Heat-curable polyurethane foams and elastomers based on aromatic polyesters
    1.
    发明授权
    Heat-curable polyurethane foams and elastomers based on aromatic polyesters 失效
    基于芳族聚酯的热固性聚氨酯泡沫塑料和弹性体

    公开(公告)号:US3718623A

    公开(公告)日:1973-02-27

    申请号:US3718623D

    申请日:1971-03-01

    申请人: CIBA GEIGY AG

    摘要: Heat-curable plasticized mixtures for the manufacture of moulding materials based on polyurethanes, containing (a) a polyisocyanate, for example 3,5,5-trimethyl-3-(isocyanatomethyl)-cyclohexane-isocyanate-(1) (''''isophoronediisocyanate''''), (b) a long-chain polyester processing terminal hydroxyl groups (for example a polyester of 4 mols of sebacic acid and 4.5 mols of 1,6-hexanediol) and (c) a defined aromatic polycarboxylic acid hydroxyester containing at least one secondary hydroxyl group (for example a hydroxyester manufactured by reacting 1 mol of trimellitic anhydride and 1 mol of 1,2-propanediol in a first stage, and further reaction with 2 mols of a monoepoxide), with the mixture containing, per 1 equivalent of isocyanate group, 0.05 to 0.3 hydroxyl equivalents of the polyester (b) and 0.3 to 1.0 hydroxyl equivalents of the aromatic polycarboxylic acid hydroxyester (c). The mouldings obtained by hot curing of the moulding compositions are flexible, tough and impact-resistant, and these mechanical properties are largely independent of temperature; a transition to the soft rubbery-elastic state only occurs above 150* C.

    摘要翻译: 含有(a)多异氰酸酯,例如3,5,5-三甲基-3-(异氰酸基 - 甲基) - 环己烷 - 异氰酸酯 - (1)[“异佛尔酮二异氰酸酯(I))的热塑性塑化混合物,用于制造基于聚氨酯的成型材料 “],(b)长链聚酯加工端羟基(例如4摩尔癸二酸的聚酯和4.5摩尔的1,6-己二醇)和(c)限定的芳族多羧酸羟基酯,其含有至少一个 仲羟基(例如通过使1摩尔偏苯三酸酐与1摩尔1,2-丙二醇在第一阶段中反应制备的羟基酯,并进一步与2摩尔单环氧化物反应),混合物每1当量 异氰酸酯基,聚酯(b)的0.05〜0.3羟基当量和芳香族多元羧酸羟基酯(c)的0.3〜1.0羟基当量。 通过模塑组合物的热固化获得的模制品是柔韧的,坚韧的和抗冲击的,并且这些机械性能在很大程度上独立于温度; 过渡到软橡胶弹性状态只发生在150℃以上。

    Polymeric compositions
    5.
    发明授权
    Polymeric compositions 失效
    聚合物组合物

    公开(公告)号:US3897399A

    公开(公告)日:1975-07-29

    申请号:US32759473

    申请日:1973-01-29

    IPC分类号: C08G18/42 C08G22/12

    摘要: A process for the production of a rigid foamed or non-foamed polyurethane which comprises reacting a low molecular weight adduct, formed by reacting a lactone and optionally an epoxide with a polyfunctional initiator having three or more active hydrogen atoms, with a di-isocyanate.

    摘要翻译: 一种用于生产刚性发泡或非发泡聚氨酯的方法,其包括使内酯和任选的环氧化物与具有三个或更多个活性氢原子的多官能引发剂反应形成的低分子量加合物与二异氰酸酯反应。

    Char resistant polyurethane
    6.
    发明授权
    Char resistant polyurethane 失效
    耐火聚氨酯

    公开(公告)号:US3577389A

    公开(公告)日:1971-05-04

    申请号:US3577389D

    申请日:1968-08-19

    发明人: KUHAR GEORGE A

    CPC分类号: C08G18/7685 C08G18/68

    摘要: A POLYURTHANE COMPOSITION PREPARED BY REACTING OTOLIDINE DIISOCYANATE, DICUMYL PROXIDE AND AN UNSATURATED POLYESTER DIOL OF THE STRUCTURE OBTAINED BY THE CONDENSATION OF ADIPIC ACID AND A MIXTURE OF ETHYLENE GLYCOL AND GLYCEROL A-ALLYL ETHER WHERE THE SAID COMPOSITION HAS A SHORE A HARDNESS OF FROM ABOUT 25 TO ABOUT 45 AND AN ARE IMAGE CHAR RATE OF FROM ABOUT 1.5 TO ABOUT 3 MILS/ SECOND.

    New thermosetting mixtures of polyisocyanates,weakly branched polyesters and polyoles
    10.
    发明授权
    New thermosetting mixtures of polyisocyanates,weakly branched polyesters and polyoles 失效
    聚异氰酸酯,弱分散聚酯和聚烯烃的新型热固化混合物

    公开(公告)号:US3821165A

    公开(公告)日:1974-06-28

    申请号:US25652772

    申请日:1972-05-24

    申请人: CIBA GEIGY CORP

    摘要: Heat-curable plasticised mixtures for the manufacture of moulding materials based on polyurethanes, containing (a) a polyisocyanate, (b) a slightly branched polyester possessing terminal hydroxyl groups and (c) a defined aromatic polycarboxylic acid hydroxyester containing at least one secondary hydroxyl group (for example a hydroxyester manufactured by reacting 1 mol of trimellitic anhydride and 1 mol of 1,2propanediol in a first stage, and further reaction with 2 mols of cresylglycid), with the mixture containing, per 1 equivalent of isocyanate group, 0.05 to 0.3 hydroxyl equivalents of the polyester (b) and 0.3 to 1.0 hydroxyl equivalents of the aromatic polycarboxylic acid hydroxyester (c). The mouldings obtained by hot curing of the moulding compositions are flexible, tough and impact-resistant, and these mechanical properties are largely independent of temperature; a transition to the soft rubberyelastic state only occurs above 150*C.