摘要:
Solvent-soluble, heat-hardening, non-gelled resins are provided by etherifying a polymethoxy siloxane with an unsaturated hydroxy-functional compound, with some of the methoxy groups of the siloxane being preserved for subsequent cure. This ether is then copolymerized with other ethylenically unsaturated materials to form a copolymer which includes methoxy groups carried by the siloxane in order to improve the elevated temperature cure of the resin. The preparation of an unsaturated ether by a reaction in which alcohol instead of water is removed coupled with subsequent polymerization enables larger proportions of the resinous siloxane material to be incorporated into the resin.
摘要:
Multiple sequence block copolymers of silicone and styrene having the formula: (1) (ABA)x ARE PRODUCED, WHERE A represents repeating diorganosiloxy units and B represents a polystyrene chain. This ABA chain is repeated from three to 10 times. The materials have high elongation and tensile strength and are useful in the formation of strong, elastic films.
摘要:
A PROCESS HAS BEEN DEVELOPED FOR DIRECTLY PRODUCING A MODIFIED POLYOLEFIN COMPOSITION IN PARTICULATE FORM WHICH HAS IMPROVED ADHESIVENESS. GENERALLY, THE PROCESS COMPRISES PROVIDING AN OLEFIN POLYMER IN PARTICULATE FORM; ADMIXING THE OLEFIN POLYMER, AN ORGANIC PEROXIDE AND A SPECIFIC POLYMERIZABLE COMPOUND HAVING THE GENERAL FORMULA
CH2=C(-R3)-(R4)(0-1)-SI(-R5)3
REACTING THE MIXTURE IN AN INERT ATMOSPHERE AT A TEMPERATURE BELOW THE TACKY POINT OF THE POLYMER; AND DIRECTLY RECOVERING THE MODIFIED POLYOLEFIN COMPOSITION.
摘要:
A method is disclosed for preparing graft polymers of alpha-substituted-beta-propiolactones, comprising the step of providing anionic sites in an amorphous base polymer and reacting the anionic compound with an alpha-substituted-beta-propiolactone. Critical concentrations of unsaturation in the base polymer and critical quantities of the beta-propiolactone concerned are indicated.
摘要:
Graft-polymers of,.alpha.,.alpha.'-disubstituted .beta.-propiolactones on isobutylene-triene copolymers are prepared by reacting an isobutylene-triene copolymer with maleic anhydride and possibly with other functionalizing agents adapted to introduce acid and ester groups in the copolymer molecule and by neutralizing or hydrolyzing, or both, with a tetraalkylammonium base, said functional groups, said neutralization or hydrolysis, or both, being followed by a grafting reaction with pivalolactone.
摘要:
Water-swellable crosslinked polymer gels show increased adhesion to wood and other cellulosic materials and also increased waterabsorbing capacity when there is incorporated in the gel up to about an equal weight of a cationic polymer such as a polyalkylenepolyamine, a polyalkylenimine, or a cationic polyacrylamide. The increased adhesion of both dry and waterswollen gels makes the invention useful in fire fighting and in the preparation of water-absorbing laminates.
摘要:
Moulding composition in particulate form comprising at least one prepolymer containing urethane groups and having the structure
and hereinafter referred to as the vinyl-ended prepolymer, in which R1 and R2 are each divalent organic groups at least one of which contains at least one cyclic group in the chain and are such that in said structure there are not more than 20 atoms in the chain between each cyclic group, n is a whole number of from 1 to 20, and when n is one and only R2 contains a cyclic group in the chain there are no more than 20 atoms in the chain between the cyclic group in R2 and the nitrogen atom attached to the group X, R3 is hydrogen or a hydrocarbyl group and X is a divalent group are useful in forming articles such as films.
摘要:
Disclosed herein are random graft copolymer compositions comprising base polymers that are amorphous to x-rays at a temperature of 130*C. or below, to which base polymer is randomly grafted, on the average, at least one sidechain of crystallizable homopolymers, of Alpha -substituted- Beta -propiolactones and/or copolymers thereof; a process for making said random graft compositions; and use thereof, inter alia, as molded or extruded articles.
摘要:
IN MODIFIED POLYOLEFIN COMPOSITION PREPARED BY REACTING AN OLEFIN POLYMER WITH A POLYMERIZABLE COMPOUND GENERALLY DEFINED BY
CH2=C(-R3)-(R4)(0-1)-SI(-R5)3
IN THE PRESENCE OF AN ORGAIC PEROXIDE, THE MELT FLOW MAY BE CONTROLLED BY INCLUDING IN THE REACTION MIXTURE A QUANTITY OF XYLENE. THE REACTION PRODUCT IS PARTICULARLY SUITED FOR REINFORCEMENT WITH FILAMENTARY MATERIAL OR AS A COATING ON METALLIC SURFACES.