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    Trisazo compounds useful in producing water-resistant ink compositions
    1.
    发明授权
    Trisazo compounds useful in producing water-resistant ink compositions 失效
    可用于生产防水油墨组合物的三唑类化合物

    公开(公告)号：US4734489A

    公开(公告)日：1988-03-29

    申请号：US844589

    申请日：1986-03-27

    申请人： Shinjiro Kawasaki ,  Hideo Kitagawa ,  Yutaka Nishii ,  Hideo Kawashita ,  Minoru Akagi

    发明人： Shinjiro Kawasaki ,  Hideo Kitagawa ,  Yutaka Nishii ,  Hideo Kawashita ,  Minoru Akagi

    IPC分类号： C09B35/46 ,  C09D11/00 ,  C09B31/18 ,  C09B33/22 ,  C09D11/18

    CPC分类号： C09D11/328 ,  C09B35/461

    摘要： An azo compound of the formula: ##STR1## wherein R is of the formula: ##STR2## R.sub.1 is hydrogen, methyl or --SO.sub.3 M; R.sub.2 is hydrogen or --SO.sub.3 M; R.sub.2 is hydrogen or --SO.sub.3 M; R.sub.3 is C.sub.4 -C.sub.18 alkyl and M is hydrogen, an alkali metal, ammonium or organic ammonium, provided that when R includes --SO.sub.3 M, R.sub.1 l and R.sub.2 are not --SO.sub.3 M, and when R does not include --SO.sub.3 M, either one of R.sub.1 and R.sub.2 is --SO.sub.3 M, which is useful as a black dyestuff for a solvent type ink composition, particularly for ink jet recording.

    摘要翻译： 下式的偶氮化合物：其中R为下式：其中R为下式：其中R 1为氢，甲基或-SO 3 M; R2是氢或-SO3M; R2是氢或-SO3M; R 3是C 4 -C 18烷基，M是氢，碱金属，铵或有机铵，条件是当R包括-SO 3 M时，R 1和R 2不是-SO 3 M，当R不包括-SO 3 M时，R 1 R2是-SO3M，可用作溶剂型油墨组合物的黑色染料，特别是用于喷墨记录。

    Trisazo dyes, inks comprising same and their use in ink jet printing
    5.
    发明授权
    Trisazo dyes, inks comprising same and their use in ink jet printing 失效
    三唑系染料，包含其的油墨及其在喷墨印刷中的用途

    公开(公告)号：US5423906A

    公开(公告)日：1995-06-13

    申请号：US108425

    申请日：1993-08-19

    申请人： Peter Gregory ,  Prahalad M. Mistry

    发明人： Peter Gregory ,  Prahalad M. Mistry

    IPC分类号： B41M5/00 ,  C09B35/46 ,  C09B67/22 ,  C09D11/00 ,  C09D11/02 ,  D06P5/00

    CPC分类号： C09D11/328 ,  C09B35/461 ,  Y10T428/31993

    摘要： A compound of Formula (1) or salt thereof: ##STR1## wherein: R.sup.1 is H, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, CO.sub.2 H, SO.sub.3 H or --NR.sup.3 R.sup.4 ;R.sup.2 is H, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, CO.sub.2 H or SO.sub.3 H;R.sup.3 and R.sup.4 are each independently H, C.sub.1-18 -alkyl or R.sup.3 and R.sup.4, together with the nitrogen atom to which they are attached, form an optionally substituted 5- or 6-membered ring;W is --OH and X is --NH.sub.2, or W is --NH.sub.2 and X is --OH; andY and Z are each independently --OH or --NR.sup.3 R.sup.4.The compound is suitable for use as a black component of ink jet printing inks.

    摘要翻译： 式（1）的化合物或其盐：其中：R 1是H，C 1-4 - 烷基，C 1-4 - 烷氧基，CO 2 H，SO 3 H或-NR 3 R 4; R2是H，C1-4 - 烷基，C1-4 - 烷氧基，CO2H或SO3H; R 3和R 4各自独立地为H，C 1-18 - 烷基或R 3和R 4与它们所连接的氮原子一起形成任选取代的5-或6-元环; W是-OH，X是-NH 2，或W是-NH 2，X是-OH; Y和Z各自独立地为-OH或-NR 3 R 4。 该化合物适合用作喷墨印刷油墨的黑色组分。

    Trisazo dyes having a 2,7-(1-amino-3,6-or 4,6-disulfo-8-hydroxynaphthylene) radical
    6.
    发明授权
    Trisazo dyes having a 2,7-(1-amino-3,6-or 4,6-disulfo-8-hydroxynaphthylene) radical 失效
    具有2,7-（1-氨基-3,6或4,6-二磺基-8-羟基萘乙烯）基的三偶氮染料

    公开(公告)号：US4097476A

    公开(公告)日：1978-06-27

    申请号：US585663

    申请日：1975-06-10

    申请人： Heinz Wicki

    发明人： Heinz Wicki

    IPC分类号： C09B35/46 ,  D21H21/28 ,  C09B31/24 ,  D06P1/06 ,  D06P3/32

    CPC分类号： C09B35/461

    摘要： Disclosed are compounds of the formula, ##STR1## in which X is hydrogen, chlorine, C.sub.1-4 alkyl or alkoxy, --SO.sub.3 M or --CO.sub.2 M, one of the Y's is hydrogen, the other --SO.sub.3 M, A is a mono- or di-sulphonaphthyl radical which is optionally further substituted, or ##STR2## in which R is hydrogen, hydroxy or C.sub.1-4 alkyl or alkoxy, B is a radical or a coupling component (b.sub.1) to (b.sub.10), ##STR3## WHERE R.sub.1 is --NH.sub.2, anilino or toluidino, R.sub.2 is --NH.sub.2 or --OH, and Either R.sub.3 is hydrogen, or When R.sub.1 and R.sub.2 both are --NH.sub.2, R.sub.3 is hydrogen, --SO.sub.3 M or C.sub.1-4 alkyl; ##STR4## WHERE R.sub.4 is hydrogen or C.sub.1-4 alkyl; ##STR5## WHERE R.sub.5 is hydrogen or --CO.sub.2 M; ##STR6## WHERE ONE OF THE Y.sub.1 's is hydrogen, the other --SO.sub.3 M; ##STR7## WHERE R.sub.6 is phenyl or C.sub.1-4 alkylphenyl; ##STR8## where R.sub.7 is --OH or --NH.sub.2, R.sub.8 is hydrogen, phenyl or sulphophenyl, and R.sub.9 is C.sub.1-4 alkyl or --CO.sub.2 M, and the M's independently, signify hydrogen or a non-chromophoric cation, their production and use for dyeing and printing anionic dyeable substrates, e.g., natural and regenerated cellulose, natural and synthetic polyamides, polyurethanes and basically modified polypropylene and particularly leather, paper and anodized aluminum. The obtained dyeings have shades ranging from deep green or blue to black. The dyeings on paper exhibit notable fastness to water and water-spotting while the dyeings on leather are level and exhibit good fastness to perspiration, dry cleaning, water, water-spotting and buffing and resistance to migration onto polyvinyl chloride.

    摘要翻译： 公开了下式的化合物，其中X是氢，氯，C 1-4烷基或烷氧基，-SO 3 M或-CO 2 M，Y之一是氢，另一个-SO 3 M，A是单或二 - 其中R是氢，羟基或C 1-4烷基或烷氧基，B是自由基或偶合组分（b1）至（b10），（b1）其中R 1，R 2， 是-NH 2，苯胺基或甲苯酰基，R 2是-NH 2或-OH，并且R 3是氢，或者当R 1和R 2都是-NH 2，R 3是氢，-SO 3 M或C 1-4烷基时; （b2）R4为氢或C1-4烷基; （b3）R5是氢或-CO 2 M; （b4）（b5）（b6）Y1中的一个是氢，另一个-SO 3 M; （b7）（b8）（b9）R6是苯基或C1-4烷基苯基; （b10）其中R7是-OH或-NH2，R8是氢，苯基或磺基苯基，R9是C1-4烷基或-CO2M，M独立地表示氢或非发色阳离子，它们的生产和 用于染色和印刷阴离子可染色基材，例如天然和再生纤维素，天然和合成聚酰胺，聚氨酯和基本上改性的聚丙烯，特别是皮革，纸和阳极氧化铝。 获得的染色有从深绿色或蓝色到黑色的色调。 纸上的染色表现出显着的耐水牢度和耐水斑性，而皮革上的染色水平，表现出良好的出汗牢度，干洗，水分，水斑和抛光以及耐氯迁移性。

    Process for dyeing oxide layers on aluminum and aluminum alloys
    7.
    发明授权
    Process for dyeing oxide layers on aluminum and aluminum alloys 失效
    在铝和铝合金上氧化层的染色工艺

    公开(公告)号：US3917887A

    公开(公告)日：1975-11-04

    申请号：US43613074

    申请日：1974-01-24

    申请人： SANDOZ AG

    发明人： STILLER FRANK P

    IPC分类号： C09B35/46 ,  C25D11/24 ,  C23F5/04

    CPC分类号： C25D11/243 ,  C09B35/461

    摘要： Dyes of the formula

    WHEREIN R is

    WHEREIN R1 is amino, anilino or toluidino, R2 is hydroxy or amino, and R3 is hydrogen, nitro, -SO3M or alkyl, with the proviso that R3 must be hydrogen if R1 and/or R2 is other than amino,

    WHEREIN R4 is hydroxy, amino, anilino or toluidino,

    WHEREIN R5 is hydroxy, alkylsulfonyloxy, phenylsulfonyloxy, amino, alkylsulfonylamino or phenylsulfonylamino, R6 is alkyl, alkoxy, acetyl, carboxy or carbamoyl, and R7 is hydrogen, acyl, alkyl, substituted alkyl, phenyl, substituted phenyl, naphthyl or substituted naphthyl, or

    WHEREIN R8 is hydrogen or amino, and R9 is hydrogen or amino, with the proviso that one of R8 and R9 is hydrogen and the other is amino, and EACH M is independently hydrogen or a cation, are useful for dyeing aluminum oxide layers, e.g., those produced on aluminum and alloys thereof by anodization.

    摘要翻译： 式WHEREIN R的染料是R1是氨基，苯胺基或甲苯胺基，R2是羟基或氨基，R3是氢，硝基，-SO3M或烷基，条件是如果R1和/或R2是其它的，R3必须是氢 氨基，烷基磺酰基氨基或苯基磺酰基氨基，R 6是烷基，烷氧基，乙酰基，羧基或氨基甲酰基，且R 7是氢，酰基，烷基，芳基， 取代的烷基，苯基，取代的苯基，萘基或取代的萘基，或WHEREIN R8是氢或氨基，R9是氢或氨基，条件是R8和R9中的一个是氢，另一个是氨基，并且EACH M独立地 氢或阳离子可用于染色氧化铝层，例如通过阳极氧化在铝及其合金上生产的那些。

    Trisazo dyes having a 4-(1-amino-3,6-disulfo-8-hydroxy-7-phenylazonaphthyl-2-azo)phenylazo group linked to a coupling component radical
    9.
    发明授权
    Trisazo dyes having a 4-(1-amino-3,6-disulfo-8-hydroxy-7-phenylazonaphthyl-2-azo)phenylazo group linked to a coupling component radical 失效
    具有与偶联成分基团连接的4-（1-氨基-3,6-二磺基-8-羟基-7-苯基偶氮萘-2-偶氮）苯基偶氮基的三偶氮染料

    公开(公告)号：US4468348A

    公开(公告)日：1984-08-28

    申请号：US118595

    申请日：1980-02-04

    申请人： Heinz Wicki

    发明人： Heinz Wicki

    IPC分类号： C09B35/46 ,  D06P1/39 ,  D06P3/32 ,  D21H21/28 ,  C09B31/16 ,  C09B31/20 ,  C09B31/24 ,  C09B31/28

    CPC分类号： C09B35/461 ,  D06P1/39 ,  D06P3/3226 ,  D21H21/28

    摘要： Dyes of the formula ##STR1## and mixtures thereof, in which R signifies a radical of formula (a), (b), (c), (d), (e), (f), (g) or (h) ##STR2## in which R.sub.1 signifies an amino, anilino or toluidino radical, R.sub.2 signifies a hydroxy or amino radical, andeither R.sub.3 signifies hydrogen,or, where R.sub.1 and R.sub.2 signify amino, R.sub.3 signifies hydrogen, nitro, --SO.sub.3 M or C.sub.1-6 alkyl; ##STR3## in which R.sub.4 signifies a hydroxy, amino, anilino or toluidino radical, preferably a hydroxy or amino radical; ##STR4## in which R.sub.5 signifies a hydroxy radical, a C.sub.1-6 alkylsulphonyloxy radical, a phenylsulphonyloxy radical, an amino radical, a C.sub.1-6 alkylsulphonylamino radical or a phenysulphonylamino radical, preferably a hydroxy radical,R.sub.6 signifies a C.sub.1-6 alkyl, C.sub.1-6 alkoxy, acetyl, carboxyl or carbamoyl radical,R.sub.7 signifies hydrogen, an acyl radical or an unsubstituted or substituted C.sub.1-6 alkyl, phenyl or naphthyl radical,R' signifies hydrogen, methyl or methoxy, andM signifies hydrogen or an equivalent of a cation,useful for dyeing natural and regenerated cellulose, natural and synthetic polyamides, polyurethanes, basically modified polyolefins and anodized aluminum and particularly for dyeing paper and leather. The obtained dyeings have shades that range from blue and green to deep black and exhibit good fastness to light, wet treatments and sweat. The dyes build-up particularly well on nylon at neutral pH conditions and have good affinity for leather.

    摘要翻译： 其中R表示式（a），（b），（c），（d），（e），（f），（g）或（h））的基团， （a）其中R1表示氨基，苯胺基或甲苯酰基，R2表示羟基或氨基，R3表示氢，或其中R1和R2表示氨基，R3表示氢，硝基，-SO3M或 C 1-6烷基; （b）其中R4表示羟基，氨基，苯胺基或甲苯酰基，优选羟基或氨基; （c）（c）（f）图像（f）图像（h）其中R 5表示羟基，C 1-6烷基磺酰氧基 ，苯基磺酰氧基，氨基，C 1-6烷基磺酰基氨基或苯磺酰氨基，优选羟基，R6表示C1-6烷基，C1-6烷氧基，乙酰基，羧基或氨基甲酰基，R7表示氢， 酰基或未取代或取代的C 1-6烷基，苯基或萘基，R'表示氢，甲基或甲氧基，M表示用于染色天然和再生纤维素，天然和合成聚酰胺的氢或等同的阳离子， 聚氨酯，基本上改性的聚烯烃和阳极氧化铝，特别是用于染色纸和皮革。 所获得的染色具有从蓝色和绿色到深黑色的色调，并具有良好的耐光牢度，湿润处理和汗水。 染料在中性pH条件下特别适用于尼龙，对皮革具有良好的亲和性。

    Trisazo or tetrakisazo dyes containing a heterocyclic group
    10.
    发明授权
    Trisazo or tetrakisazo dyes containing a heterocyclic group 失效
    含有杂环基的三偶氮或四偶氮染料

    公开(公告)号：US4285860A

    公开(公告)日：1981-08-25

    申请号：US112635

    申请日：1980-01-16

    申请人： Guenter Hansen ,  Hans J. Kolbinger ,  Horst Scheuermann ,  Georg Zeidler

    发明人： Guenter Hansen ,  Hans J. Kolbinger ,  Horst Scheuermann ,  Georg Zeidler

    IPC分类号： C09B31/22 ,  C09B31/18 ,  C09B35/46 ,  C09B35/60 ,  D06P3/32 ,  C09B31/30 ,  C09B33/22 ,  C09B33/28

    CPC分类号： C09B35/60 ,  C09B35/461 ,  D06P3/3226

    摘要： Polyazo dyes which in the form of the free acids correspond to the general formula I ##STR1## where D is the radical of a diazo component, or a radical of the formula ##STR2## n is 0 or 1, R.sup.1 is hydrogen, chlorine, bromine, methyl, ethyl, methoxy, ethoxy, carboxyl, trifluoromethyl, methylsulfonyl, ethylsulfonyl or hydroxysulfonyl,R.sup.2 is hydrogen, chlorine, bromine, methyl, methoxy, carbamyl or sulfamyl,one X is hydroxyl and the other X is amino, Y is hydrogen or hydroxysulfonyl, but at least one Y is hydroxysulfonyl andZ is a radical of the formula ##STR3##

    摘要翻译： 游离酸形式的多偶氮染料对应于通式I，其中D是重氮组分的基团，或下式的基团n为0或1，R 1为氢，氯 ，溴，甲基，乙基，甲氧基，乙氧基，羧基，三氟甲基，甲基磺酰基，乙基磺酰基或羟基磺酰基，R2是氢，氯，溴，甲基，甲氧基，氨基甲酰基或氨磺酰基，一个X是羟基，另一个X是氨基，Y是 氢或羟基磺酰基，但是至少一个Y是羟基磺酰基，Z是下式的基团：