Process to remove hydrogen-sulfide from gas by reflux recycle from sour water stripper
    1.
    发明授权
    Process to remove hydrogen-sulfide from gas by reflux recycle from sour water stripper 有权
    通过从酸性水汽提塔回流循环从气体中除去硫化氢的方法

    公开(公告)号:US07837965B2

    公开(公告)日:2010-11-23

    申请号:US12316152

    申请日:2008-12-10

    Inventor: Mark C. Anderson

    Abstract: A process for reducing hydrogen sulfide from a gas comprising contacting the gas with an aqueous scrubbing liquid recycled from a sour water stripper. The aqueous scrubbing liquid comprises ammonia. The contacting of the gas with the aqueous scrubbing liquid thereby produces a semi-sweet gas with reduced concentration of hydrogen sulfide and a rich liquid solution.

    Abstract translation: 一种从气体中还原硫化氢的方法,包括使气体与从酸性水汽提器再循环的水性洗涤液接触。 含水洗涤液包含氨。 气体与含水洗涤液的接触由此产生具有降低的硫化氢浓度和富液体溶液的半甜味气体。

    Treatment of a water stream containing ammonium sulfide salts

    公开(公告)号:US3634037A

    公开(公告)日:1972-01-11

    申请号:US3634037D

    申请日:1968-12-23

    CPC classification number: C02F1/725 C01B17/06 C01C1/20

    Abstract: A water stream containing NH4HS is treated to produce elemental sulfur, an ammoniacal aqueous stream and a treated water stream by the steps of: (a) catalytically treating the water stream with an airstream to produce an effluent stream containing ammonium polysulfide, N2 and unreacted NH4HS; (b) separating the effluent stream from step (a) into a vent gas stream and a water stream; (c) decomposing the polysulfide contained in the water stream from step (b) to produce a vapor stream and a bottom stream containing elemental sulfur; (d) separating sulfur from the bottom stream from step (c) to form a treated water stream; (e) recovering a first portion of the treated water stream from step (d) as a product stream; (f) using a second portion of the treated water stream from step (d) to scrub the vent gas stream from step (b) in order to remove NH3 and H2S therefrom; (g) fractionating the overhead vapor stream from step (c) and the bottom stream from the scrubbing step to form an ammoniacal aqueous overhead stream and an aqueous bottom stream containing essentially all of the unreacted sulfide present in the effluent stream from the treating step; and, (h) recycling the bottom stream from step (g) to step (a). Key feature is the use of a scrubbing step on the vent gases from the treating step operated at a relatively low pressure and a relatively high-liquid gas loading, coupled with a combination scrubbing and fractionating step on the bottom stream from the scrubbing step and on the vapor stream from the polysulfide decomposition step. This combination scrubbing and fractionating step is operated at a relatively high pressure, thereby increasing the amount of H2S that can be absorbed. The principle advantages of the resulting process are significant improvements in the amount of ammonia and sulfur recovered and a substantial simplification of the overall process.

    Method for reducing oxysulfur compounds
    5.
    发明授权
    Method for reducing oxysulfur compounds 失效
    减少氧化物化合物的方法

    公开(公告)号:US3737517A

    公开(公告)日:1973-06-05

    申请号:US3737517D

    申请日:1971-02-08

    Inventor: URBAN P

    CPC classification number: B01J27/049 C01B17/28

    Abstract: Inorganic, water-soluble oxysulfur compounds are reduced by contacting an aqueous solution of the oxysulfur compound and hydrogen with a bimetallic catalyst at reduction conditions. The bimetallic catalyst comprises catalytically effective amounts of a metallic sulfide selected from sulfides of the transition metals from group VI and of a metallic sulfide selected from the sulfides of the transition metals of group VIII combined with a porous carrier material. A specific example of the disclosed invention is a method for reducing an inorganic, water-soluble thiosulfate compound to a sulfide compound by contacting an aqueous solution of the thiosulfate compound and hydrogen, at reduction conditions, with a catalyst comprising a combination of catalytically effective amounts of molybdenum sulfide and of cobalt sulfide with a porous carrier material.

    Abstract translation: 通过在还原条件下使氧硫化合物和氢的水溶液与双金属催化剂接触来降低无机,水溶性氧硫化合物。 双金属催化剂包含催化有效量的金属硫化物,其选自来自第VI族的过渡金属的硫化物和选自第VIII族的过渡金属的硫化物与多孔载体材料结合的金属硫化物。 所公开的发明的具体实例是通过使硫代硫酸盐化合物的水溶液和氢在还原条件下与包含催化有效量的组合的催化剂接触而将无机水溶性硫代硫酸盐化合物还原为硫化物化合物的方法 的硫化钼和硫化钴与多孔载体材料。

    Method and system for regenerating catalyst from a plurality of hydrocarbon conversion apparatuses
    10.
    发明授权
    Method and system for regenerating catalyst from a plurality of hydrocarbon conversion apparatuses 有权
    从多个烃转化装置再生催化剂的方法和系统

    公开(公告)号:US08299314B2

    公开(公告)日:2012-10-30

    申请号:US11787857

    申请日:2007-04-18

    Abstract: The present invention is directed to a method and system for integrating a catalyst regeneration system with a plurality of hydrocarbon conversion apparatuses, preferably, a plurality of multiple riser reactor units. One embodiment of the present invention is a reactor system including a plurality of reactor units, at least one reactor unit preferably comprising a plurality of riser reactors. The system also includes a regenerator for converting an at least partially deactivated catalyst to a regenerated catalyst. A first conduit system transfers the at least partially deactivated catalyst from the reactor units to the regenerator, and a second conduit system transfers regenerating catalysts from the regenerator to the plurality of reactor units. Optionally, catalysts from a plurality of hydrocarbon conversion apparatuses may be directed to a single stripping unit and/or a single regeneration unit.

    Abstract translation: 本发明涉及用于将催化剂再生系统与多个烃转化装置(优选多个提升管反应器单元)整合的方法和系统。 本发明的一个实施方案是包括多个反应器单元的反应器系统,至少一个反应器单元优选包括多个提升管反应器。 该系统还包括用于将至少部分失活的催化剂转化为再生催化剂的再生器。 第一管道系统将至少部分失活的催化剂从反应器单元转移到再生器,并且第二管道系统将再生催化剂从再生器传递到多个反应器单元。 任选地,来自多个烃转化装置的催化剂可以被引导到单个汽提单元和/或单个再生单元。

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