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公开(公告)号：US5561232A
公开(公告)日：1996-10-01
申请号：US319399
申请日：1994-10-06
Applicant: Zhimin Hao , John S. Zambounis , Abul Iqbal
Inventor： Zhimin Hao , John S. Zambounis , Abul Iqbal
IPC: C09B1/00 , C09B1/22 , C09B5/62 , C09B7/02 , C09B7/08 , C09B19/00 , C09B19/02 , C09B29/00 , C09B47/12 , C09B47/16 , C09B47/20 , C09B47/26 , C09B48/00 , C09B57/04 , C09B67/20 , C09B67/28 , C09B69/00 , C09B69/08 , C09K11/06 , G03G5/06 , G03G9/06 , G03G9/09 , C07D471/04
CPC classification number: C09B68/443 , C09B1/005 , C09B19/02 , C09B29/0033 , C09B47/12 , C09B47/26 , C09B48/00 , C09B5/62 , C09B57/04 , C09B67/0077 , C09B68/46 , C09B68/4677 , C09B69/08 , C09B7/02 , C09K11/06 , G03G9/0908 , G03G9/0912 , G03G9/0918 , G03G9/092 , G03G9/0924 , G03G9/0926 , G03G5/0696
Abstract: Compounds of formulaA(B).sub.x, (I),whereinx is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m and n, are as defined in claim 1. These carbamate group-containing soluble chromophores am distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.
Abstract translation: 式A（B）x，（I）的化合物，其中x为1至4的整数，A为喹吖啶酮，蒽醌，苝，靛蓝，喹酞酮，异吲哚啉酮，异吲哚啉，二恶嗪，酞菁或偶氮的发色团的基团 该基团含有连接到B上的x个N原子，优选与至少一个直接相邻的或共轭的羰基相连，B是下式的基团：（III）（IV）和 如果x是2,3或4，也可以是一个，两个或三个氢原子。 符号Q，R1，R2，R3，R4，X，Y，Z，m和n如权利要求1中所定义。这些含氨基甲酸酯基团的可溶性发色团的特征在于UV范围内出色的固态荧光，以及 通过它们可以将它们转化成它们所掺入的底物中的相应颜料。
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公开(公告)号：US3480378A
公开(公告)日：1969-11-25
申请号：US3480378D
申请日：1965-03-10
Applicant: BAYER AG
Inventor： TAUBE CARL , FREYTAG KARL-HEINZ
IPC: C09B69/00 , C09B69/08 , D06P1/00 , D06P1/52 , D06P1/645 , D06P1/673 , D06P3/36 , D06P3/54 , D06P3/52
CPC classification number: D06P3/36 , C09B69/00 , C09B69/08 , D06P1/0048 , D06P1/52 , D06P1/645 , D06P1/673 , D06P1/6735 , D06P3/54 , Y10S8/922
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公开(公告)号：US3084988A
公开(公告)日：1963-04-09
申请号：US4454860
申请日：1960-07-22
Applicant: CFMC
IPC: C09B43/124 , C09B69/08 , D06P1/00 , D06P3/70
CPC classification number: D06P3/70 , C09B43/1245 , C09B69/08 , D06P1/0048 , Y10S8/927
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公开(公告)号：US6127549A
公开(公告)日：2000-10-03
申请号：US89142
申请日：1998-06-02
Applicant: Zhimin Hao , John S. Zambounis , Abul Iqbal
Inventor： Zhimin Hao , John S. Zambounis , Abul Iqbal
IPC: C09B1/00 , C09B1/22 , C09B5/62 , C09B7/02 , C09B7/08 , C09B19/00 , C09B19/02 , C09B29/00 , C09B47/12 , C09B47/16 , C09B47/20 , C09B47/26 , C09B48/00 , C09B57/04 , C09B67/20 , C09B67/28 , C09B69/00 , C09B69/08 , C09K11/06 , G03G5/06 , G03G9/06 , G03G9/09 , C07D209/36
CPC classification number: C09B68/443 , C09B1/005 , C09B19/02 , C09B29/0033 , C09B47/12 , C09B47/26 , C09B48/00 , C09B5/62 , C09B57/04 , C09B67/0077 , C09B68/46 , C09B68/4677 , C09B69/08 , C09B7/02 , C09K11/06 , G03G9/0908 , G03G9/0912 , G03G9/0918 , G03G9/092 , G03G9/0924 , G03G9/0926 , G03G5/0696
Abstract: Compounds of formula:A(B).sub.x, (I),wherein x is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula: ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m und n, are as defined in claim 1.These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.
Abstract translation: A（B）x，（I）的化合物，其中x是1至4的整数，A是喹吖啶酮，蒽醌，苝，靛蓝，喹酞酮，异吲哚啉酮，异吲哚啉，二恶嗪，酞菁的发色团的基团 或偶氮系列，该基团含有与B连接的x个N原子，优选与至少一个直接相邻或共轭的羰基，B是下式的基团：并且如果x是2,3或4，也可以是一个， 两个或三个氢原子。 符号Q，R 1，R 2，R 3，R 4，X，Y，Z，m和n如权利要求1中所定义。这些含氨基甲酸酯基团的可溶性发色团的特征在于UV范围内的突出的固态荧光，以及 通过它们可以将它们转化成它们所掺入的底物中的相应颜料。
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公开(公告)号：US5811543A
公开(公告)日：1998-09-22
申请号：US677486
申请日：1996-07-09
Applicant: Zhimin Hao , John S. Zambounis , Abul Iqbal
Inventor： Zhimin Hao , John S. Zambounis , Abul Iqbal
IPC: C09B1/00 , C09B1/22 , C09B5/62 , C09B7/02 , C09B7/08 , C09B19/00 , C09B19/02 , C09B29/00 , C09B47/12 , C09B47/16 , C09B47/20 , C09B47/26 , C09B48/00 , C09B57/04 , C09B67/20 , C09B67/28 , C09B69/00 , C09B69/08 , C09K11/06 , G03G5/06 , G03G9/06 , G03G9/09 , C07D487/22 , C09B67/50
CPC classification number: C09B68/443 , C09B1/005 , C09B19/02 , C09B29/0033 , C09B47/12 , C09B47/26 , C09B48/00 , C09B5/62 , C09B57/04 , C09B67/0077 , C09B68/46 , C09B68/4677 , C09B69/08 , C09B7/02 , C09K11/06 , G03G9/0908 , G03G9/0912 , G03G9/0918 , G03G9/092 , G03G9/0924 , G03G9/0926 , G03G5/0696
Abstract: Compounds of the formula A(B).sub.x (I), wherein x is an integer from 1 to 4, A is the radical of a chromophore of the phthalocyanine series, which radical contains x B groups attached to N-atoms, preferably with at least one directly adjacent to or conjugated with a carbonyl group, B is a group of the formula ##STR1## and, if x is 2,3 or 4, may also be one, two or three hydrogen atoms, wherein the symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, Y, Z, m and n, are as defined in the disclosure These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.
Abstract translation: 式A（B）x（I）的化合物，其中x是1至4的整数，A是酞菁系发色团的基团，该基团含有与N原子连接的x B基团，优选在 至少一个直接与羰基相邻或与羰基结合，B是式（II）的化合物（III）或（IMAGE）（IV），如果x是2,3或4，可以 也可以是1,2或3个氢原子，其中符号Q，R 1，R 2，R 3，R 4，Y，Z，m和n如本公开所定义。这些含氨基甲酸酯基团的可溶性发色团的特征在于优异的固态 在UV范围内的荧光以及它们可以被转化成它们所掺入的底物中的相应颜料的容易程度。
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Patent Agency Ranking
公开(公告)号：US5750758A
公开(公告)日：1998-05-12
申请号：US681205
申请日：1996-07-22
Applicant: John Zambounis , Veronique Hall-Goulle
Inventor： John Zambounis , Veronique Hall-Goulle
IPC: B01J31/02 , C07B61/00 , C07C68/06 , C07C69/96 , C07D471/04 , C07D487/04 , C09B1/00 , C09B5/62 , C09B7/02 , C09B19/02 , C09B29/00 , C09B47/16 , C09B47/26 , C09B48/00 , C09B57/00 , C09B57/04 , C09B69/08 , C09K9/02
CPC classification number: C07D471/04 , C07D487/04 , C09B1/005 , C09B19/02 , C09B29/0037 , C09B47/16 , C09B47/26 , C09B48/00 , C09B5/62 , C09B57/004 , C09B57/04 , C09B69/08 , C09B7/02 , C09K9/02
Abstract: This invention is a process for the preparation of a pyrocarbonic acid diester of formula (I) ##STR1## wherein R.sub.1 and R.sub.1 ' are each, independently of the other, an optionally substituted branched or straight-chain C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 alkenyl, C.sub.3 -C.sub.24 alkynyl, C.sub.4 -C.sub.12 cycloalkyl, C.sub.4 -C.sub.12 cycloalkenyl or C.sub.7 -C.sub.24 aralkyl, by reacting at least one ester carbonate of formula (II) ##STR2## with 40-50 mol % of a sulfochloride of formula (IV) ##STR3## in the presence of 0.8-5 mol % of a catalyst of formula (V) ##STR4## and with minor amounts of a heterocyclic aromatic amine in a nonpolar inert solvent, in which process the amount of heterocyclic aromatic amine is 1-3 mol % and the reaction is carried out in the temperature range from -10.degree. C. to +25.degree. C., all molar amounts being based on 100 mol % of ester carbonate of formula (II).
Abstract translation: 本发明是制备式（I）的焦碳酸二酯的方法，其中R 1和R 1'各自独立地为任选取代的支链或直链C 1 -C 24烷基，C 3 C 20 -C 20炔基，C 4 -C 12环烷基，C 4 -C 12环烯基或C 7 -C 24芳烷基，通式（II）的至少一种碳酸酯与式（IV）的40-50摩尔％磺酰氯反应， ）（IV）在0.8-5mol％的式（V）催化剂（V）和少量杂环芳族胺存在下，在非极性惰性溶剂中，其中量 的杂环芳族胺为1-3摩尔％，反应在-10℃至+ 25℃的温度范围内进行，所有摩尔量均为100摩尔％的式（II）酯酸酯， 。
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公开(公告)号：US6013777A
公开(公告)日：2000-01-11
申请号：US095618
申请日：1998-06-10
Applicant: Zhimin Hao , John S. Zambounis , Abul Iqbal
Inventor： Zhimin Hao , John S. Zambounis , Abul Iqbal
IPC: C09B1/00 , C09B1/22 , C09B5/62 , C09B7/02 , C09B7/08 , C09B19/00 , C09B19/02 , C09B29/00 , C09B47/12 , C09B47/16 , C09B47/20 , C09B47/26 , C09B48/00 , C09B57/04 , C09B67/20 , C09B67/28 , C09B69/00 , C09B69/08 , C09K11/06 , G03G5/06 , G03G9/06 , G03G9/09 , C07D209/77 , C07D221/18 , C07D403/02 , C07D471/04 , C07D487/22
CPC classification number: C09B68/443 , C09B1/005 , C09B19/02 , C09B29/0033 , C09B47/12 , C09B47/26 , C09B48/00 , C09B5/62 , C09B57/04 , C09B67/0077 , C09B68/46 , C09B68/4677 , C09B69/08 , C09B7/02 , C09K11/06 , G03G9/0908 , G03G9/0912 , G03G9/0918 , G03G9/092 , G03G9/0924 , G03G9/0926 , G03G5/0696
Abstract: Compounds of formulaA(B).sub.x, (I),wherein x is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m and n, are as defined in claim 1.These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.
Abstract translation: 式A（B）x，（I）的化合物，其中x是1至4的整数，A是喹吖啶酮，蒽醌，苝，靛蓝，喹酞酮，异吲哚啉酮，异吲哚啉，二恶嗪，酞菁或偶氮的发色团的基团 该基团包含与B连接的x个N原子，优选与至少一个直接相邻或共轭的羰基，B是式的基团，如果x是2,3或4，也可以是一个，两个或三个 氢原子。 符号Q，R1，R2，R3，R4，X，Y，Z，m和n如权利要求1中所定义。这些含氨基甲酸酯基团的可溶性发色团的特征在于UV范围内的优异的固态荧光，以及 通过它们可以将它们转化成它们所掺入的底物中的相应颜料。
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公开(公告)号：US5874580A
公开(公告)日：1999-02-23
申请号：US89143
申请日：1998-06-02
Applicant: Zhimin Hao , John S. Zambounis , Abul Iqbal
Inventor： Zhimin Hao , John S. Zambounis , Abul Iqbal
IPC: C09B1/00 , C09B1/22 , C09B5/62 , C09B7/02 , C09B7/08 , C09B19/00 , C09B19/02 , C09B29/00 , C09B47/12 , C09B47/16 , C09B47/20 , C09B47/26 , C09B48/00 , C09B57/04 , C09B67/20 , C09B67/28 , C09B69/00 , C09B69/08 , C09K11/06 , G03G5/06 , G03G9/06 , G03G9/09 , C07D221/18
CPC classification number: C09B68/443 , C09B1/005 , C09B19/02 , C09B29/0033 , C09B47/12 , C09B47/26 , C09B48/00 , C09B5/62 , C09B57/04 , C09B67/0077 , C09B68/46 , C09B68/4677 , C09B69/08 , C09B7/02 , C09K11/06 , G03G9/0908 , G03G9/0912 , G03G9/0918 , G03G9/092 , G03G9/0924 , G03G9/0926 , G03G5/0696
Abstract: Compounds of formulaA(B).sub.x, (I),wherein x is an integer from 1 to 4, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula ##STR1## and, if x is 2,3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m und n, are as defined in claim 1.These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.
Abstract translation: 式A（B）x，（I）的化合物，其中x是1至4的整数，A是喹吖啶酮，蒽醌，苝，靛蓝，喹酞酮，异吲哚啉酮，异吲哚啉，二恶嗪，酞菁或偶氮的发色团的基团 该基团含有连接到B上的x个N原子，优选与至少一个直接相邻的或共轭的羰基相连，B是下式的基团：（III）（IV）和 如果x是2,3或4，也可以是一个，两个或三个氢原子。 符号Q，R 1，R 2，R 3，R 4，X，Y，Z，m和n如权利要求1中所定义。这些含氨基甲酸酯基团的可溶性发色团的特征在于UV范围内的突出的固态荧光，以及 通过它们可以将它们转化成它们所掺入的底物中的相应颜料。
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9.发明授权Water-soluble dyestuffs readily convertible into insoluble form and process for preparing them 失效水溶性染料易于转化为不溶形式，并可用于制备它们
公开(公告)号：US3972904A
公开(公告)日：1976-08-03
申请号：US157667
申请日：1971-06-28
Applicant: Hans-Ulrich von der Eltz , Dieter Gunther , Karl-Heinz Krell , Karl Matterstock , Hansjorg Vollmann
Inventor： Hans-Ulrich von der Eltz , Dieter Gunther , Karl-Heinz Krell , Karl Matterstock , Hansjorg Vollmann
IPC: C09B1/38 , C09B1/51 , C09B1/54 , C09B1/60 , C09B7/10 , C09B25/00 , C09B43/20 , C09B47/26 , C09B69/08 , C09B1/36 , D06P3/52
CPC classification number: C09B69/08 , C09B1/38 , C09B1/51 , C09B1/545 , C09B1/547 , C09B1/60 , C09B25/00 , C09B43/206 , C09B47/26 , C09B7/10
Abstract: Water-soluble dyestuffs of the general formula ##EQU1## WHEREIN F represents the radical of a water-insoluble anthraquinone dyestuff, X represents an oxygen atom, a sulfur atom or a nitrogen atom which is substituted by a hydrogen atom, a lower alkyl, phenyl, lower acyl or sulfonyl group and Me represents an alkali metal or ammonium ion made by solubilizing insoluble dyestuffs which may be indigo, nitro, azo, imide, anthraquinone, oxazine, thiazine, dioxazine, quinoline, methine, polymethine or phthalocyanine dyestuffs. The water-soluble dyestuffs are adapted to be used in dyeing and printing synthetic fibers and are characterized by the fact that they can easily be converted during the process of dyeing to the original water-insoluble dyestuffs by the influence of heat. They are especially useful for the dyeing of polyester in which material they yield deep dyeings.
Abstract translation: 通式FX-CO-N-SO 3 Me | Me的水溶性染料代表水不溶性蒽醌染料的基团，X表示氧原子，硫原子或被氢原子取代的氮原子 ，低级烷基，苯基，低级酰基或磺酰基，Me表示通过溶解不溶性染料制成的碱金属或铵离子，其可以是靛蓝，硝基，偶氮，酰亚胺，蒽醌，恶嗪，噻嗪，二恶嗪，喹啉，次甲基，聚甲基 或酞菁染料。 水溶性染料适用于染色和印刷合成纤维，其特征在于它们可以通过热量的影响在染色过程中容易地转化成原始的水不溶性染料。 它们对于其中产生深染色的材料的聚酯染色特别有用。
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公开(公告)号：US3763193A
公开(公告)日：1973-10-02
申请号：US3763193D
申请日：1971-02-17
Applicant: BAYER AG
CPC classification number: C09B69/08 , C09B1/06 , C09B1/50 , C09B1/51 , C09B1/58 , D06P1/0048 , D06P3/36 , Y10S8/921 , Y10S8/922 , Y10S8/924
Abstract: ANTHRAQUINONE DYESTUFFS USEFUL IN THE DYEING OF CELLULOSE ESTERS, POLYAMIDES, OR POLYESTER FIBRE MATERIALS CONTAINING FROM TWO TO FOUR AUXOCHROMES IN THE ALPHA POSITION AND AN ACYLOXY GROUP IN THE BETA POSITION, SAID ACYLOXY GROUP BEING PREFERABLY A SULPHONOXY GROUP CONTAINING AN ARYL, ALKYL, OR DIALKYLAMINO SUBSTITUENT.
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