摘要:
The invention is directed to a macromer comprising unit derived from a siloxane diol, di-isocyanates and a diol comprising a pendant group comprising an oligomer or polymer derived from methyl oxazoline or ethyl oxazoline. The invention also relates to a process for the preparation of said macromers, and to that the use of said macromers. The macromers according to the invention may be used in lenses, such as ophthalmic lenses. Films comprising the macromers according to the invention provide a surprisingly low modulus in combination with a high water content and oxidative stability.
摘要:
A plurality of solid particles including a thermoplastic composition having a softening temperature in a range from 50° C. to 180° C. and a blocked isocyanate resin; optionally at least some of the particles in the plurality of solid particles comprise both the thermoplastic composition and the blocked isocyanate resin. A composition comprising the plurality of particles dispersed in a fluid is also disclosed. A method of modifying a wellbore within a geological formation is also disclosed. The method includes introducing the fluid composition into the wellbore. A method of making a plurality of particles, for example, to use in the fluid composition, is also disclosed.
摘要:
Polyurethane carpet backings are made using a polyurethane-forming composition that includes fatty acid amide polyols. The formulation allows a significant replacement of conventional polyols with polyols derived from annually renewable resources, while maintaining important properties like edge curl, tuftbind, viscosity and curing rates.
摘要:
A microcapsule which includes a polymer as a capsule wall of the microcapsule, in which the polymer is obtained by polymerizing a dendritic branching molecule having a hydroxyl group in a terminal thereof, an isocyanate compound, and a compound having two or more active hydrogen atoms in a molecule thereof. A process for manufacturing a microcapsule includes the step of polymerizing an isocyanate compound, a dendritic branching molecule having a hydroxyl group in a terminal thereof, and a compound having two or more active hydrogen atoms in a molecule thereof, so as to form a capsule wall of the microcapsule.
摘要:
The present invention relates to ionic and nonionic polyamide modified polyurethane polymers for use in coating compositions, a method for forming the polymer and coating compositions containing these polymers. The polyamide modified polyurethane polymers of the present invention include polyamide formed from aromatic, aliphatic, or cycloaliphatic anhydrides or diacid halides and an amine containing compound such as amino alcohol, amino thiol, diamine or mixtures thereof, wherein the reactive terminii of the polyamide ere substituted by hydroxyl or thiol functional groups, together with a chain extending alcohol and diisocyanate functional monomer.
摘要:
A thermoplastic polyamide urethane urea resin of improved properties which is derived from (A) a linear polyhydroxylterminated oligomer free from ethylene terephthalate unit, which has an average molecular weight of 400 to 4,000 and is liquid at 80*C., (B) a hydroxyl-terminated polyester oligomer having an average molecular weight of 500 to 4,000 and a melting point of 50* to 220*C., 55 to 100 mol% of its molecular chain consisting of ethylene terephthalate and ethylene naphthalate units, and in which ethylene terephthalate unit occupying 50 to 85 mol% of the polyester oligomer, (C) a linear polyamide oligomer having an average molecular weight of 400 to 4,000 and a melting pont of 100* to 200*C., at least 80% of the terminal groups thereof being amino groups, and (D) an organic diisocyanate; the composition of the reactions (A) through (D) satisfying the expressions below: I. 0.8
摘要:
WATER ABSORPTIVE POLYURETHANE POLYMERS PREPARED FROM RESINS HAVING A LOW RATIO OF CARBON TO OXYGEN TO NITROGEN OR HAVING IONIC, QUATERNARY AMMONIUM OR SALT GROUPS IN THE RESIN BACKBONE AND A LOW AMOUNT OF ISOCYANATE. THE WATER ABSORPTIVITY OF THE POLYURETHANE POLYMERS IS ABOUT 10%, PREFERABLY ABOVE 20%, AND THESE POLYMERS MAY RANGE TO COMPLETELY GEL-LIKE, HIGH WATER ABSORPTIVE, POLYMERS; THESE POLYMERS ARE USEFUL AS COATINGS, MEMBRANES, ETC.
摘要:
1,134,213. Coated sheet material. COURTAULDS Ltd. 15 Feb., 1966 [16 Feb., 1965], No. 6588/65. Addition to 1,087,867. Heading B2E [Also in Division C3] A gas permeable laminated sheet is produced by forming a solution of a block copolymer having segments of a polyamide and a polymeric substance having a melting point of less than 80‹C, the solution also containing a dissolved elastomer, applying the solution to a coherent fibrouslayer, precipitating the copolymer from the solution to form a gel containing residual solvent and reducing the solvent content of the gel at a temperature below the glass temperature of the gel, whereby the copolymer tends to aggregate in interconnected micelles, generating pores in the gel. The solvent is preferably an aqueous solution of alkali metal or alkaline earth metal thiocyanate containing ethyl or methyl alcohol but other salts e.g. alkaline earth metal halides, ZnC1 2 and LiBr, are useful. The elastomer may be a copolymer of at least two acrylates, an acrylonitrile-alkyl acrylate copolymer, the alkyl group containing at least two carbon atoms, or an acrylonitrile-butadiene copolymer containing at least 40% of acrylonitrile units. The elastomer may be formed in situ in the salt solution which may contain the block polymer by copolymerizing acrylate with another, or with acrylonitrile. The polyamide may be a homo or random copolymer e.g. nylon or a copolymer of caprolactam and hexamethylene adipamide salt. The elastomer segment of the block polymer may be a polyether carrying terminal isocyanate groups, which may be reacted with an amine terminated polyamide in the presence of the solvent so that the copolymer is formed in solution. The weight ratio of the block copolymer to the elastomer may be between 2:3 and 3:2. The solution may be applied by doctor blade to a dense felt of crimped nylon bonded with an elastomer and the coated felt is washed with water to remove the thiocyanate.
摘要:
The invention is directed to a macromer comprising unit derived from a siloxane diol, di-isocyanates and a diol comprising a pendant group comprising an oligomer or polymer derived from methyl oxazoline or ethyl oxazoline. The invention also relates to a process for the preparation of said macromers, and to that the use of said macromers. The macromers according to the invention may be used in lenses, such as ophthalmic lenses. Films comprising the macromers according to the invention provide a surprisingly low modulus in combination with a high water content and oxidative stability.