisingly high temperatures, and give good incorporation of the polar comonomers and good polymer productivity. These copolymers are often unique structures, which are described.
摘要翻译: 还包含选定的第15或16族(IUPAC)元素并且与第3至11族(IUPAC)过渡金属或镧系元素金属配位的选择性单阴离子膦配体的过渡金属络合物是用于(共) 烯烃如乙烯和α-烯烃的聚合,以及这些烯烃与极性基团烯烃的共聚。 中性和单阴离子双齿配体的这些和其它镍配合物在相对高的乙烯压力和惊人的高温下共聚乙烯和极性共聚单体,特别是丙烯酸酯,并且使极性共聚单体具有良好的掺入性和良好的聚合物生产率。 这些共聚物通常是独特的结构,其被描述。
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公开(公告)号:US20090143550A1
公开(公告)日:2009-06-04
申请号:US12002925
申请日:2007-12-19
申请人: Steven Dale Ittel , Lynda Kaye Johnson , Lin Wang , Ying Wang , Elizabeth Forrester McCord , Chatherine E. Radzewich , Stephan J. McLain , Karl J. Sweetman , Alison Margaret Anne Bennett , Alex Sergey Ionkin , Rinaldo S. Schiffino
发明人: Steven Dale Ittel , Lynda Kaye Johnson , Lin Wang , Ying Wang , Elizabeth Forrester McCord , Chatherine E. Radzewich , Stephan J. McLain , Karl J. Sweetman , Alison Margaret Anne Bennett , Alex Sergey Ionkin , Rinaldo S. Schiffino
CPC分类号: C08F210/02 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/619 , C08F2500/03 , C08F2500/10 , C08F230/08 , C08F2500/04 , C08F2500/12 , C08F210/06 , C08F4/7006
摘要: Ethylene and allyl- or vinylsilanes are efficiently copolymerized by certain late transition metal complexes containing selected bidentate or tridentate ligands. The resulting novel polymers may be crosslinked by moisture when vinylsilane contains groups bound to silicon which are hydrolyzable. The polymers are useful for wire coating, crosslinked foams, pipes, and other uses.
摘要翻译: 乙烯和烯丙基或乙烯基硅烷通过含有选择的二齿或三齿配体的某些后期过渡金属络合物有效共聚。 当乙烯基硅烷含有与可水解的硅结合的基团时,所得到的新型聚合物可以通过水分交联。 聚合物可用于线涂,交联泡沫,管道和其他用途。
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公开(公告)号:US07348388B2
公开(公告)日:2008-03-25
申请号:US10295606
申请日:2002-11-15
申请人: Steven Dale Ittel , Lynda Kaye Johnson , Lin Wang , Ying Wang , Elizabeth Forrester McCord , Catherine E. Radzewich , Stephan J. Mclain , Karl J. Sweetman , Alison Margaret Anne Bennett , Alex Sergey Ionkin , Rinaldo S. Schiffino
发明人: Steven Dale Ittel , Lynda Kaye Johnson , Lin Wang , Ying Wang , Elizabeth Forrester McCord , Catherine E. Radzewich , Stephan J. Mclain , Karl J. Sweetman , Alison Margaret Anne Bennett , Alex Sergey Ionkin , Rinaldo S. Schiffino
IPC分类号: C08G30/08
CPC分类号: C08F210/02 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/619 , C08F2500/03 , C08F2500/10 , C08F230/08 , C08F2500/04 , C08F2500/12 , C08F210/06 , C08F4/7006
摘要: Ethylene and allyl- or vinylsilanes are efficiently copolymerized by certain late transition metal complexes containing selected bidentate or tridentate ligands. The resulting novel polymers may be crosslinked by moisture when vinylsilane contains groups bound to silicon which are hydrolyzable. The polymers are useful for wire coating, crosslinked foams, pipes, and other uses.
摘要翻译: 乙烯和烯丙基或乙烯基硅烷通过含有选择的二齿或三齿配体的某些后期过渡金属络合物有效共聚。 当乙烯基硅烷含有与可水解的硅结合的基团时,所得到的新型聚合物可以通过水分交联。 聚合物可用于线涂,交联泡沫,管道和其他用途。
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公开(公告)号:US06897275B2
公开(公告)日:2005-05-24
申请号:US09871099
申请日:2001-05-31
申请人: Lin Wang , Elisabeth Hauptman , Lynda Kaye Johnson , Elizabeth Forrester McCord , Ying Wang , Steven Dale Ittel
发明人: Lin Wang , Elisabeth Hauptman , Lynda Kaye Johnson , Elizabeth Forrester McCord , Ying Wang , Steven Dale Ittel
IPC分类号: C07C251/08 , B01J31/00 , C07C251/20 , C07C251/24 , C07F5/06 , C07F7/00 , C07F9/50 , C07F9/572 , C07F9/58 , C07F15/04 , C07F19/00 , C08F4/00 , C08F4/06 , C08F4/16 , C08F4/44 , C08F4/60 , C08F4/605 , C08F4/619 , C08F4/642 , C08F4/70 , C08F4/76 , C08F4/80 , C08F10/00 , C08F10/02 , C08F110/02 , C08F118/02 , C08F210/00 , C08F210/02
CPC分类号: C08F10/00 , B01J31/1805 , B01J31/2282 , B01J2231/122 , B01J2531/847 , C07F9/46 , C07F9/5004 , C07F9/5009 , C07F15/0066 , C07F15/04 , C07F15/045 , C08F4/619 , C08F110/02 , C08F210/02 , C08F2500/04 , C08F2500/10 , C08F2500/20 , C08F220/10 , C08F2500/03 , C08F220/12 , C08F4/6028 , C08F4/64065 , C08F4/7031 , C08F4/7029 , C08F4/7019 , C08F4/7022 , C08F4/7014 , C08F4/7008 , C08F4/7006 , C08F4/40
摘要: Transition metal complexes of selected monoanionic phosphine ligands, which also contain a selected Group 15 or 16 (IUPAC) element and which are coordinated to a Group 3 to 11 (IUPAC) transition metal or a lanthanide metal, are polymerization catalysts for the (co)polymerization of olefins such as ethylene and α-olefins, and the copolymerization of such olefins with polar group-containing olefins. These and other nickel complexes of neutral and monoanionic bidentate ligands copolymerize ethylene and polar comonomers, especially acrylates, at relatively high ethylene pressures and surprisingly high temperatures, and give good incorporation of the polar comonomers and good polymer productivity. These copolymers are often unique structures, which are described.
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公开(公告)号:US08022152B2
公开(公告)日:2011-09-20
申请号:US12002925
申请日:2007-12-19
申请人: Steven Dale Ittel , Lynda Kaye Johnson , Lin Wang , Ying Wang , Elizabeth Forrester McCord , Catherine E. Radzewich , Stephan James McLain , Karl Jeffrey Sweetman , Alison Margaret Anne Bennett , Alex Sergey Ionkin , Rinaldo Soria Schiffino
发明人: Steven Dale Ittel , Lynda Kaye Johnson , Lin Wang , Ying Wang , Elizabeth Forrester McCord , Catherine E. Radzewich , Stephan James McLain , Karl Jeffrey Sweetman , Alison Margaret Anne Bennett , Alex Sergey Ionkin , Rinaldo Soria Schiffino
IPC分类号: C08F2/38 , C08F4/00 , C08F30/08 , C08F210/00
CPC分类号: C08F210/02 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/619 , C08F2500/03 , C08F2500/10 , C08F230/08 , C08F2500/04 , C08F2500/12 , C08F210/06 , C08F4/7006
摘要: Ethylene and allyl- or vinylsilanes are efficiently copolymerized by certain late transition metal complexes containing selected bidentate or tridentate ligands. The resulting novel polymers may be crosslinked by moisture when vinylsilane contains groups bound to silicon which are hydrolyzable. The polymers are useful for wire coating, crosslinked foams, pipes, and other uses.
摘要翻译: 乙烯和烯丙基或乙烯基硅烷通过含有选择的二齿或三齿配体的某些后期过渡金属络合物有效共聚。 当乙烯基硅烷含有与可水解的硅结合的基团时,所得到的新型聚合物可以通过水分交联。 聚合物可用于线涂,交联泡沫,管道和其他用途。
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公开(公告)号:US06689910B2
公开(公告)日:2004-02-10
申请号:US10437685
申请日:2003-05-12
申请人: Lin Wang , Samuel David Arthur , Elizabeth Forrester McCord , Yueli Wang , Peter Arnold Morken , Lynda Kaye Johnson
发明人: Lin Wang , Samuel David Arthur , Elizabeth Forrester McCord , Yueli Wang , Peter Arnold Morken , Lynda Kaye Johnson
IPC分类号: C07C23305
CPC分类号: C07C309/82
摘要: Olefins containing selected functional groups such as silyl, ether and alkenyl, and often containing a blocking group, may be copolymerized with unsubstituted olefins such as ethylene and propylene in the presence of certain coordination compounds of nickel or palladium. The resulting polymers are useful as molding resins, elastomers, in adhesives and for films.
摘要翻译: 含有选择的官能团的烯烃,例如甲硅烷基,醚和烯基,并且通常含有封闭基团,可以在镍或钯的某些配位化合物的存在下与未取代的烯烃如乙烯和丙烯共聚。 所得聚合物可用作模塑树脂,弹性体,粘合剂和薄膜。
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公开(公告)号:US06482907B1
公开(公告)日:2002-11-19
申请号:US09496105
申请日:2000-02-01
申请人: Lin Wang , Samuel David Arthur , Elizabeth Forrester McCord , Yueli Wang , Peter Arnold Morken , Lynda Kaye Johnson
发明人: Lin Wang , Samuel David Arthur , Elizabeth Forrester McCord , Yueli Wang , Peter Arnold Morken , Lynda Kaye Johnson
IPC分类号: C08F470
CPC分类号: C07C309/82
摘要: Olefins containing selected functional groups such as silyl, ether and alkenyl, and often containing a blocking group, may be copolymerized with unsubstituted olefins such as ethylene and propylene in the presence of certain coordination compounds of nickel or palladium. The resulting polymers are useful as molding resins, elastomers, in adhesives and for films.
摘要翻译: 含有选择的官能团的烯烃,例如甲硅烷基,醚和烯基,并且通常含有封闭基团,可以在镍或钯的某些配位化合物的存在下与未取代的烯烃如乙烯和丙烯共聚。 所得聚合物可用作模塑树脂,弹性体,粘合剂和薄膜。
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公开(公告)号:US06605679B1
公开(公告)日:2003-08-12
申请号:US09496114
申请日:2000-02-01
申请人: Lin Wang , Samuel David Arthur , Elizabeth Forrester McCord , Yueli Wang , Peter Arnold Morken , Lynda Kaye Johnson
发明人: Lin Wang , Samuel David Arthur , Elizabeth Forrester McCord , Yueli Wang , Peter Arnold Morken , Lynda Kaye Johnson
IPC分类号: C08F21418
CPC分类号: C07C309/82
摘要: Olefins containing selected functional groups such as silyl, ether and alkenyl, and often containing a blocking group, may be copolymerized with unsubstituted olefins such as ethylene and propylene in the presence of certain coordination compounds of nickel or palladium. The resulting polymers are useful as molding resins, elastomers, in adhesives and for films.
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公开(公告)号:US5866663A
公开(公告)日:1999-02-02
申请号:US891332
申请日:1997-07-10
申请人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Lin Wang , Zhen-Yu Yang
发明人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Lin Wang , Zhen-Yu Yang
IPC分类号: B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号: C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译: 本文公开了聚合乙烯,无环烯烃和/或选择的环烯烃,和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物,有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性,因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的,特别是在它们的微结构方面,这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂,以及一些制备它们的新方法。 制备的聚合物可用作弹性体,模塑树脂,粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃,将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸,或通过使选择的α-二亚胺镍络合物与乙烯接触。
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