摘要:
Hydrogen cyanide is produced by reacting ammonia and a hydrocarbon gas in the presence of a platinum-group-metal catalyst while the catalyst is heated by induction heating at a frequency of 0.5 to 30 MHz.
摘要:
A catalytic process and apparatus therefor for the manufacture of hydrogen cyanide. In the process an oxygen rich oxidant stream and at least one oxidant-free feed stream containing methane and ammonia are separately preheated and rapidly mixed to form a detonable mixed stream at a temperature which is at least 50° C. below the autoignition temperature of the mixed stream. The mixed stream is then conveyed to a catalyst capable of catalyzing the formation of hydrogen cyanide at such a velocity that detonation is avoided. The process is more energy efficient and gives rise to an effluent stream containing more hydrogen than the conventional Andrussow process.
摘要:
A process increasing the yield of both HCN and acetonitrile produced during the manufacture of acrylonitrile comprising introducing a hydrocarbon selected from the group consisting of propylene and propane, a crude ketone and/or a mixture of at least two ketones, ammonia and air, into a reaction zone containing an ammoxidation catalyst, reacting the hydrocarbon, the ketone, ammonia and oxygen over said catalyst at an elevated temperature to produce acrylonitrile, hydrogen cyanide and acetonitrile, and recovering the acrylonitrile, hydrogen cyanide and acetonitrile from the reactor.
摘要:
A process increasing the yield of both HCN and acetonitrile produced during the manufacture of acrylonitrile comprising introducing a hydrocarbon selected from the group consisting of propylene and propane, a crude ketone and/or a mixture of at least two ketones, ammonia and air, into a reaction zone containing an ammoxidation catalyst, reacting the. hydrocarbon, the ketone, ammonia and oxygen over said catalyst at an elevated temperature to produce acrylonitrile, hydrogen cyanide and acetonitrile, and recovering the acrylonitrile, hydrogen cyanide and acetonitrile from the reactor.
摘要:
This invention relates to improvements in processes and catalysts for elevated temperature, gas phase, catalyzed reactions in general; it is particularly illustrated by reference to the manufacture of hydrogen cyanide.
摘要:
Carbon-nitrogen nanofibers are prepared by contacting a gaseous mixture comprising hydrogen and a carbon-nitrogen compound such as pyridine with a cobalt-iron catalyst at a temperature in the range of about 500-1000° C. The nanofibers are characterized by a structure in which layers emanate from a core catalyst particle and are parallel to each other but not parallel to the length axis of the nanofibers.
摘要:
A process for the synthesis of hydrogen cyanide by the Andrussow process by reaction of methane or methane-containing natural gas, ammonia and oxygen or oxygen-enriched air on a catalyst at an elevated temperature, wherein O 2 O 2 + N 2 = 0.25 - 1.0 ( vol / vol ) .
摘要:
A reactor for performing endothermic catalytic reactions is disclosed formed of a monolithic counterflow reactor with parallel heating and reaction channels. The internal walls of the reaction channels are coated with a catalyst for the catalytic reaction to be performed, while the internal walls of the heating channels have a catalyst for the catalytic combustion of a fuel gas/air mixture.
摘要:
A process for the production of hydrogen cyanide is provided, wherein hydrogen cyanide is synthesized by reacting methane or methane-containing natural gas, ammonia and oxygen-enriched air or oxygen in the presence of a catalyst comprising platinum or a platinum alloy; wherein the reactants are present in the following molar ratios [ O 2 ] [ O 2 + N 2 ] = 0.25 to 1.0 ; [ CH 4 ] [ NH 3 ] = 0.95 to 1.05 ; and where a molar ratio of ammonia to the sum of oxygen and nitrogen obeys the following relationship: Y=m·X−a, wherein Y = [ NH 3 ] [ O 2 + N 2 ] X = [ O 2 ] [ O 2 + N 2 ] m=1.25 to 1.40; and a 0.05 to 0.14.
摘要:
A catalytic process and apparatus therefor for the manufacture of hydrogen cyanide. In the process an oxygen rich oxidant stream and at least one oxidant-free feed steam containing methane and ammonia are separately preheated and rapidly mixed to form a detonable mixed stream at a temperature which is at least 50° C. below the autoignition temperature of the mixed stream. The mixed stream is then conveyed to a catalyst capable of catalysing the formation of hydrogen cyanide at such a velocity that detonation is avoided. The process is more energy efficient and gives rise to an effluent stream containing more hydrogen than the conventional Andrussow process.