公开(公告)号：US20160216211A1

公开(公告)日：2016-07-28

申请号：US14917978

申请日：2014-09-10

申请人： GunJin Yun

发明人： GunJin Yun

IPC分类号： G01N21/70 ,  G01N21/88 ,  G01L1/24 ,  C09D5/22

CPC分类号： G01N21/70 ,  C09D5/22 ,  C09K11/02 ,  C09K11/574 ,  C09K11/7721 ,  C09K11/7734 ,  C09K11/7792 ,  F21K2/04 ,  G01L1/24 ,  G01N21/8803

摘要： A method of using a paint sensor to observe stress distributions of a stressed substrate includes the steps of applying a composition including a paintable medium and a mechanoluminescence material to a substrate, allowing the composition to form a solid film on the substrate, allowing the substrate to be stressed following the formation of the solid film, and measuring the stress the substrate has undergone by determining the mechanoluminescence of the solid film. A composition for visualizing stress or crack distributions includes a paintable medium and a mechanoluminescence material dispersed therein.

摘要翻译： 使用涂料传感器来观察应力基材的应力分布的方法包括以下步骤：将包含可涂漆介质和机械发光材料的组合物施加到基材上，使组合物在基材上形成固体膜， 在固体膜的形成之后受到应力，并且通过测定固体膜的机械发光来测量衬底已经发生的应力。 用于可视化应力或裂纹分布的组合物包括分散在其中的可涂漆介质和机械发光材料。

公开(公告)号：US20160053172A1

公开(公告)日：2016-02-25

申请号：US14780942

申请日：2014-03-26

申请人： SAKAI CHEMICAL INDUSTRY CO., LTD. ,  NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

发明人： Kenji MORI ,  Keita KOBAYASHI ,  Hiroshi NAKAO ,  Tomonori TOJO ,  Chao-Nan XU

IPC分类号： C09K11/77

CPC分类号： C09K11/7792 ,  C08K3/22 ,  C08K2003/2227 ,  C08L101/00 ,  F21K2/04

摘要： The present invention aims to provide a mechanoluminescent material which is excellent in mechanoluminescent properties and can achieve a mechanoluminescence intensity sufficiently suited to practical use, a raw material composition for producing the mechanoluminescent material, and a method for producing a mechanoluminescent material. The mechanoluminescent material of the present invention includes strontium aluminate as a base material, a Eu ion, and at least one ion selected from the group consisting of Nd, Dy, and Ho. An amount of the Eu ion contained in the mechanoluminescent material is 0.0001 to 0.1 mol per mole of the strontium aluminate. An amount of the at least one ion selected from the group consisting of Nd, Dy, and Ho contained in the mechanoluminescent material is, as the sum of amounts of the three ions Nd, Dy, and Ho, 0.0001 to 0.01 mol per mole of the strontium aluminate. The present invention also provides a raw material composition for a mechanoluminescent material used for synthesizing the mechanoluminescent material, a mechanoluminescent coating composition and a resin composition each containing the mechanoluminescent material, and applied articles such as mechanoluminescent articles formed from the resin composition.

摘要翻译： 本发明的目的在于提供一种机械发光性能优异，能够实现充分适用于实际应用的机械发光强度的机械发光材料，用于制造机械发光材料的原料组合物，以及制造机械发光材料的方法。 本发明的机械发光材料包括铝酸锶作为基材，Eu离子和至少一种选自Nd，Dy和Ho的离子。 机械发光材料中所含的Eu离子的量相对于每摩尔铝酸锶为0.0001〜0.1摩尔。 作为在机械发光材料中含有的选自Nd，Dy和Ho中的至少一种离子的量，作为三价离子Nd，Dy和Ho的量，相对于每摩尔的摩尔量为0.0001〜0.01摩尔 铝酸锶。 本发明还提供了用于合成机械发光材料的机械致发光材料的原料组合物，机械发光涂料组合物和各自含有机械发光材料的树脂组合物，以及由树脂组合物形成的机械发光制品等应用制品。

公开(公告)号：US20090061202A1

公开(公告)日：2009-03-05

申请号：US11887902

申请日：2006-04-07

申请人： Chao-Nan Xu ,  Hiroshi Yamada

发明人： Chao-Nan Xu ,  Hiroshi Yamada

IPC分类号： B32B3/26

CPC分类号： F21K2/04 ,  C09K11/666 ,  C09K11/667 ,  C09K11/7721 ,  C09K11/7724 ,  C09K11/7738 ,  C09K11/7774 ,  C09K11/7792 ,  Y10T428/249953

摘要： One embodiment of the present invention provides (i) a luminant having a unique crystal structure so as to exhibit high luminosity and (ii) a manufacturing method thereof. Further, the present invention discloses (I) a luminant which exhibits ultraviolet luminescence and (II) a manufacturing method thereof. The inventors developed a stress-stimulated luminescent material which exhibits high luminosity by using a compound having a structure obtained by inserting alkali metal ions and alkali earth metal ions into a base material structure constituted of polyhedral-structure molecules and partially substituting the alkali metal ions and alkali earth metal ions by rare earth metal ions, transition metal ions, group-III metal ions, or group-IV metal ions. Further, the inventors developed a stress-stimulated luminescent material which exhibits high-luminosity stress-stimulated ultraviolet luminescence by adding specific metal ions such as Ce as a luminescent center to the aforementioned stress-stimulated luminescent material.

摘要翻译： 本发明的一个实施方案提供（i）具有独特晶体结构以发挥高亮度的发光体，和（ii）其制造方法。 此外，本发明公开了（I）显示紫外线发光的发光体和（II）其制造方法。 本发明人开发了通过使用具有通过将碱金属离子和碱土金属离子插入到由多面体结构分子构成的基体结构中并且部分取代碱金属离子获得的结构的化合物而显示高亮度的应力激发的发光材料，以及 碱土金属离子，稀土金属离子，过渡金属离子，III族金属离子或Ⅳ族金属离子。 此外，本发明人开发了通过将诸如Ce作为发光中心的特定金属离子添加到上述应力刺激发光材料中而显示出高亮度应力刺激的紫外线发光的应力刺激发光材料。

公开(公告)号：US20090050847A1

公开(公告)日：2009-02-26

申请号：US11887837

申请日：2006-04-06

申请人： Chao-Nan Xu ,  Hiroshi Yamada

发明人： Chao-Nan Xu ,  Hiroshi Yamada

IPC分类号： C09K11/08

CPC分类号： F21K2/04 ,  C09K11/7706 ,  C09K11/7734 ,  C09K11/7774 ,  C09K11/7792

摘要： One embodiment of the present invention is to provide a stress-stimulated luminescent material which has a unique crystal structure and which emits conventionally unachievable intense light. The stress-stimulated luminescent material of one embodiment of the present invention includes a basic structure in which a plurality of tetrahedral molecules each having an AlO4-like tetrahedral structure or an SiO4-like tetrahedral structure share atoms of apexes of the tetrahedral structures so as to be coupled to one another so that a basic material structure is formed and at least either alkali metal ions or alkali earth metal ions are inserted into the void are partially substituted by at least either rare earth metal ions or transition metal ions.

摘要翻译： 本发明的一个实施方案是提供具有独特晶体结构并且发射常规不可实现的强光的应力激发的发光材料。 本发明的一个实施方案的应力刺激发光材料包括其中各自具有AlO 4样四面体结构或SiO 4样四面体结构的多个四面体分子共享四面体结构的顶点的原子的基本结构，从而 彼此耦合，从而形成基本材料结构，并且至少将碱金属离子或碱土金属离子插入到空隙中，部分被至少一种稀土金属离子或过渡金属离子所取代。

公开(公告)号：US20090010306A1

公开(公告)日：2009-01-08

申请号：US11773547

申请日：2007-07-05

申请人： Yasuhiro Egami ,  Uwe Frey ,  Christian Klein ,  Jurgen Quest ,  Uwe Beifuss ,  Vladimir Ondrus

发明人： Yasuhiro Egami ,  Uwe Frey ,  Christian Klein ,  Jurgen Quest ,  Uwe Beifuss ,  Vladimir Ondrus

IPC分类号： G01K11/00

CPC分类号： C09K11/06 ,  C09D5/22 ,  C09D175/04 ,  C09K9/02 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/185 ,  F21K2/04

摘要： A temperature sensitive paint comprises a binder for forming a polymer matrix, a transition metal complex embedded in the binder and displaying a temperature dependent fluorescence, the fluorescence of the transition metal complex showing a maximum relative temperature sensitivity per Kelvin at a first temperature, and a rare earth complex also embedded in the binder and displaying a temperature dependent fluorescence, the fluorescence of the rare earth complex showing a maximum relative temperature sensitivity per Kelvin at a second temperature. The second temperature is higher than the first temperature by 50 to 150 Kelvin so that the overall temperature range covered by both complexes as temperature probes is extended.

摘要翻译： 温度敏感性涂料包括用于形成聚合物基质的粘合剂，嵌入粘合剂中的过渡金属络合物并显示温度依赖性荧光，过渡金属络合物的荧光在第一温度下显示出每开氏度的最大相对温度敏感度，以及 稀土配合物也嵌入粘合剂中并显示温度依赖性荧光，稀土配合物的荧光在第二温度下显示出每开氏度的最大相对温度敏感度。 第二温度高于第一温度50至150开尔文，使得作为温度探针的两个络合物覆盖的总体温度范围延长。

公开(公告)号：US3159029A

公开(公告)日：1964-12-01

申请号：US3117460

申请日：1960-05-23

申请人： ISOMET CORP

发明人： WARREN RUDERMAN IRVING

IPC分类号： B64G1/56 ,  F21K2/04 ,  G01T1/202

CPC分类号： B64G1/56 ,  F21K2/04 ,  G01T1/202

公开(公告)号：US20190184242A1

公开(公告)日：2019-06-20

申请号：US16286713

申请日：2019-02-27

申请人： NIKE, Inc.

发明人： Arthur P. Molinari

IPC分类号： A63B41/08 ,  A63B41/02 ,  A63B43/06

CPC分类号： A63B41/08 ,  A63B41/02 ,  A63B43/06 ,  A63B2207/02 ,  A63B2209/00 ,  F21K2/04

摘要： An inflatable sports ball is provided. The sports ball includes an interior bladder and a cover disposed about the interior bladder. The cover may include an outer substrate and an intermediate structure. The cover may further include an outer substrate surface, defined by the outer substrate, and a feature surface radially spaced apart from the outer substrate surface. Together the outer substrate surface and the feature surface cooperate to define an exterior surface of the cover. A mechanoluminescent material may be embedded in a portion of the cover. The mechanoluminescent material may be disposed at only one of the outer substrate surface and the feature surface, such that it is positioned to form a predetermined design on the cover. The mechanoluminescent material emits visible light in response to an externally-applied stress, such that the predetermined design illuminates when an external stress or mechanical stimulus is exerted upon the cover.

公开(公告)号：US09964493B2

公开(公告)日：2018-05-08

申请号：US14917978

申请日：2014-09-10

申请人： GunJin Yun

发明人： GunJin Yun

IPC分类号： G01B11/16 ,  G01N21/70 ,  C09K11/02 ,  C09D5/22 ,  C09K11/77 ,  F21K2/04 ,  C09K11/57 ,  G01L1/24 ,  G01N21/88

CPC分类号： G01N21/70 ,  C09D5/22 ,  C09K11/02 ,  C09K11/574 ,  C09K11/7721 ,  C09K11/7734 ,  C09K11/7792 ,  F21K2/04 ,  G01L1/24 ,  G01N21/8803

摘要： A method of using a paint sensor to observe stress distributions of a stressed substrate includes the steps of applying a composition including a paintable medium and a mechanoluminescence material to a substrate, allowing the composition to form a solid film on the substrate, allowing the substrate to be stressed following the formation of the solid film, and measuring the stress the substrate has undergone by determining the mechanoluminescence of the solid film. A composition for visualizing stress or crack distributions includes a paintable medium and a mechanoluminescence material dispersed therein.

公开(公告)号：US20160222290A1

公开(公告)日：2016-08-04

申请号：US14917659

申请日：2014-06-24

申请人： NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

发明人： Nao TERASAKI ,  Chao-Nan XU

IPC分类号： C09K11/77

CPC分类号： C09K11/7792 ,  F21K2/04 ,  G01L1/248 ,  G01N21/70

摘要： Provided is a mechanoluminescent material which can radiate near-infrared light. The mechanoluminescent material includes an aluminate co-doped with Eu2+, Cr3+, and an ion or ion cluster of at least any one rare earth metal element selected from Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu. In addition, in the mechanoluminescent material, the aluminate is an aluminate represented by Formula MAl2O4 (provided that, M is any of Mg, Ca, Sr, or Ba) and Eu2+, Cr3+, and the ion or ion cluster of a rare earth metal element are co-doped at a concentration at which M in the aluminate is substituted by from 0.25 to 10%.

摘要翻译： 提供可以辐射近红外光的机械发光材料。 机械发光材料包括与Eu2 +，Cr3 +共掺的铝酸盐，以及选自Sc，Y，La，Ce，Pr，Nd，Pm，Sm，Eu，Gd中的至少一种稀土金属元素的离子或离子簇 ，Tb，Dy，Ho，Er，Tm，Yb或Lu。 此外，在机械发光材料中，铝酸盐是由式MAl 2 O 4表示的铝酸盐（条件是M是Mg，Ca，Sr或Ba中的任一种）和Eu 2+，Cr 3+，以及稀土金属的离子或离子簇 元素以铝酸盐中的M被0.25至10％代替的浓度共掺杂。

公开(公告)号：US20150267107A1

公开(公告)日：2015-09-24

申请号：US14664092

申请日：2015-03-20

申请人： Jiahua Zhu ,  Gunjin Yun

发明人： Jiahua Zhu ,  Gunjin Yun

IPC分类号： C09K11/02 ,  G01L1/24 ,  G01N21/88 ,  H01F1/01

CPC分类号： G01L1/24 ,  F21K2/04 ,  G01L1/247 ,  H01F1/0054

摘要： A sensor for visualizing stress includes a medium and a plurality of mechanoluminescence assemblies dispersed therein. A mechanoluminescence assembly can include a mechanoluminescence material and a coating material, where the mechanoluminescence material is at least partially coated with the coating material. A method of using the sensor can include applying the medium to a substrate and allowing the medium to form a solid film on the substrate. Methods of using the mechanoluminescence assemblies are also provided.

摘要翻译： 用于可视化应力的传感器包括分散在其中的介质和多个机械发光组件。 机械发光组件可以包括机械发光材料和涂层材料，其中机械发光材料至少部分地涂覆有涂层材料。 使用传感器的方法可以包括将介质施加到基底并允许介质在基底上形成固体膜。 还提供了使用机械发光组件的方法。