Abstract:
A process/apparatus is disclosed for continuously separating a liquid medium comprising diluent and unreacted monomers from a polymerization effluent comprising diluent, unreacted monomers and polymer solids, comprising a continuous discharge of the polymerization effluent from a slurry reactor through a discharge valve and transfer conduit into a first intermediate pressure flash tank with a conical bottom defined by substantially straight sides inclined at an angle to that of horizontal equal to or greater than the angle of slide of the slurry/polymer solids and an exit seal chamber of such diameter (d) and length (l) as to maintain a desired volume of concentrated polymer solids/slurry in the exit seal chamber such as to form a pressure seal while continuously discharging a plug flow of concentrated polymer solids/slurry bottom product of the first flash tank from the exit seal chamber through a seal chamber exit reducer with inclined sides defined by substantially straight sides inclined at an angle to that of horizontal equal to or greater than the angle of slide of the polymer solids which remain after removal of about 50 to 100% of the inert diluent therefrom to a second flash tank at a lower pressure.
Abstract:
A process for obtaining polyglycolyl urea from aromatic diglycinate, to insulate electric conductors without forming HCN polluting residues, characterized because a mixture of methylene bromopropionate and methylenedianiline in aliphatic solvent reacts in presence of a catalizer; the solvent is separated through distillation, filtration of the mother waters and purification through washing with water and addition to the resulting product of cresylic acid and methylene dilisocyanate under stirring, up to a temperature, of 60null C., and addition of a triethylenediamino catalizer, heating at a temperature of up to 185null C. and it is then distilled at a temperature of up to 200null C., obtaining a polyglycolyl urea hydantoin resin.
Abstract:
A method of removing substantially all solvent from a solution containing a polyphenylene ether polymer resin with little by-product formation (less than 250 ppm) is provided. The method employs a wiped thin film evaporator with a cylindrical heating chamber operating under conditions that satisfy the relationships defined by Equations I and II. 5.3*1024RLnull exp(null24123/T)/m
Abstract translation:提供了从含有少量副产物形成的聚苯醚聚合物树脂(小于250ppm)的溶液中除去基本上所有溶剂的方法。 该方法采用具有圆柱形加热室的擦拭薄膜蒸发器,其工作条件满足方程式I和II定义的关系。 5.3 * 1024RLdelta exp(-24123 / T)/ m
Abstract:
Provided is a method of producing a polymeric fluorescent substance wherein one or more monomers represented by the general formula (1) are polymerized in the presence of a zerovalent nickel complex, X1nullAr1nullX2nullnull(1) wherein, Ar1 represents a divalent group selected from the group consisting of arylene groups, divalent heterocyclic compound groups, and divalent or trivalent hetero atom-bonded arylene or divalent heterocyclic compound groups, and X1 and X2 represent leaving groups. By using the polymeric fluorescent substance, a high performance polymer LED can easily be obtained.
Abstract:
A method for continuously stripping an unreacted monomer from a vinyl chloride paste resin latex, comprising the steps of continuously supplying the latex to a vacuum recovery vessel, wherein the latex is boiling with generation of foam, under the condition that the temperature of the latex to be supplied is higher than that of the latex in the recovery vessel, withdrawing a monomer gas generated in the recovery vessel through an exhaust line provided with a foam separator, contacting the foam entrained into the exhaust line with steam introduced to the exhaust line and/or the foam separator, thereby destroying the foam, and returning the resulting latex in the separator to the recovery vessel. The unreacted monomer can be efficiently recovered from the latex by a continuous operation, and defoaming can be achieved without deteriorating the quality and without lowering the productivity.