摘要:
Heat-curable plasticized mixtures for the manufacture of moulding materials based on polyurethanes, containing (a) a polyisocyanate, for example 3,5,5-trimethyl-3-(isocyanatomethyl)-cyclohexane-isocyanate-(1) (''''isophoronediisocyanate''''), (b) a long-chain polyester processing terminal hydroxyl groups (for example a polyester of 4 mols of sebacic acid and 4.5 mols of 1,6-hexanediol) and (c) a defined aromatic polycarboxylic acid hydroxyester containing at least one secondary hydroxyl group (for example a hydroxyester manufactured by reacting 1 mol of trimellitic anhydride and 1 mol of 1,2-propanediol in a first stage, and further reaction with 2 mols of a monoepoxide), with the mixture containing, per 1 equivalent of isocyanate group, 0.05 to 0.3 hydroxyl equivalents of the polyester (b) and 0.3 to 1.0 hydroxyl equivalents of the aromatic polycarboxylic acid hydroxyester (c). The mouldings obtained by hot curing of the moulding compositions are flexible, tough and impact-resistant, and these mechanical properties are largely independent of temperature; a transition to the soft rubbery-elastic state only occurs above 150* C.
摘要:
A polyester- or polyether- urethane segmented polymer of substantially homogeneous structure, comprising polyester or polyether segments with reversibly thermolabile urethane crosslinks between neighboring polymer chains, and processes for producing such polymers.
摘要:
A TACKY ADHESIVE COMPOSITION WHICH CURES AT ROOM TEMPERATURE TO STRONG, ADHESIVE, AND FLEXIBLE STATE IS OBTAINED WHEN (1) A NORMALLY SOLID POLYOL-ARYLENE-DIISOCYANATE PREPOLYMER CARRYING AT LEAST THREE ISOCYANATO SUBSTITUENTS; (2) A NORMALLY SOLID LINEAR PREPOLYMER COMPOSED OF POLYESTER AND POLYURETHANE LINKAGES AND CARRYING TWO TERMINAL ALCOHOLIC-OH SUBSTITUENTS; (3) A SATURATED POLYOL HAVING A MOLECULAR WEIGHT IN EXCESS OF 2,000 AND HAVING AN AVERAGE CONTENT OF AT LEAST THREE ALCOHOLIC-OH SUBSTIUENTS PER MOLECULE; AND (4) A DIFUNCTIONAL MONOMERIC CURING AGENT FOR THE COMPONENTS OF SAID COMPOSITON WHICH CARRY ISOCYANATO SUBSTITUENTS, THE FUNCTIONAL GROUPS OF SAID AGENT BEING SEPARATED BY AT LEAST 4 CARBON ATOMS; ARE MIXED WHEN APPROXIMATLELY EQUIVALENT REACTIVE RATIO.
摘要:
AN OPEN-PORT POLYURETHANE STRUCTURE HAVING A POROSITY OF AT LEAST 50% AND A DENSITY OF 0.1-0.5 GRAM PER CUBIC CENTIMETER, AND COMPRISING COHERENT SPERICAL PARTICLES OF LESS THAN 10 MICRONS DIAMETER SEPARATED BY INTERCONNECTED INTERSTICES USEFUL AS A FILTER AND OIL-ABSORBENT; AND THE METHOD OF PRODUCING SAID STRUCTURE.
摘要:
A process for the production of a rigid foamed or non-foamed polyurethane which comprises reacting a low molecular weight adduct, formed by reacting a lactone and optionally an epoxide with a polyfunctional initiator having three or more active hydrogen atoms, with a di-isocyanate.
摘要:
A POLYURTHANE COMPOSITION PREPARED BY REACTING OTOLIDINE DIISOCYANATE, DICUMYL PROXIDE AND AN UNSATURATED POLYESTER DIOL OF THE STRUCTURE OBTAINED BY THE CONDENSATION OF ADIPIC ACID AND A MIXTURE OF ETHYLENE GLYCOL AND GLYCEROL A-ALLYL ETHER WHERE THE SAID COMPOSITION HAS A SHORE A HARDNESS OF FROM ABOUT 25 TO ABOUT 45 AND AN ARE IMAGE CHAR RATE OF FROM ABOUT 1.5 TO ABOUT 3 MILS/ SECOND.
摘要:
A process for preparing a light-sensitive high molecular weight polymer compound, which comprises reacting an Beta -unsaturated carboxylic acid with an aliphatic or aromatic diepoxide to form the corresponding diol compound and reacting a diisocyanate compound with said diol compound and a process for preparing the light-sensitive high molecular weight polymer compounds, and to the novel polymer compounds produced.
摘要:
Heat-curable plasticised mixtures for the manufacture of moulding materials based on polyurethanes, containing (a) a polyisocyanate, (b) a slightly branched polyester possessing terminal hydroxyl groups and (c) a defined aromatic polycarboxylic acid hydroxyester containing at least one secondary hydroxyl group (for example a hydroxyester manufactured by reacting 1 mol of trimellitic anhydride and 1 mol of 1,2propanediol in a first stage, and further reaction with 2 mols of cresylglycid), with the mixture containing, per 1 equivalent of isocyanate group, 0.05 to 0.3 hydroxyl equivalents of the polyester (b) and 0.3 to 1.0 hydroxyl equivalents of the aromatic polycarboxylic acid hydroxyester (c). The mouldings obtained by hot curing of the moulding compositions are flexible, tough and impact-resistant, and these mechanical properties are largely independent of temperature; a transition to the soft rubberyelastic state only occurs above 150*C.