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    Process for synthesizing hydrocarbons from synthesis gas with control of the temperature of the external loop
    1.
    发明授权
    Process for synthesizing hydrocarbons from synthesis gas with control of the temperature of the external loop 有权
    通过控制外部环路的温度从合成气中合成烃的方法

    公开(公告)号：US09290699B2

    公开(公告)日：2016-03-22

    申请号：US14408621

    申请日：2013-04-10

    申请人： IFP ENERGIES NOUVELLES ,  ENI S.P.A.

    发明人： Jean Philippe Heraud ,  Jean Christophe Viguie ,  Sebastien Boucher ,  Chiara Della Torre ,  Elsa Mignone

    IPC分类号： C07C27/00 ,  C10G2/00 ,  B01J23/75 ,  B01J8/22 ,  B01J8/00 ,  B01D21/02

    CPC分类号： C10G2/332 ,  B01D21/02 ,  B01J8/001 ,  B01J8/007 ,  B01J8/228 ,  B01J23/75 ,  B01J2208/00176 ,  B01J2208/003 ,  B01J2219/00202 ,  B01J2219/00207 ,  B01J2219/00213 ,  B01J2219/00238 ,  B01J2219/0024 ,  C10G2/342

    摘要： The present invention concerns a process for the synthesis of hydrocarbons from a feed comprising synthesis gas, in which a solid catalyst comprising cobalt is used in a three-phase reaction section operated such that said catalyst is maintained in suspension in a liquid phase by movement of a gas phase from the bottom to the top of said reaction section, said process comprising an external loop for separating waxes, characterized in that: 1) the theoretical ratio PH2O:PH2 in the external loop for separating waxes is determined using the following calculation: PH2O:PH2 theoretical=Cv/(R1−Rft×Cv) where Cv=(COinlet−COdegas)/COinlet R1=H2 inlet/COinlet Rft=(H2 inlet−H2 degas)/(COinlet−COdegas) 2) if the theoretical ratio PH2O:PH2 determined in step 1) has a value of Rthreshold or higher, the temperature in the degassing means for the external loop for separating waxes is reduced, 3) steps 1) to 2) are repeated until the theoretical ratio PH2O:PH2 has a value strictly less than Rthreshold, where Rthreshold is in the range 0.1 to 1.1.

    摘要翻译： 本发明涉及从包含合成气的原料合成烃的方法，其中在三相反应段中使用含有钴的固体催化剂，其操作使得所述催化剂在液相中通过运动而保持在液相中的悬浮液 所述方法包括用于分离蜡的外部回路，其特征在于：1）用于分离蜡的外部回路中的理论比PH 2 O：PH 2通过以下计算确定： PH2理论值= Cv /（R1-Rft×Cv）其中Cv =（COinlet-Codegas）/ COinlet R1 = H2入口/ COinlet Rft =（H2入口-H2脱气）/（COinlet-COdegas）2） 在步骤1）中测定的PH2O：PH2的值为Rthreshold以上，用于分离蜡的外部回路的脱气装置中的温度降低3）重复步骤1）〜2），直到理论比PH 2 O：PH 2 具有严格小于Rt的值 阈值，其中Rthreshold在0.1到1.1的范围内。

    REACTOR SCHEME IN ANDRUSSOW PROCESS
    2.
    发明申请
    REACTOR SCHEME IN ANDRUSSOW PROCESS 审中-公开
    安德鲁斯过程中的反应堆计划

    公开(公告)号：US20160046497A1

    公开(公告)日：2016-02-18

    申请号：US14742050

    申请日：2013-12-12

    申请人： INVISTA NORTH AMERICA S.A R.L. ,  INVISTA TECHNOLOGIES S.A.R.L.

    发明人： Stewart FORSYTH ,  Aiguo LIU ,  Martin J. RENNER ,  Brent J. STAHLMAN

    IPC分类号： C01C3/02

    CPC分类号： C01C3/0212 ,  B01J12/007 ,  B01J19/2495 ,  B01J2219/00038 ,  B01J2219/002 ,  B01J2219/00202 ,  B01J2219/00213 ,  B01J2219/0024 ,  C01C3/0216 ,  C01C3/022 ,  Y02P20/132

    摘要： A process for the production of hydrogen cyanide comprises feeding a reaction mixture feed to a plurality of primary reactors each comprising a catalyst bed comprising platinum, wherein the reaction mixture feed comprises gaseous ammonia, methane, and oxygen gas, determining whether a percent yield of hydrogen cyanide in any of the plurality of primary reactors is at or below a threshold, identifying one or more suboptimal reactors amongst the plurality of primary reactors when the percent yield of hydrogen cyanide in any of the plurality of primary reactors is at or below the threshold, and supplementally feeding the reaction mixture feed to one or more supplementary reactors when the one or more suboptimal reactors are identified, wherein each of the one or more supplementary reactors comprises a catalyst bed comprising platinum. The supplemental feeding can be performed in place of the feeding of the reaction mixture feed to the one or more suboptimal reactors or in addition to the feeding of the reaction mixture feed to the one or more suboptimal reactors. The overall process is sufficient to maintain an overall measured hydrogen cyanide production rate amongst the one or more supplementary reactors and the primary reactors that is within a desired overall hydrogen cyanide production rate range.

    摘要翻译： 一种生产氰化氢的方法包括将反应混合物进料加入至包含铂的催化剂床的多个初级反应器中，其中反应混合物进料包括气态氨，甲烷和氧气，确定氢的百分比产率 在多个初级反应器中的任何一个反应器中的氰化物处于或低于阈值时，鉴定多个初级反应器中的任何一个中的氰化氢的百分比产率处于或低于阈值时，在多个初级反应器中识别一个或多个次优反应器， 以及当鉴定出所述一个或多个次优反应器时，将所述反应混合物进料补充进料至一个或多个辅助反应器，其中所述一个或多个辅助反应器中的每一个包括含有铂的催化剂床。 可以进行补充进料，代替反应混合物进料进料至一个或多个次最佳反应器，或者将反应混合物进料进料至一个或多个次最佳反应器。 整个方法足以在一个或多个辅助反应器和初级反应器中保持在所需的总体氰化氢生产速率范围内的总体测量的氰化氢生产速率。

    Method and apparatus for carbonylating methanol with acetic acid enriched flash stream
    6.
    发明申请
    Method and apparatus for carbonylating methanol with acetic acid enriched flash stream 有权
    用富含乙酸的闪蒸液羰基化甲醇的方法和装置

    公开(公告)号：US20110021817A1

    公开(公告)日：2011-01-27

    申请号：US12924234

    申请日：2010-09-23

    申请人： Jeremy J. Patt

    发明人： Jeremy J. Patt

    IPC分类号： C07C51/12 ,  B01J19/00

    CPC分类号： C07C51/12 ,  B01D3/06 ,  B01J14/005 ,  B01J19/0013 ,  B01J31/0231 ,  B01J31/20 ,  B01J2219/00006 ,  B01J2219/00164 ,  B01J2219/00202 ,  B01J2219/00213 ,  B01J2219/0024 ,  B01J2531/822 ,  B01J2531/827 ,  C07C51/445 ,  C07C53/08

    摘要： A carbonylation process for producing acetic acid including: (a) carbonylating methanol or its reactive derivatives in the presence of a Group VIII metal catalyst and methyl iodide promoter to produce a liquid reaction mixture including acetic acid, water, methyl acetate and methyl iodide; (b) feeding the liquid reaction mixture at a feed temperature to a flash vessel which is maintained at a reduced pressure; (c) heating the flash vessel while concurrently flashing the reaction mixture to produce a crude product vapor stream, wherein the reaction mixture is selected and the flow rate of the reaction mixture fed to the flash vessel as well as the amount of heat supplied to the flash vessel is controlled such that the temperature of the crude product vapor stream is maintained at a temperature less than 90° F. cooler than the feed temperature of the liquid reaction mixture to the flasher and the concentration of acetic acid in the crude product vapor stream is greater than 70% by weight of the crude product vapor stream.

    摘要翻译： 一种用于生产乙酸的羰基化方法，包括：（a）在第VIII族金属催化剂和甲基碘助催化剂存在下羰基化甲醇或其活性衍生物以产生包括乙酸，水，乙酸甲酯和甲基碘的液体反应混合物; （b）将进料温度下的液体反应混合物送入保持在减压状态的闪蒸容器; （c）加热闪蒸器，同时使反应混合物闪烁以产生粗产物蒸汽流，其中选择反应混合物，并将反应混合物的流速加入闪蒸容器以及供应至闪蒸器的热量 控制闪蒸容器，使得粗产物蒸汽流的温度保持在比液体反应混合物进入闪蒸器的进料温度低于90°F的温度和粗产物蒸气流中乙酸的浓度 大于70重量％的粗产物蒸气流。

    Method and apparatus for carbonylating methanol with acetic acid enriched flash stream
    7.
    发明申请
    Method and apparatus for carbonylating methanol with acetic acid enriched flash stream 有权
    用富含乙酸的闪蒸液羰基化甲醇的方法和装置

    公开(公告)号：US20090270650A1

    公开(公告)日：2009-10-29

    申请号：US12150481

    申请日：2008-04-29

    申请人： Jeremy J. Patt

    发明人： Jeremy J. Patt

    IPC分类号： C07C51/10 ,  B01J8/04

    CPC分类号： C07C51/12 ,  B01D3/06 ,  B01J14/005 ,  B01J19/0013 ,  B01J31/0231 ,  B01J31/20 ,  B01J2219/00006 ,  B01J2219/00164 ,  B01J2219/00202 ,  B01J2219/00213 ,  B01J2219/0024 ,  B01J2531/822 ,  B01J2531/827 ,  C07C51/445 ,  C07C53/08

    摘要： A carbonylation process for producing acetic acid including: (a) carbonylating methanol or its reactive derivatives in the presence of a Group VIII metal catalyst and methyl iodide promoter to produce a liquid reaction mixture including acetic acid, water, methyl acetate and methyl iodide; (b) feeding the liquid reaction mixture at a feed temperature to a flash vessel which is maintained at a reduced pressure; (c) heating the flash vessel while concurrently flashing the reaction mixture to produce a crude product vapor stream, wherein the reaction mixture is selected and the flow rate of the reaction mixture fed to the flash vessel as well as the amount of heat supplied to the flash vessel is controlled such that the temperature of the crude product vapor stream is maintained at a temperature less than 90° F. cooler than the feed temperature of the liquid reaction mixture to the flasher and the concentration of acetic acid in the crude product vapor stream is greater than 70% by weight of the crude product vapor stream.

    摘要翻译： 一种用于生产乙酸的羰基化方法，包括：（a）在第VIII族金属催化剂和甲基碘助催化剂存在下羰基化甲醇或其活性衍生物以产生包括乙酸，水，乙酸甲酯和甲基碘的液体反应混合物; （b）将进料温度下的液体反应混合物送入保持在减压状态的闪蒸容器; （c）加热闪蒸器，同时使反应混合物闪烁以产生粗产物蒸汽流，其中选择反应混合物，并将反应混合物的流速加入闪蒸容器以及供应至闪蒸器的热量 控制闪蒸容器，使得粗产物蒸汽流的温度保持在比液体反应混合物进入闪蒸器的进料温度低于90°F的温度和粗产物蒸气流中乙酸的浓度 大于70重量％的粗产物蒸气流。

    Method and Apparatus for Microwave Assisted High Throughput High Pressure Chemical Synthesis
    8.
    发明申请
    Method and Apparatus for Microwave Assisted High Throughput High Pressure Chemical Synthesis 有权
    微波辅助高通量高压化学合成方法与装置

    公开(公告)号：US20080053989A1

    公开(公告)日：2008-03-06

    申请号：US11853102

    申请日：2007-09-11

    申请人： Wyatt Hargett ,  James Thomas

    发明人： Wyatt Hargett ,  James Thomas

    IPC分类号： H05B6/64

    CPC分类号： H05B6/806 ,  B01J19/0046 ,  B01J19/126 ,  B01J2219/00162 ,  B01J2219/002 ,  B01J2219/00231 ,  B01J2219/0024 ,  B01J2219/00283 ,  B01J2219/0034 ,  B01J2219/00353 ,  B01J2219/00477 ,  B01J2219/00495 ,  B01J2219/00601 ,  B01J2219/00689 ,  B01J2219/00691 ,  B01J2219/0869 ,  B01J2219/1215 ,  B01J2219/1239 ,  B01J2219/1275 ,  C40B60/14 ,  H05B6/6408

    摘要： A method and associated instrument are disclosed for increasing the sequential rate at which a series of microwave assisted chemical reactions that potentially generate high pressure can be carried out. The method includes the steps of opening a pressure-resistant valve on a microwave-transparent pressure-resistant vessel to define a unpressurized pathway through the valve into the vessel, inserting a tube through the pathway in the valve and into the vessel, transferring at least one composition into the vessel through the tube, removing the tube from the vessel and from the pathway in the valve, closing the valve to seal the vessel against pressure release, and exposing the vessel and its contents to microwave radiation. The instrument includes a source of microwave radiation, a cavity in microwave communication with the source, an attenuator that forms at least a portion of the cavity, a pressure-resistant microwave-transparent reaction vessel having portions in the cavity and portions in the attenuator, a pressure-resistant valve on the mouth of the vessel, a reciprocating tube for passing through the valve and into the vessel when the valve is open, and means for mechanically inserting and retracting the tube through the valve and into the vessel when the vessel is in the cavity and the attenuator.

    摘要翻译： 公开了一种方法和相关联的仪器，用于增加可以进行可能产生高压的一系列微波辅助化学反应的顺序速率。 该方法包括以下步骤：在微波透明耐压容器上打开耐压阀，以限定通过阀进入容器的非加压路径，将管穿过阀中的通道插入容器中，至少转移 一个组合物通过管子进入容器，从容器中取出管子并从阀门中的通道中取出管子，关闭阀门以密封容器以抵抗压力释放，并将容器及其内容物暴露于微波辐射。 仪器包括微波辐射源，与源极微波连通的空腔，形成空腔的至少一部分的衰减器，具有空腔中的部分和衰减器中的部分的耐压微波透明反应容器， 容器口上的耐压阀，当阀打开时通过阀门并进入容器的往复式管，以及用于当管是容器时通过阀机械地插入和收回管并进入容器的装置 在腔和衰减器中。

    Resonant Shaking
    9.
    发明申请
    Resonant Shaking 审中-公开
    共鸣震动

    公开(公告)号：US20070280036A1

    公开(公告)日：2007-12-06

    申请号：US11840698

    申请日：2007-08-17

    申请人： Ricardo Carreras

    发明人： Ricardo Carreras

    IPC分类号： B01F11/00

    CPC分类号： B01J19/285 ,  B01F11/0022 ,  B01J2219/00191 ,  B01J2219/00207 ,  B01J2219/0024 ,  B06B1/0261 ,  Y10S366/601

    摘要： A resonant shaker includes a support tray for supporting a target carrier. A sensor generates an electrical signal that is related to an acceleration of the support tray. A linear drive motor includes an armature that is coupled to the support tray. The linear drive motor provides an oscillating drive force to the support tray in response to a drive current applied to the linear drive motor. The resonant shaker also includes a controller. The controller receives the electrical signal from the sensor and a drive signal that is related to the drive current. The controller transmits a modified drive current to the linear drive motor in response to a predetermined phase relationship between the electrical signal and the drive signal.

    摘要翻译： 共振振动器包括用于支撑目标载体的支撑盘。 传感器产生与支撑盘的加速度有关的电信号。 线性驱动电动机包括联接到支撑盘的电枢。 线性驱动电机响应于施加到线性驱动电动机的驱动电流而向支撑盘提供振荡驱动力。 共振振荡器还包括一个控制器。 控制器接收来自传感器的电信号和与驱动电流相关的驱动信号。 控制器响应于电信号和驱动信号之间的预定相位关系向线性驱动电动机传送修改的驱动电流。