公开(公告)号：US10351436B2

公开(公告)日：2019-07-16

申请号：US15598011

申请日：2017-05-17

申请人： LANXESS SOLUTIONS US, INC.

发明人： Thomas G. Ray ,  David W. Bartley ,  Hugh Broadhurst ,  Nate Goodwin

IPC分类号： B01J19/24 ,  C01F11/34 ,  B01J19/00 ,  C01B9/04 ,  C01D3/10 ,  C01D15/04 ,  C01F5/36

摘要： Bromine containing compounds, such as calcium bromide, sodium bromide and the like, are prepared in high purity and more quickly with less waste by using a process with two bromination stages and often a third step wherein the crude product mixture can be adjusted to meet specific product requirements. In the first bromination stage, the majority, but not all, of a substrate is brominated using a reductive bromination reaction, the remaining unreacted substrate is converted to product in the second stage through another a reductive bromination reaction, although the specific reagents may be different, wherein the addition of bromine and a reducing agent are carefully monitored.

公开(公告)号：US20140341798A1

公开(公告)日：2014-11-20

申请号：US14218879

申请日：2014-03-18

申请人： Dru L. DeLaet

发明人： Dru L. DeLaet

IPC分类号： C01D3/10 ,  C01D3/04 ,  C07C263/00 ,  C01D3/02

CPC分类号： C01D3/10 ,  C01D3/02 ,  C01D3/04 ,  C07C209/12 ,  C07C263/00 ,  C07C291/10 ,  C07C211/63

摘要： A method of reacting amine compounds with halons and perhalogenated compounds, resulting in the conversion of these ozone-depleting species into non-volatile salts and a variety of other amine derivatives is disclosed.

摘要翻译： 公开了使胺化合物与哈龙和全卤代化合物反应的方法，导致将这些消耗臭氧的物质转化为非挥发性盐和多种其它胺衍生物。

公开(公告)号：US4248850A

公开(公告)日：1981-02-03

申请号：US15067

申请日：1979-02-26

申请人： Kestutis A. Keblys

发明人： Kestutis A. Keblys

IPC分类号： C01D3/10 ,  C01F11/34 ,  C01G1/06 ,  C01G9/04

CPC分类号： C01G9/04 ,  C01D3/10 ,  C01F11/34 ,  C01G1/06

摘要： Metal bromides, and particularly alkali and alkaline earth metal bromides, are prepared from a basic metal compound and bromine in the presence of added formaldehyde as a reducing agent.

摘要翻译： 金属溴化物，特别是碱金属和碱土金属溴化物，在加入甲醛作为还原剂的存在下，由碱金属化合物和溴制备。

公开(公告)号：US4055457A

公开(公告)日：1977-10-25

申请号：US716051

申请日：1976-08-20

申请人： Carl F. Swinehart

发明人： Carl F. Swinehart

IPC分类号： C30B11/00 ,  C30B17/00 ,  B01J17/06 ,  B01J17/08 ,  C01D3/04 ,  C01D3/10

CPC分类号： C30B17/00 ,  C30B11/00 ,  C30B29/12

摘要： Large ultra-pure, prism-quality essentially single crystal boules and ingots of alkali metal chlorides and alkali metal bromides are grown by the methods of Kyropoulos and Stockbarger. Optically single crystals of these alkali metal halides are clear optical bodies free of haze throughout. A typical Kyropoulos grown boule of KBr of this invention is also absorption-free, and has cleavage or crystallographic planes which deviate from parallel by 1.degree. to 3.degree. per inch. By `absorption-free` is meant freedom of absorption at 7.2 microns (.mu.) due to nitrate, at 9.5-11 .mu. due to silicate, and at between 8 and 9 .mu. due to sulfate, which are the most difficult to control but as the term implies the bodies are also free of infrared absorption for impurities such as CO.sub.3.sup.-2, PO.sub.4.sup.-3, OH.sup.-, BO.sub.2.sup.-, SH.sup.-, CNO.sup.-, HCO.sub.3.sup.-, etc., which are easily avoided by use of good commercially available growth stock.A particular process for growth for either of the foregoing methods in a silica or quartz crucible, comprises growing an ultrapure ingot of KBr from a relatively impure melt containing silicate, sulfate, nitrate and nitrite ions, and includes maintaining the sodium content of the melt during growth to less than about 20 ppm (parts per million) and the barium content less than 10 ppm, adding barium bromide to the melt if necessary, and, contacting the melt with a trace of free bromine in a covered, but not air-tight, pot.

摘要翻译： 通过Kyropoulos和Stockbarger的方法生长大型超纯，棱柱质量的碱性金属氯化物和碱金属溴化物。 这些碱金属卤化物的光学单晶是透明的光学体。 本发明的KBr的典型的Kyropoulos生长的棒也是无吸收的，并且具有相对于每平方英寸1°至3°的切割或结晶平面。 “无吸收”是指由于硝酸盐在7.2微米（μm）下的吸收自由度，由于硅酸盐而在9.5-11微米处，并且由于硫酸盐而在8至9微米之间，这是最难控制的，但是作为 该术语意味着物体对于诸如CO 3 -2，PO 4 -3，OH-，BO 2 - ，SH-，CNO-，HCO 3 - 等杂质也没有红外吸收，这些容易通过使用商业上很好地避免 可用成长股。

公开(公告)号：US3433583A

公开(公告)日：1969-03-18

申请号：US3433583D

申请日：1967-06-28

申请人： TEXACO INC

发明人： HESS HOWARD V ,  MCCOY FREDERIC C

IPC分类号： C01B21/50 ,  C01D3/06 ,  C01D3/10 ,  C01D3/12 ,  C01D15/00 ,  C01D3/04

CPC分类号： C01B21/50 ,  C01D3/06 ,  C01D3/10 ,  C01D3/12 ,  C01D15/00

公开(公告)号：US2007758A

公开(公告)日：1935-07-09

申请号：US65752333

申请日：1933-02-20

申请人： DOW CHEMICAL CO

发明人： HARLOW IVAN F ,  SHORT CHARLES E

IPC分类号： C01B7/09 ,  C01D3/10 ,  C01F11/34

CPC分类号： C01F11/34 ,  C01B7/09 ,  C01D3/10

公开(公告)号：US20240010507A1

公开(公告)日：2024-01-11

申请号：US17626805

申请日：2021-09-18

申请人： Beijing University of Technology

发明人： Dean Pan ,  Guanjun Li

IPC分类号： C01D3/10 ,  B01D11/04 ,  B01D9/00

CPC分类号： C01D3/10 ,  B01D11/0492 ,  B01D9/0018 ,  B01D11/0488

摘要： The invention belongs to the field of bromine recovery from waste circuit board, and particularly relates to a method for recovering high-purity sodium bromide from bromine-containing crude salt. The invention mainly includes the steps of acidification oxidation, multi-stage extraction, and cooperative back extraction. Compared with traditional chlorine oxidation and single urea back extraction technology, the acidification oxidation process can be effectively controlled by reasonable adjustment of the added amount of hydrochloric acid and sodium chlorate, and the tail gas can be absorbed and reused to avoid secondary pollution and resource waste. At the same time, urea is used with sodium carbonate for cooperative back extraction to achieve a high back extraction rate which greatly reduces the amount of urea, and obtains high-purity sodium bromide crystals. The efficient recovery of bromine resources in bromine-containing crude salt is realised. The benefits of the invention are: high product purity, simple operation, environmental friendliness.

公开(公告)号：US20230143246A1

公开(公告)日：2023-05-11

申请号：US18082799

申请日：2022-12-16

申请人： Takeda Pharmaceutical Company Limited

发明人： Megumi Ikeda ,  Shohei Horiuchi ,  Tomomi Sato ,  Shinichiro Nakai ,  Kenichiro Kiyoshima

IPC分类号： A61K47/02 ,  A61K47/12 ,  A61K9/00 ,  A61K31/4439 ,  C01D3/04 ,  C01D3/10 ,  C01F11/24

CPC分类号： A61K47/02 ,  A61K9/0019 ,  A61K31/4439 ,  A61K47/12 ,  C01D3/04 ,  C01D3/10 ,  C01F11/24

摘要： Provided are a liquid preparation wherein the pharmaceutically active ingredient is stabilized, and a stabilizing method therefor. A liquid preparation comprising a pharmaceutically active ingredient having a primary or secondary amino group (wherein the amino group does not constitute a part of the amide structure), an organic acid and a salt, which is substantially free of a reaction product of the pharmaceutically active ingredient and the organic acid.

公开(公告)号：US09399576B2

公开(公告)日：2016-07-26

申请号：US14154810

申请日：2014-01-14

申请人： King Fahd University of Petroleum and Minerals

发明人： Muhammad Ashraf Gondal ,  Kai Shen ,  Xiafeng Chang ,  Zain Hasan Abdallah Yamani

IPC分类号： C01B11/20 ,  A62D3/17 ,  C01D3/10

CPC分类号： C01B11/20 ,  A62D3/17 ,  A62D2101/45 ,  A62D2101/47 ,  C01D3/10

摘要： A method for degrading Rhodamine B including: mixing BiOBr and Rhodamine B; and irradiating the mixture with a radiation having a wavelength of from 440 nm to 554 nm. The Rhodamine B may be in an aqueous solution. The BiOBr may be added to the aqueous solution of Rhodamine B in an amount of from 0.2 to 0.5 mg/ml. The BiOBr may have a sheet-like structure with particles having a diameter of from 3 μm to 5 μm. The BiOBr may be in a pure crystal tetragonal phase.

摘要翻译： 一种降解罗丹明B的方法，包括：混合BiOBr和罗丹明B; 并用波长为440nm至554nm的辐射照射该混合物。 罗丹明B可以是水溶液。 BiOBr可以以0.2至0.5mg / ml的量加入到罗丹明B的水溶液中。 BiOBr可以具有直径为3μm至5μm的颗粒的片状结构。 BiOBr可以是纯晶体四方相。

公开(公告)号：US5230879A

公开(公告)日：1993-07-27

申请号：US827334

申请日：1992-01-29

申请人： Phillip R. Beaver ,  Bonnie G. McKinnie

发明人： Phillip R. Beaver ,  Bonnie G. McKinnie

IPC分类号： C01B9/04 ,  C01D3/10 ,  C01F5/26

CPC分类号： C01D3/10 ,  C01B9/04 ,  C01F5/26

摘要： This invention relates to a process for reducing metal halates to metal halides, the process comprising reacting a metal halate with a reducing agent in an aqueous alkaline reaction medium having a pH above about 7, wherein the amount of reducing agent is sufficient to reduce substantially all of the metal halate to metal halide.

摘要翻译： 本发明涉及将金属卤化物还原成金属卤化物的方法，该方法包括使金属卤化物与还原剂在pH高于约7的碱性水溶液中反应，其中还原剂的量足以基本上减少 的金属卤化物与金属卤化物反应。